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Supersonic beams of polar molecules are deflected using inhomogeneous electric fields. The quantum-state selectivity of the deflection is used to spatially separate molecules according to their quantum state. A detailed analysis of the…

We have developed and experimentally demonstrated an improved electrostatic deflector for the spatial separation of molecules according to their dipole-moment-to-mass ratio. The device features a very open structure that allows for…

化学物理 · 物理学 2017-07-25 Jens S. Kienitz , Karol Długołecki , Sebastian Trippel , Jochen Küpper

A strong inhomogeneous static electric field is used to spatially disperse a supersonic beam of polar molecules, according to their quantum state. We show that the molecules residing in the lowest-lying rotational states can be selected and…

Laser spectroscopy of cold and trapped molecular ions is a powerful tool for fundamental physics, including the determination of fundamental constants, the laboratory test for their possible variation, and the search for a possible electric…

原子物理 · 物理学 2016-02-26 Fabian Wolf , Yong Wan , Jan C. Heip , Florian Gebert , Chunyan Shi , Piet O. Schmidt

We demonstrate and analyze a strongly driven quantum pendulum in the angular motion of stateselected and laser aligned OCS molecules. Raman-couplings during the rising edge of a 50-picosecond laser pulse create a wave packet of pendular…

The manipulation of the motion of neutral molecules with electric or magnetic fields has seen tremendous progress over the last decade. Recently, these techniques have been extended to the manipulation of large and complex molecules. In…

化学物理 · 物理学 2011-04-07 Frank Filsinger , Gerard Meijer , Henrik Stapelfeldt , Henry N. Chapman , Jochen Küpper

The structure and quantum state of the reactants have a profound impact on the kinetics and dynamics of chemical reactions. Over the past years, significant advances have been made in the control and manipulation of molecules with external…

化学物理 · 物理学 2021-12-22 L. Ploenes , P. Straňák , H. Gao , J. Küpper , S. Willitsch

Quantum-logic techniques used to manipulate quantum systems are now increasingly being applied to molecules. Previous experiments on single trapped diatomic species have enabled state detection with excellent fidelities and highly precise…

量子物理 · 物理学 2025-03-18 Kaveh Najafian , Ziv Meir , Mudit Sinhal , Stefan Willitsch

The properties of molecule-optical elements such as lenses or prisms based on the interaction of molecules with optical fields depend in a crucial way on the molecular quantum state and its alignment created by the optical field. However,…

化学物理 · 物理学 2016-08-02 Lee Yeong Kim , Ju Hyeon Lee , Hye Ah Kim , Sang Kyu Kwak , Bretislav Friedrich , Bum Suk Zhao

A beam of diatomic molecules scattered off a standing wave laser mode splits according to the rovibrational quantum state of the molecules. Our numerical calculation shows that single state resolution can be achieved by properly tuned,…

量子物理 · 物理学 2009-11-06 P. Domokos , T. Kiss , J. Janszky

A moderately intense $450$ fs laser pulse is used to create rotational wave packets in gas phase $\rm{I_2}$ molecules. The ensuing time-dependent alignment, measured by Coulomb explosion imaging with a delayed probe pulse, exhibits the…

We demonstrate that a bichromatic standing-wave laser field can exert a significantly larger force on a molecule than ordinary radiation pressure. Our experiment measures the deflection of a pulsed supersonic beam of CaF molecules by a…

原子物理 · 物理学 2018-08-22 S. E. Galica , L. Aldridge , D. J. McCarron , E. E. Eyler , P. L Gould

We consider deflection of rotating symmetric molecules by inhomogeneous optical and static electric fields, compare results with the case of linear molecules, and find new singularities in the distribution of the scattering angle.…

化学物理 · 物理学 2015-05-28 Erez Gershnabel , Ilya Sh. Averbukh

We demonstrate the experimental realization of impulsive alignment of carbonyl sulfide (OCS) molecules at the Low Density Matter Beamline (LDM) at the free-electron laser FERMI. OCS molecules in a molecular beam were impulsively aligned…

A strong inhomogeneous static electric field is used to spatially disperse a rotationally cold supersonic beam of 2,6-difluoroiodobenzene molecules according to their rotational quantum state. The molecules in the lowest lying rotational…

The directional control of molecular dissociation with the laser electric field waveform is a paradigm and was demonstrated for a variety of molecules. In most cases, the directional control occurs via a dissociative ionization pathway. The…

We have experimentally and theoretically investigated the mixed-field orientation of rotational-state-selected OCS molecules and we achieve strong degrees of alignment and orientation. The applied moderately intense nanosecond laser pulses…

Detecting the internal state of polar molecules is a substantial challenge when standard techniques such as resonance-enhanced multi photon ionization (REMPI) or laser-induced fluorescense (LIF) do not work. As this is the case for most…

原子物理 · 物理学 2014-12-01 Rosa Glöckner , Alexander Prehn , Gerhard Rempe , Martin Zeppenfeld

An inhomogeneous electric field is used to study the deflection of a supersonic beam of water molecules. The deflection profiles show strong broadening accompanied by a small net displacement towards higher electric fields. The profiles are…

化学物理 · 物理学 2009-11-13 Ramiro Moro , Jaap Bulthuis , Jonathon Heinrich , Vitaly V. Kresin

A barrier to realizing the potential of molecules for quantum information science applications is a lack of high-fidelity, single-molecule imaging techniques. Here, we present and theoretically analyze a general scheme for dispersive…

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