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We present a novel comprehensive first-principles theoretical study of the electronic properties and relative stabilities of edge-oxidized zigzag graphene nanoribbons. The oxidation schemes considered include hydroxyl, carboxyl, ether, and…

材料科学 · 物理学 2015-05-13 Oded Hod , Veronica Barone , Juan E. Peralta , Gustavo E. Scuseria

We investigate the magnetism in graphite by controlled oxidation. Our approach renders graphite an insulator while maintaining its structure. Fourier transform infrared spectroscopy and X-ray absorption near edge structure spectra reveal…

强关联电子 · 物理学 2011-02-24 D. W. Lee , J. M. Cole , J. W. Seo , S. S. Saxena , C. H. W. Barnes , E. E. M. Chia , C. Panagopoulos

Room temperature ferromagnetic materials composed only by light elements like carbon, hydrogen and/or nitrogen, so called carbon magnet, are very attractive for creating new material categories both in science and industry. Recently several…

介观与纳米尺度物理 · 物理学 2011-01-24 Norio Ota , Narjes Gorjizadeh , Yoshiyuki Kawazoe

Novel route for the establishing of magnetism in realistic oxidized graphene nanoribbons is proposed. Modelling of the migration of hydroxyl groups from central part to the zig-zag edges of graphene nanoribbons passivated by oxygen are…

材料科学 · 物理学 2015-05-20 D. W. Boukhvalov

Electronic and magnetic properties of ribbon-shaped nanographite systems with zigzag and armchair edges in a magnetic field are investigated by using a tight binding model. One of the most remarkable features of these systems is the…

材料科学 · 物理学 2016-08-31 Katsunori Wakabayashi , Mitsutaka Fujita , Hiroshi Ajiki , Manfred Sigrist

Realizing magnetism in graphene/carbon nanostructures is a decade-long challenge. The magnetic edge state and half metallicity in zigzag graphene nanoribbons are particularly promising [Y.-W. Son, et al., Nature 444, 347 (2006)]. However,…

介观与纳米尺度物理 · 物理学 2018-12-05 Shiyuan Gao , Li Yang

Investigations of the magnetic properties of graphenes prepared by different methods reveal that dominant ferromagnetic interactions coexist along with antiferromagnetic interactions in all the samples. Thus, all the graphene samples…

化学物理 · 物理学 2009-04-20 H. S. S. Ramakrishna Matte , K. S. Subrahmanyam , C. N. R. Rao

It is shown that apart from well-known factors, like temperature, substrate, and edge reconstruction effects, also the presence of external contacts is destructive for the formation of magnetic moments at the edges of graphene nanoribbons.…

介观与纳米尺度物理 · 物理学 2014-11-18 S. Krompiewski

Hydrogenated nanographite can display spontaneous magnetism. Recently we proposed that hydrogenation of nanographite is able to induce finite magnetization. We have performed theoretical investigation of a graphene ribbon in which each…

材料科学 · 物理学 2009-11-07 Koichi Kusakabe , Masanori Maruyama

The possibility for carbon materials such as activated carbon fibers or graphite ribbons, to support edge-states could change drastically their magnetic properties. The purpose of this work is to propose a novel way to identify the…

凝聚态物理 · 物理学 2007-05-23 S. Pleutin , A. A. Ovchinnikov

Zigzag graphene nanoribbons patterned on graphane are studied using spin-polarized ab initio calculations. We found that the electronic and magnetic properties of the graphene/graphane superlattice strongly depends on the degree of…

介观与纳米尺度物理 · 物理学 2010-10-19 A. D. Hernandez-Nieves , B. Partoens , F. M. Peeters

We review our recent work on magnetic properties of graphite and related carbon materials. The results demonstrate that a structural disorder, topological defects, as well as adsorbed foreign atoms can be responsible for the occurrence of…

强关联电子 · 物理学 2007-05-23 Y. Kopelevich , S. Moehlecke , R. R. da Silva

We have performed a first-principles study on the deformation effect of the electronic structures of graphite nanoribbon arrays with zigzag edges on both sides, and the edge atoms are terminated with hydrogen atoms. A uniaxial strain is…

材料科学 · 物理学 2008-10-28 W. S. Su , B. R. Wu , T. C. Leung

Nanographite systems, where graphene sheets of the orders of the nanometer size are stacked, show novel magnetic properties, such as, spin-glass like behaviors and the change of ESR line widths in the course of gas adsorptions. We…

材料科学 · 物理学 2016-08-31 K. Harigaya

The influence of carrier density on magnetism in a zigzag graphene nanoribbon is studied in a $\pi$-orbital Hubbard-model mean-field approximation. Departures from half-filling alter the magnetism, leading to states with charge density…

介观与纳米尺度物理 · 物理学 2011-01-31 J. Jung , A. H. MacDonald

Armchair graphene nanoribbons with different proportions of edge oxygen atoms are investigated by using crystal orbital method based on density functional theory. All the nanoribbons are energetically favorable, although buckled edges are…

材料科学 · 物理学 2014-11-07 Hongyu Ge , Guo Wang , Yi Liao

We perform density functional calculations on one-dimensional zigzag edge graphene nano-ribbons (ZGNRs) of different widths, with and without edge doping including semi-local exchange-correlations. Our study reveals that, although the…

材料科学 · 物理学 2008-06-13 Sudipta Dutta , Swapan K. Pati

Antiferromagnetism in stacked nanographite is investigated with using the Hubbard-type model. The A-B stacking is favorable for the hexagonal nanographite with zigzag edges, in order that magnetism appears. Next, we find that the open shell…

凝聚态物理 · 物理学 2016-08-31 Kikuo Harigaya , Naoki Kawatsu , Toshiaki Enoki

We have theoretically investigated the electronic and magnetic properties of graphene whose zigzag edges are oxidized. The alteration of these properties by adsorption of $\mathrm{H_{2}O}$ and $\mathrm{NH_3}$ molecules have been considered.…

化学物理 · 物理学 2015-05-14 Julia Berashevich , Tapash Chakraborty

We explore possible ways to manipulate the intrinsic edge magnetism in hexagonal graphene nanoflake with zigzag edges, using density functional theory supplemented with on-site Coulomb interaction. The effect of carrier doping, chemical…

介观与纳米尺度物理 · 物理学 2014-07-08 Mukul Kabir , T. Saha-Dasgupta
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