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Transport coefficients and dielectric relaxation in liquids are often treated as distinct manifestations of molecular dynamics. We show that, in polar liquids, orientational dipolar fluctuations generate a substantial contribution to the…

统计力学 · 物理学 2026-05-12 David S. Dean , Haim Diamant

For several atomistic models of glass formers, at conditions below their glassy dynamics onset temperatures, ${T_\mathrm{o}}$, we use importance sampling of trajectory space to study the structure, statistics and dynamics of excitations…

统计力学 · 物理学 2014-05-08 Aaron S. Keys , Lester O. Hedges , Juan P. Garrahan , Sharon C. Glotzer , David Chandler

Brillouin scattering has been used to measure the dynamic structure factor of glycerol as a function of temperature from the high temperature liquid to the glassy state. Our investigation aims at understanding the number and the nature of…

软凝聚态物质 · 物理学 2009-11-10 Lucia Comez , Daniele Fioretto , Filippo Scarponi , Giulio Monaco

It is commonly accepted that shear waves do not propagate in a liquid medium. The shear wave energy is supposed to dissipate nearly instantaneously. This statement originates from the difficulty to access static shear stress in macroscopic…

介观与纳米尺度物理 · 物理学 2021-07-28 Eni Kume , Alessio Zaccone , Laurence Noirez

By analyzing the experimental data for various glass-forming liquids and polymers, we find that non-exponentiality $\beta$ and the relaxation time $\tau$ are uniquely related: $\log(\tau)$ is an approximately linear function of $1/\beta$,…

无序系统与神经网络 · 物理学 2008-07-15 K. Trachenko , C. M. Roland , R. Casalini

The dynamic response of an interacting electron system is determined by an extension of the relaxation-time approximation forced to obey local conservation laws for number, momentum and energy. A consequence of these imposed constraints is…

强关联电子 · 物理学 2009-11-07 G. S. Atwal , N. W. Ashcroft

We study the mechanical response under time-dependent sources of a simple class of holographic models that exhibit viscoelastic features. The ratio of viscosity over elastic modulus defines an intrinsic relaxation time scale -- the…

高能物理 - 理论 · 物理学 2019-12-04 Tomas Andrade , Matteo Baggioli , Oriol Pujolas

We address a recent conjecture according to which the relaxation time $\tau$ of a viscous liquid obeys density scaling ($\tau=F(\rho^\gamma/T)$ where $\rho$ is density) if the liquid is ``strongly correlating,'' i.e., has almost 100%…

软凝聚态物质 · 物理学 2012-03-27 Thomas B. Schrøder , Ulf R. Pedersen , Jeppe C. Dyre

A non-contact scanning-probe-microscopy method was used to probe local near-surface dielectric susceptibility and dielectric relaxation in poly-vinyl-acetate (PVAc) near the glass transition. Dielectric spectra were measured from 10-4 Hz to…

软凝聚态物质 · 物理学 2009-11-13 P. S. Crider , M. R. Majewski , Jingyun Zhang , H. Oukris , N. E. Israeloff

We review the recently proposed elastic approach to glass transition. This approach is based on a simple and a physically transparent idea of elastic interactions between local relaxation events in a liquid. Central to this picture is the…

软凝聚态物质 · 物理学 2008-07-25 Kostya Trachenko

If a liquid is cooled rapidly to form a glass, its structural relaxation becomes retarded, producing a drastic increase in viscosity. In two dimensions, strong long-wavelength fluctuations persist, even at low temperature, making it…

软凝聚态物质 · 物理学 2019-12-25 Hayato Shiba , Takeshi Kawasaki , Kang Kim

We report relaxation dynamics of glycerol-water mixtures as probed by megahertz-to-terahertz dielectric spectroscopy in a frequency range from 50 MHz to 0.5 THz at room temperature. The dielectric relaxation spectra reveal several…

化学物理 · 物理学 2019-09-04 Ali Charkhesht , Djamila Lou , Ben Sindle , Chengyuan Wen , Shengfeng Cheng , Nguyen Q. Vinh

Dielectric spectroscopy measurements over a broad range of temperature and pressure were carried out on poly(oxybutylene) (POB), a type-A polymer (dielectrically-active normal mode). There are three dynamic processes appearing at lower…

软凝聚态物质 · 物理学 2009-11-10 R. Casalini , C. M. Roland

Kramers relaxation times $\tau_{K}$ and relaxation times $\tau_{R}$ and $\tau_{G}$ for the end-to-end distances and for center of mass diffusion are calculated for dense systems of athermal lattice chains. $\tau_{K}$ is defined from the…

凝聚态物理 · 物理学 2015-06-24 O. Durr , H. L. Frisch , W. Dieterich

Deep in the Earth's crust, pressure exceeds one thousand times the atmospheric pressure. Water still flows under these conditions, but experiences dramatic changes in structure and fluidity. Using combined dynamic and inelastic light…

We demonstrate, via numerical simulations, that the relaxation dynamics of supercooled liquids correlates well with a plastic length scale measuring a particle's response to impulsive localized perturbations and weakly to measures of local…

软凝聚态物质 · 物理学 2022-06-23 Yan-Wei Li , Yugui Yao , Massimo Pica Ciamarra

The nonlocal dielectric properties of liquid water are studied in the context of {\it ab initio} molecular dynamics simulations based on density functional theory. We calculate the dielectric response from the charge structure factor of the…

Understanding the flow behaviors of supercooled liquids presents a major challenge in liquid-state physics due to the strong nonlinearity and rich phenomena. To unravel this complexity, we introduce the concept of local configurational…

软凝聚态物质 · 物理学 2025-11-25 Dong-Xu Yu , Ke-Qi Zeng , Zhe Wang

In some theoretical analyses of microwave-induced magnetoresistance oscillations in high-mobility two-dimensional systems, the "inelastic relaxation time" $\tau_{in}$ due to electron-electron scattering is evaluated using an equilibrium…

介观与纳米尺度物理 · 物理学 2007-05-23 X. L. Lei , S. Y. Liu

Published dielectric relaxation measurements on polypropylene glycol and 1,4-polyisoprene are analyzed to determine the relative effect that thermal energy and volume have on the temperature dependence of the normal mode relaxation times,…

软凝聚态物质 · 物理学 2015-06-24 C. M. Roland , R. Casalini , M. Paluch
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