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The out-of-plane intercalate phonons of superconducting YbC6 have been measured with inelastic x-ray scattering. Model fits to this data, and previously measured out-of-plane intercalate phonons in graphite intercalation compounds (GICs),…

超导电性 · 物理学 2015-05-20 M. H. Upton , T. R. Forrest , A. C. Walters , C. A. Howard , M. Ellerby , A. H. Said , D. F. McMorrow

We investigate the dispersion and temperature dependence of a number of phonons in the recently discovered superconductor CaC6 utilizing inelastic x-ray scattering. Four [00L] and two ab-plane phonon modes are observed, and measured at…

Recently deiscovered superconductivity in YbC$_6$ and CaC$_6$ at temperatures substantially higher than previously known for intercalated graphites, raised several new questions: (1) Is the mechanism considerably different from the…

超导电性 · 物理学 2009-11-11 I. I. Mazin

We present the results of a neutron scattering study of the high energy phonons in the superconducting graphite intercalation compound CaC$_6$. The study was designed to address hitherto unexplored aspects of the lattice dynamics in…

We discuss the current status of the theory of the "high-temperature" superconductivity in intercalated graphites YbC6 and CaC6. We emphasize that while the general picture of conventional, phonon-driven superconductivity has already…

In this letter, we report the discovery of superconductivity in Li3Ca2C6. Several graphite intercalation compounds (GICs) with electron donors, are well known as superconductors. It is probably not astonishing, since it is generally…

The superconducting state of Ca-intercalated graphite CaC6 has been investigated by specific heat measurements. The characteristic anomaly at the superconducting transition (Tc = 11.4 K) indicates clearly the bulk nature of the…

超导电性 · 物理学 2009-11-11 J. S. Kim , R. K. Kremer , L. Boeri , F. S. Razavi

We report the discovery of superconductivity below 1.65(6) K in Sr-intercalated graphite SrC6, by susceptibility and specific heat (Cp) measurements. In comparison with CaC6, we found that the anisotropy of the upper critical fields for…

超导电性 · 物理学 2009-11-13 J. S. Kim , L. Boeri , J. R. O'Brien , F. S. Razavi , R. K. Kremer

The discovery of superconductivity in CaC6 with a critical temperature (Tc) of 11.5 K reignites much interest in exploring high-temperature superconductivity in graphite intercalation compounds (GICs). Here we identify a GIC NaC4,…

Inelastic x-ray scattering (IXS) with very high (meV) energy resolution has become a valuable spectroscopic tool, complementing the well established coherent inelastic neutron scattering (INS) technique for phonon dispersion investigations.…

强关联电子 · 物理学 2009-11-07 M. d'Astuto , P. K. Mang , P. Giura , A. Shukla , A. Mirone , M. Krisch , F. Sette , P. Ghigna , M. Braden , M. Greven

Motivated by the recent discovery of superconductivity in Ca- and Yb-intercalated graphite (CaC$_{6}$ and YbC$_{6}$) and from the ongoing debate on the nature and role of the interlayer state in this class of compounds, in this work we…

超导电性 · 物理学 2016-08-14 Lilia Boeri , Giovanni B. Bachelet , Matteo Giantomassi , Ole K. Andersen

Using density functional theory we investigate the occurrence of superconductivity in AC$_6$ with A=Mg,Ca,Sr,Ba. We predict that at zero pressure, Ba and Sr should be superconducting with critical temperatures (T$_c$) 0.2 K and 3.0 K,…

超导电性 · 物理学 2009-11-11 Matteo Calandra , Francesco Mauri

We report the superconductivity in Ca-intercalated bilayer graphene C$_6$CaC$_6$, the thinnest limit of Ca graphite intercalation compound. We performed \textit{in situ} electrical transport measurements on pristine bilayer graphene,…

超导电性 · 物理学 2016-02-02 S. Ichinokura , K. Sugawara , A. Takayama , T. Takahashi , S. Hasegawa

The pressure effect on the superconducting transition temperature ($T_c$) of the newly-discovered Ca-intercalated graphite compound CaC$_6$ has been investigated up to $\sim$ 16 kbar. $T_c$ is found to increase under pressure with a large…

超导电性 · 物理学 2015-06-25 J. S. Kim , L. Boeri , R. K. Kremer , F. S. Razavi

In this study, we conducted experiments on CaC6 for elucidating the Na-catalyzed formation mechanism and achieving rapid mass synthesis of graphite intercalation compounds (GICs). Rapidly synthesized CaC6 was characterized by analysis of…

In this letter we report the discovery of superconductivity in the isostructural graphite intercalation compounds C6Yb and C6Ca, with transition temperatures of 6.5K and 11.5K respectively. A structural characterisation of these compounds…

Using density functional theory we demonstrate that superconductivity in C6Ca is due to a phonon-mediated mechanism with electron-phonon coupling 0.83 and phonon-frequency logarithmic-average 24.7 meV. The calculated isotope exponents are…

超导电性 · 物理学 2007-05-23 Matteo Calandra , Francesco Mauri

We have performed photoemission studies of the electronic structure in LiC$_6$ and KC$_8$, a non-superconducting and a superconducting graphite intercalation compound, respectively. We have found that the charge transfer from the…

超导电性 · 物理学 2011-05-20 Z. -H. Pan , J. Camacho , M. H. Upton , A. V. Fedorov , C. A. Howard , M. Ellerby , T. Valla

We report a study of the temperature dependence of the surface resistance RS in the graphite intercalated compound (GIC) CaC6, where superconductivity at 11.5 K was recently discovered. Experiments are carried out using a copper…

超导电性 · 物理学 2009-11-11 G. Cifariello , E. Di Gennaro , G. Lamura , A. Andreone , N. Emery , C. Herold , J. F. Mareche , P. Lagrange

We report the first Raman scattering measurements of BaC$_6$, SrC$_6$, and YbC$_6$, which along with new data on CaC$_6$, permits a systematic study of the phonons and the electron-phonon interaction within the doped graphene layers of…

强关联电子 · 物理学 2010-06-08 Mark P. M. Dean , Christopher A. Howard , Siddharth S. Saxena , Mark Ellerby
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