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We report the crystal growth and structural, magnetic, conductivity, and specific heat investigations of Rb(1-x)Fe(2-y)Se2 single crystals with varying stoichiometry prepared by self-flux and Bridgman methods. The system exhibits a strongly…

超导电性 · 物理学 2011-11-01 V. Tsurkan , J. Deisenhofer , A. Günther , H. -A. Krug von Nidda , S. Widmann , A. Loidl

The ThCr2Si2-type arsenide-selenide phase KFe2AsSe is proposed as a parent system for a new "intermediate" group of Fe-based superconducting materials bridging the known families of Fe-pnictides (such as BaFe2As2) and Fe-chalcogenides (such…

超导电性 · 物理学 2015-05-28 Igor R. Shein , Alexander L. Ivanovskii

We report thermal transport measurement of KxFe2-ySe2 superconducting single crystal. Significant peak anomaly in thermal conductivity is observed at nearly TC/2 indicating a large phonon mean-free-path in the superconducting state. The…

超导电性 · 物理学 2015-05-27 Kefeng Wang , Hechang Lei , C. Petrovic

We report the results of electrical and magnetic properties on two new compounds, K0.8Fe1.7S2 and K0.8Fe1.7SeS, both having similar structures to newly discovered superconducting K0.8Fe1.7Se2. K0.8Fe1.7S2 exhibits a semiconductor-like…

We present LDA band structure of novel hole doped high temperature superconductors (Tc~30K) KxFe2Se2 and CsxFe2Se2 and compare it with previously studied electronic structure of isostructural FeAs superconductor BaFe2As2 (Ba122). We show…

超导电性 · 物理学 2011-04-20 I. A. Nekrasov , M. V. Sadovskii

First principles FLAPW-GGA method was used for the comparative study of the structural and electronic properties of three related tetragonal ThCr2Si2-type phases KFe2Ch2, where Ch are S, Se, and Te. The main trends in electronic bands,…

超导电性 · 物理学 2011-02-23 I. R. Shein , A. L. Ivanovskii

High-pressure magnetization, structural and 57Fe M\"ossbauer studies were performed on superconducting Rb0.8Fe1.6Se2.0 with Tc = 32.4 K. The superconducting transition temperature gradually decreases on increasing pressure up to 5.0 GPa…

The discovery of superconductivity in the two-leg ladder compound BaFe$_2$S$_3$ has established the 123-type iron chalcogenides as a novel and interesting subgroup of the iron-based superconductors family. However, in this 123 series,…

材料科学 · 物理学 2018-01-18 Yang Zhang , Ling-Fang Lin , Jun-Jie Zhang , Elbio Dagotto , Shuai Dong

Up to now, there have been two material families, the cuprates and the iron-based compounds with high-temperature superconductivity (HTSC). An essential open question is whether the two classes of materials share the same essential physics.…

超导电性 · 物理学 2011-04-20 Minghu Fang , Hangdong Wang , Chiheng Dong , Zujuan Li , Chunmu Feng , Jian Chen , H. Q. Yuan

A new layered iron arsenide oxide (Fe2As2)(Ca4(Mg,Ti)3Oy) was discovered. Its crystal structure is tetragonal with a space group of I4/mmm consisted of the anti-fluorite type FeAs layer and blocking layer of triple perovskite cells and is…

The discovery of superconductivity in the 122 iron selenide materials above 30 K necessitates an understanding of the underlying magnetic interactions. We present a combined experimental and theoretical investigation of magnetic and…

强关联电子 · 物理学 2015-06-23 E. E. McCabe , C. Stock , J. L. Bettis , M. -H. Whangbo , J. S. O. Evans

We have synthesized two iron fluo-arsenides $A$Ca$_2$Fe$_4$As$_4$F$_2$ with $A$ = Rb and Cs, analogous to the newly discovered superconductor KCa$_2$Fe$_4$As$_4$F$_2$. The quinary inorganic compounds crystallize in a body-centered…

超导电性 · 物理学 2017-04-05 Zhi-Cheng Wang , Chao-Yang He , Zhang-Tu Tang , Si-Qi Wu , Guang-Han Cao

Much remains unknown of the microscopic origin of superconductivity when it materializes in atomically disordered systems as in amorphous alloys (1) or in crystals riddled with defects(2). A manifestation of this conundrum is envisaged in…

超导电性 · 物理学 2013-02-12 Despina Louca , Keeseong Park , Bing Li , Joerg Neuefeind , Jiaqiang Yan

The correlation and competition between antiferromagnetism and superconductivity are one of the most fundamental issues in all of high temperature superconductors. The superconductivity in high temperature cuprate superconductors arises…

超导电性 · 物理学 2012-04-11 Y. J. Yan , M. Zhang , A. F. Wang , J. J. Ying , Z. Y. Li , W. Qin , X. G. Luo , J. Q. Li , Jiangping Hu , X. H. Chen

The discovery of a new family of high Tc materials, the iron arsenides (FeAs), has led to a resurgence of interest in superconductivity. Several important traits of these materials are now apparent, for example, layers of iron tetrahedrally…

Fe-based superconductors exhibit a diverse interplay between charge, orbital, and magnetic ordering1-4. Variations in atomic geometry affect electron hopping between Fe atoms5,6 and the Fermi surface topology, influencing magnetic…

Heterogeneous superconductivity onset is a common phenomenon in high-$T_c$ superconductors of both the cuprate and iron-based families. It is manifested by a fairly wide transition from the metallic to zero-resistance state. Usually, in…

超导电性 · 物理学 2023-07-04 P. D. Grigoriev , V. D. Kochev , A. P. Orlov , A. V. Frolov , A. A. Sinchenko

The superconducting properties of a recently discovered high $T_{\rm c}$ superconductor, Sr/ammonia-intercalated FeSe, have been measured using pulsed magnetic fields down to $4.\,\rm {K}$ and muon spin spectroscopy down to $1.5\,\rm K$.…

Two-dimensional (2D) superconductors supply important platforms for exploring new quantum physics and high-$T_c$ superconductivity. The intrinsic superconducting properties in the 2D iron-arsenic superconductors are still unknown owing to…

超导电性 · 物理学 2021-05-10 Chi Zhang , Tao Hu , Teng Wang , Yufeng Wu , Aobo Yu , Jianan Chu , Han Zhang , Hong Xiao , Wei Peng , Zengfeng Di , Shan Qiao , Gang Mu

We report structurally tuned superconductivity in KxFe2-ySe2-zSz (0<=z<=2) phase diagram. Superconducting Tc is suppressed as S is incorporated into the lattice, eventually vanishing at 80% of S. The magnetic and conductivity properties can…

超导电性 · 物理学 2011-09-22 Hechang Lei , Milinda Abeykoon , Emil S. Bozin , Kefeng Wang , J. B. Warren , C. Petrovic