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The magnetic and iron vacancy orders in superconducting (Tl,Rb)2Fe4Se5 single-crystals are investigated by using a high-pressure neutron diffraction technique. Similar to the temperature effect, the block antiferromagnetic order gradually…

The crystal structure of the superconductor FeSe0.44Te0.56 was redetermined by high-resolution X-ray single crystal diffraction at 173 K (anti-PbO-type, P4/nmm, a=3.7996(2), c=5.9895(6) A, R1=0.022, wR2=0.041, 173 F^2). Significantly…

超导电性 · 物理学 2010-02-24 Marcus Tegel , Catrin Loehnert , Dirk Johrendt

We report on synthesis of single crystals of BaFe2Se3 and study of their crystal and magnetic structures by means of synchrotron single crystal X-ray and neutron powder diffraction. The crystal structure has orthorhombic symmetry and…

The latest discovery of a new iron-chalcogenide superconductor A$_x$Fe$_{2-y}$Se$_2$(A=K, Cs, Rb, Tl and etc.) has attracted much attention due to a number of its unique characteristics, such as the possible insulating state of the parent…

超导电性 · 物理学 2012-01-04 Daixiang Mou , Lin Zhao , Xingjiang Zhou

Crystal structures and microstructural features, such as structural phase transitions, defect structures, chemical and structural inhomogeneities, are known to have profound effects on the physical properties of superconducting materials.…

超导电性 · 物理学 2013-07-22 Wang Zhen , Cai Yao , Yang Huai-Xin , Tian Huan-Fang , Wang Zhi-Wei , Ma Chao , Chen Zhen , Li Jian-Qi

Structural investigations by means of transmission electron microscopy (TEM) on KFexSe2 with 1.5 \leq x \leq 1.8 have revealed a rich variety of microstructure phenomena, the KFe1.5Se2 crystal often shows a superstructure modulation along…

超导电性 · 物理学 2013-05-29 Z. Wang , Y. J. Song , H. L. Shi , Z. W. Wang , Z. Chen , H. F. Tian , G. F. Chen , J. G. Guo , H. X. Yang , J. Q. Li

Elastic neutron scattering simultaneously probes both the crystal structure and magnetic order in a material. Inelastic neutron scattering measures phonons and magnetic excitations. Here, we review the average composition, crystal structure…

超导电性 · 物理学 2014-12-15 Wei Bao

FeSe-derived superconductors show some unique behaviors relative to iron-pnictide superconductors, which are very helpful to understand the mechanism of superconductivity in high-Tc iron-based superconductors. The low-energy electronic…

超导电性 · 物理学 2014-12-17 X. F. Lu , N. Z. Wang , H. Wu , Y. P. Wu , D. Zhao , X. Z. Zeng , X. G. Luo , T. Wu , W. Bao , G. H. Zhang , F. Q. Huang , Q. Z. Huang , X. H. Chen

The magnetic structure of BaFe2As2 was completely determined from polycrystalline neutron diffraction measurements soon after the ThCr2Si2-type FeAs-based superconductors were discovered. Both the moment direction and the in-plane…

超导电性 · 物理学 2009-05-08 M. Kofu , Y. Qiu , Wei Bao , S. -H. Lee , S. Chang , T. Wu , G. Wu , X. H. Chen

We studied the correlation among structure and transport properties and superconductivity in the different $A_x$Fe$_2$Se$_2$ single crystals ($A$ = K, Rb, and Cs). Two sets of (00$l$) reflections are observed in the X-ray single crystal…

Neutron and x-ray powder and single crystal synchrotron diffraction of CsyFe2-xSe2 show the presence of superstructure reflections with propagation vector k=[2/5, 1/5, 1] with respect to the average crystal structure I4/mmm (a = 4, c =…

We report on the synthesis of large single crystals of a new FeSe-layer superconductor Cs0.8(FeSe0.98)2. X-ray powder diffraction, neutron powder-diffraction and magnetization measurements have been used to compare the crystal structure and…

The magnetic order in CaK(Fe[1-x]Ni[x])4As4 (1144) single crystals (x = 0.051 and 0.033) has been studied by neutron diffraction. We observe magnetic Bragg peaks associated to the same propagation vectors as found for the collinear stripe…

In this review, we present a summary of the results on single crystal growth of two types of iron-chalcogenide superconductors, Fe(1+y)Te(1-x)Se(x) (11), and A(x)Fe(2-y)Se(2) (A= K, Rb, Cs, Tl, Tl/K, Tl/Rb), using Bridgman, zone-melting,…

超导电性 · 物理学 2011-10-11 Jinsheng Wen , Guangyong Xu , Genda Gu , J. M. Tranquada , R. J. Birgeneau

The superconducting and magnetic properties of Fe$_{y}$Se$_{0.25}$Te$_{0.75}$ single crystals ($0.9\leq y \leq1.1$) were studied by means of x-ray diffraction, SQUID magnetometry, muon spin rotation, and elastic neutron diffraction. The…

The FeSe superconductor and its related systems have attracted much attention in the iron-based superconductors owing to their simple crystal structure and peculiar electronic and physical properties. The bulk FeSe superconductor has a…

超导电性 · 物理学 2015-06-24 Xu Liu , Lin Zhao , Shaolong He , Junfeng He , Defa Liu , Daixiang Mou , Bing Shen , Yong Hu , Jianwei Huang , X. J. Zhou

The relationship between vacancy ordering and magnetism in TlFe1.6Se2 has been investigated via single crystal neutron diffraction, nuclear forward scattering, and transmission electron microscopy. The examination of chemically and…

With single crystal X-ray diffraction studies, we compare the structures of three sample showing optimal superconductivity, K0.774(4)Fe1.613(2)Se2, K0.738(6)Fe1.631(3)Se2 and Cs0.748(2)Fe1.626(1)Se2. All have an almost identical ordered…

We have synthesized two iron fluo-arsenides $A$Ca$_2$Fe$_4$As$_4$F$_2$ with $A$ = Rb and Cs, analogous to the newly discovered superconductor KCa$_2$Fe$_4$As$_4$F$_2$. The quinary inorganic compounds crystallize in a body-centered…

超导电性 · 物理学 2017-04-05 Zhi-Cheng Wang , Chao-Yang He , Zhang-Tu Tang , Si-Qi Wu , Guang-Han Cao

The magnetic structure of CsCo2Se2 was investigated using single-crystal neutron diffraction technique. An antiferromagnetic transition with the propagation vector (0,0,1) was observed at T_N = 78 K. The Co magnetic moment 0.772(6) {\mu}_B…

强关联电子 · 物理学 2018-11-02 Juanjuan Liu , Jieming Sheng , Wei Luo , Jinchen Wang , Bao Wei , Jinhu Yang , Minghu Fang , S. A. Danilkin
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