相关论文: Ices in starless and starforming cores
Analyses of infrared signatures of CO$_2$ in water dominated ices in the ISM can give information on the physical state of CO$_2$ in icy grains and on the thermal history of the ices themselves. In many sources, CO$_2$ was found in the…
We investigate the role of carbon monoxide ice in the chemical evolution of prestellar cores using astrochemical rate equation models. We constrain the ratios of the binding energies on CO ice and H$_{2}$O ice for a series of adsorbates…
The properties of the ices that form in dense molecular clouds represent an important set of initial conditions in the evolution of interstellar and preplanetary matter in regions of active star formation. Of the various spectral features…
Context. The gas and ice-grain chemistry of the pre-stellar core L1544 has been the subject of several observations and modelling studies conducted in the past years. The chemical composition of the ice mantles reflects the environmental…
Ice is a major component of astrophysical environment - from interstellar molecular clouds through protoplanetary disks to evolved solar systems. Ice and complex organic matter coexist in these environments as well, and it is thought…
We investigate the chemical history of interstellar OCS and SO2 by deriving a statistically-significant sample of gas-phase column densities towards massive protostars and comparing to observations of gas and ices towards other sources…
Context: HCOOH is one of the more common species in interstellar ices with abundances of 1-5% with respect to solid H2O. Aims: This study aims at characterizing the HCOOH spectral features in astrophysically relevant ice mixtures in order…
The composition of protoplanetary disks, and hence the initial conditions of planet formation, may be strongly influenced by the infall and thermal processing of material during the protostellar phase. Composition of dust and ice in…
In regions where stars form, variations in density and temperature can cause gas to freeze-out onto dust grains forming ice mantles, which influences the chemical composition of a cloud. The aim of this paper is to understand in detail the…
Grains of ice are formed spontaneously when water vapor is injected into a weakly-ionized laboratory plasma in which the background gas has been cooled to cryogenic temperatures comparable to those of deep space. These ice grains are…
Protoplanetary disk ice lines shape a multitude of planet formation processes, setting the environmental composition through evolution. Ice line locations depend on molecular sublimation and deposition properties, but in dynamic disks where…
CO is thought to be the main reservoir of volatile carbon in protoplanetary disks, and thus the primary initial source of carbon in the atmospheres of forming giant planets. However, recent observations of protoplanetary disks point towards…
We study the formation conditions of icy planetesimals in protoplanetary disks in order to determine the composition of ices in small and cold extrasolar planets. Assuming that ices are formed from hydrates, clathrates, and pure…
A model is proposed for the formation of water ice mantles on grains in interstellar clouds. This occurs by direct accretion of monomers from the gas, be they formed by gas or surface reactions. The model predicts the existence of a…
This paper will review the basic concepts of gas-phase and grain surface chemistry of dense molecular clouds, where low mass and high mass stars form. The chemistry of cold pre-stellar cloud cores, where molecular freeze-out and deuterium…
We investigate the molecular evolution and D/H abundance ratios that develop as star formation proceeds from a dense-cloud core to a protostellar core, by solving a gas-grain reaction network applied to a 1-D radiative hydrodynamic model…
Major components of ices on interstellar grains in molecular clouds - water and carbon oxides - occur at various optical depths. This implies that selective desorption mechanisms are at work. An astrochemical model of a contracting low-mass…
Water ice is expected to be the dominant volatile component of bodies formed in the outer Solar System. However, recent observations of comets and trans-Neptunian objects suggest that the relative abundances of ices can vary substantially,…
The disk midplane temperature is potentially affected by the dust traps/rings. The dust depletion beyond the water snowline will cast a shadow. In this study, we adopt a detailed gas-grain chemical reaction network, and investigate the…
Comets have similar compositions to interstellar medium ices, suggesting at least some of their molecules maybe inherited from an earlier stage of evolution. To investigate the degree to which this might have occurred we compare the…