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The nucleation and growth of single wall carbon nanotubes from a carbon-saturated catalytic particle surrounded by a single sheet of graphene is described qualitatively by using a very restricted number of elementary processes, namely…

材料科学 · 物理学 2007-05-23 Francois Beuneu

It is shown that nanotubes with thicker walls can be grown from strongly bonded multi-layered structures only in accord with some basic crystallographic principles. Either the diameters of such tubes remain large in comparison with the…

材料科学 · 物理学 2009-01-23 Albert Prodan , Herman J. P. van Midden , Erik Zupanic

During the catalytic synthesis of graphene, nanotubes, fibers, and other nanostructures, many intriguing phenomena occur, such as phase separation, precipitation, and analogs of capillary action. We demonstrate that catalytic nanoparticles…

介观与纳米尺度物理 · 物理学 2018-04-11 Pin Ann Lin , Bharath Natarajan , Michael Zwolak , Renu Sharma

Single-walled carbon nanotubes are hollow cylinders, that can grow centimeters long by carbon incorporation at the interface with a catalyst. They display semi-conducting or metallic characteristics, depending on their helicity, that is…

材料科学 · 物理学 2018-11-14 Yann Magnin , Hakim Amara , François Ducastelle , Annick Loiseau , Christophe Bichara

A simple model for the nucleation and growth of single wall carbon nanotubes from a graphene sheet at the surface of a metallic catalyst saturated in carbon is developed. It enables to predict the geometry and energy of tube embryos of all…

介观与纳米尺度物理 · 物理学 2012-03-26 Francois Beuneu

Based on first-principles calculations we predict a peculiar growth process, where carbon adatoms adsorbed to graphene readily diffuse above room temperature and nucleate segments of linear carbon chains attached to graphene. These chains…

材料科学 · 物理学 2011-05-03 C. Ataca , S. Ciraci

In order to accommodate an increasing demand for carbon nanotubes (CNTs) with desirable characteristics one has to understand the origin of helicity of their structures. Here, through in situ microscopy we demonstrate that the nucleation of…

We use ab initio density functional calculations to study the formation and structural as well as thermal stability of cellular foam-like carbon nanostructures. These systems with a mixed $sp^2/sp^3$ bonding character may be viewed as…

材料科学 · 物理学 2015-06-11 Zhen Zhu , David Tománek

By sequential feeding of catalyst materials, it is revealed that the active growth sites are at the bottom of the carbon nanotubes (CNTs), and that catalyst particles are constantly encapsulated into nanotubes from the bottom. This gives a…

材料科学 · 物理学 2007-07-19 Rong Xiang , Guohua Luo , Weizhong Qian , Qiang Zhang , Yao Wang , Fei Wei , Qi Li , Anyuan Cao

Recent direct measurements of the growth kinetics of individual carbon nanotubes revealed abrupt changes in the growth rate of nanotubes maintaining the same crystal structure. These stochastic switches call into question the possibility of…

介观与纳米尺度物理 · 物理学 2023-02-24 Georg Daniel Förster , Vladimir Pimonov , Huy-Nam Tran , Saïd Tahir , Vincent Jourdain , Christophe Bichara

Formation, evolution, and vanishing of bubbles are common phenomena in our nature, which can be easily observed in boiling or falling waters, carbonated drinks, gas-forming electrochemical reactions, etc. However, the morphology and the…

Carbon nanotubes have properties depending on the arrangement of carbon atoms on the tube walls, called chirality. Also it has been tried to grow nanotubes of only one chirality for more than a decade it is still not possible today. A…

材料科学 · 物理学 2013-05-02 Heiko Dumlich , John Robertson , Stephanie Reich

Carbon nanotubes are of potential interest as heterogeneous catalysis supports, in part because they offer a high surface area hexagonal array of carbon atoms for columnar or epitaxial attachment. Fringe visibility modeling of electron…

材料科学 · 物理学 2009-11-11 Jinfeng Wang , P. Fraundorf , Yangchuan Xing

Carbon nanotubes (CNT) hold enormous technological promise. It can only be harnessed if one controls in a practical way the CNT chirality, the feature of the tubular carbon topology that governs all the CNT properties---electronic, optical,…

材料科学 · 物理学 2014-09-18 Vasilii I. Artyukhov , Evgeni S. Penev , Boris I. Yakobson

Understanding the kinetic selectivity of carbon nanotube growth at the scale of individual nanotubes is essential for the development of high chiral selectivity growth methods. Here we demonstrate that homodyne polarization microscopy can…

Microtubule dynamics is largely influenced by nucleotide hydrolysis and the resultant tubulin configuration changes. The GTP cap model has been proposed to interpret the stabilizing mechanism of microtubule growth from the view of…

生物物理 · 物理学 2015-05-30 Xiang-Ying Ji , Xi-Qiao Feng

Optimized growth of Single Wall Carbon Nanotubes requires a full knowledge of the actual state of the catalyst nanoparticle and its interface with the tube. Using Tight Binding based atomistic computer simulations, we calculate carbon…

We investigate the growth of the recently demonstrated composite material composed of vertically aligned carbon nanotubes capped by few graphene layers. We show that the carbon nanotubes grow epitaxially under the few graphene layers. By…

材料科学 · 物理学 2011-03-24 V. Jousseaume , J. Cuzzocrea , N. Bernier , Vincent Thomas Francois Renard

We investigate the role of carbon nanotubes structure on their optical limiting properties. Samples of different and well-characterized structural features are studied by optical limiting and pump-probe experiments. The influence of the…

其他凝聚态物理 · 物理学 2009-11-11 Nicolas Izard , Pierre Billaud , Didier Riehl , Eric Anglaret

We present a detailed study of the geometry, structure and energetics of carbon nanotube caps. We show that the structure of a cap uniquely determines the chirality of the nanotube that can be attached to it. The structure of the cap is…

材料科学 · 物理学 2015-06-25 S. Reich , L. Li , J. Robertson
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