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The exact superconducting phase of K2-xFe4+ySe5 has yet conclusively decided since its discovery due to its intrinsic multiphase in early material. In an attempt to resolve the mystery, we have carried out systematic structural studies on a…

We report a detailed study of the Te vapor annealing effect in Fe$_{1+y}$Te$_{0.6}$Se$_{0.4}$ single crystals. Bulk superconductivity can be gradually induced by annealing with increasing amount of Te, until the molar ratio of Te to the…

The interplay between superconductivity and magnetism is an important subject in condensed matter physics. EuFe$_{2}$As$_{2}$-based iron pnictides could offer an interesting plateau to study their relationship that has attracted…

We report the results of electrical and magnetic properties on two new compounds, K0.8Fe1.7S2 and K0.8Fe1.7SeS, both having similar structures to newly discovered superconducting K0.8Fe1.7Se2. K0.8Fe1.7S2 exhibits a semiconductor-like…

With single crystal X-ray diffraction studies, we compare the structures of three sample showing optimal superconductivity, K0.774(4)Fe1.613(2)Se2, K0.738(6)Fe1.631(3)Se2 and Cs0.748(2)Fe1.626(1)Se2. All have an almost identical ordered…

Single crystals of Tl0.58Rb0.42Fe1.72Se2 are successfully grown with the superconducting transition temperatures Tconset=32K and Tczero=31.4K. The Hall coefficient exhibits a multi-band behavior, which is very similar to that of all other…

超导电性 · 物理学 2011-02-21 Hangdong Wang , Chihen Dong , Zujuan Li , Shasha Zhu , Qianhui Mao , Chunmu Feng , H. Q. Yuan , Minghu Fang

The normal state and superconducting properties are investigated in the phase diagram of K_xSr_{1-x}Fe_2As_2 for 0<x<1. The ground state upper critical field, H_{c2}(0), is extrapolated from magnetic field dependent resistivity…

超导电性 · 物理学 2009-03-03 B. Lv , M. Gooch , B. Lorenz , F. Chen , A. M. Guloy , C. W. Chu

We have successfully grown single crystalline NaFeAs with cobalt or phosphor doping. Bulk superconductivity occurs in NaFe$_{0.95}$Co$_{0.05}$As at 19 K while much higher transition temperature is observed in NaFeAs$_{0.8}$P$_{0.2}$, in…

超导电性 · 物理学 2010-02-03 T. -L. Xia , J. B. He , D. M. Wang , G. F. Chen

The recent discovery and subsequent developments of FeAs-based superconductors have presented novel challenges and opportunities in the quest for superconducting mechanisms in correlated-electron systems. Central issues of ongoing studies…

Enhancements of superconducting properties were observed in FeSe wires using a quenching technique. Zero resistivity was achieved at about 10 K in quenched wires, which is about 2 K higher than that of polycrystalline FeSe bulk.…

Experimental evidences from transport, magnetic, and magneto-optical (MO) image measurements confirmed that arsenic (As) vapor annealing was another effective way to induce bulk superconductivity with isotropic, large, and homogenous…

In this paper, we address a number of outstanding issues concerning the nature and the role of magnetic inhomogenities in the iron chalcogenide system FeTe1-xSex and their correlation with superconductivity in this system. We report…

The nuclear and magnetic structure of Fe1+y(Te1-x,Sex) (0 < x < 0.20) compounds was analyzed between 2 K and 300 K by means of Rietveld refinement of neutron powder diffraction data. Samples with x < 0.075 undergo a tetragonal to monoclinic…

By the first-principle electronic structure calculations, we study the effect of Wyckoff position of K atom on the crystal and electronic structures of KFe$_2$Se$_2$ compound.When the K atoms take up the Wyckoff position $2a$, $2b$ or $4c$…

超导电性 · 物理学 2014-03-07 Xun-Wang Yan , Miao Gao

Superconductivity has been explored in single crystals of the Ni-doped FeAs-compound SrFe2-xNixAs2 grown by self-flux solution method. The antiferromagnetic order associated with the magnetostructural transition of the parent compound…

超导电性 · 物理学 2011-01-27 Shanta R. Saha , Nicholas P. Butch , Kevin Kirshenbaum , Johnpierre Paglione

Calculations of the electronic and magnetic properties of the non-magnetic metallic compound YFe$_2$Si$_2$ are reported. These show that at the density functional level a magnetic state involving ordering along the $c$-axis. The electronic…

强关联电子 · 物理学 2016-06-30 D. J. Singh

To explore the origin of the unusual non-bulk superconductivity with a Tc up to 49 K reported in the rare-earth-doped CaFe2As2 , the chemical composition, magnetization, specific heat, resistivity, and annealing effect are systematically…

超导电性 · 物理学 2016-03-02 L. Z. Deng , B. Lv , K. Zhao , F. Y. Wei , Y. Y. Xue , Z. Wu , C. W. Chu

We report synthesis, structural details and magnetization of SmFe1-xCoxAsO with x ranging from 0.0 to 1.0 at close interval of 0.10. It is found that Co substitutes fully at Fe site in SmFeAsO in an iso-structural lattice with slightly…

超导电性 · 物理学 2012-01-20 V. P. S. Awana , Anand Pal , Mushahid Hussain , H. Kishan

The discovery of superconductivity in alkali-ammonia co-intercalated FeSe has generated intensive interest because of their highest Tc (~ 45 K) among iron-chalcogenide superconductors with bulk form. Here, we report the phase diagrams of…

超导电性 · 物理学 2014-12-10 Hechang Lei , Jiangang Guo , Fumitaka Hayashi , Hideo Hosono

We compare the superconducting phase-diagram under high magnetic fields (up to $H = 45$ T) of Fe$_{1+y}$Se$_{0.4}$Te$_{0.6}$ single crystals originally grown by the Bridgman-Stockbarger (BRST) technique, which were annealed to display…