相关论文: Atoms can be divided into three categories: polar,…
We propose a simple three-body model of an atom in which one electron on a circular Rydberg orbit is treated as an independent particle and the remaining core electrons are collectively described as a single object. Within this model we…
The properties of the electronic ground state of the polar and paramagnetic europium-$S$-state-atom molecules have been investigated. Ab initio techniques have been applied to compute the potential energy curves for the…
The two-dimensional hydrogen-like atom in a constant magnetic field is considered. It is found that this is actually two separate problems. One for which the magnetic field causes an effective attraction between the nucleus and the electron…
We propose a method for entangling a system of two-level atoms in photonic crystals. The atoms are assumed to move in void regions of a photonic crystal. The interaction between the atoms is mediated either via a defect mode or via resonant…
For a bound state internal wave function respecting parity symmetry, it can be rigorously argued that the mean electric dipole moment must be strictly zero. Thus, both the neutron, viewed as a bound state of three quarks, and the water…
The electric dipole moments (EDMs) of neutron-odd nuclei with even protons are systematically evaluated. We first derive the relation between the EDM and the magnetic moment operators by making use of the core polarization scheme. This…
Quantum mechanics thinks that all atoms do not have permanent electric dipole moment (EDM) because of their spherical symmetry. Therefore, there is no polar atom in nature except for polar molecules. The electric susceptibility Xe caused by…
We theoretically investigate the properties of highly polar diatomic molecules containing $^2S$-state transition-metal atoms. We calculate potential energy curves, permanent electric dipole moments, spectroscopic constants, and leading…
We describe a new mechanism of decoherence in excited atoms as a result of thermal particles scattering by the atomic nucleus. It is based on the idea that a single scattering will produce a sudden displacement of the nucleus, which will be…
The hydrogen atom theory is developed for the de Sitter and anti de Sitter spaces on the basis of the Klein-Gordon-Fock wave equation in static coordinates. In both models, after separation of the variables, the problem is reduced to the…
Based on thermodynamic integration we introduce atoms in molecules (AIM) using the orbital-free framework of alchemical perturbation density functional theory (APDFT). Within APDFT, atomic energies and electron densities in molecules are…
The interplay between electron correlation and nuclear quantum effects makes our understanding of elemental hydrogen a formidable challenge. Here, we present the phase diagram of hydrogen and deuterium at low temperatures and high-pressure…
A review with 106 references of the recent advances in understanding the structure, dynamics, and photodynamics of solvated electrons in polar liquids (and, to some degree, clusters): water, alcohols, ammonia, ethers. Both the orthodox…
The formation of a Pd atomic chain in a hydrogen atmosphere was investigated by measurements of conductance and vibrational spectroscopy of a single molecular junction, and the theoretical calculation. While atomic chains were not formed…
In molecules like hydrogen, most chemical bonds are formed by sharing two electrons from each atom in the bonding molecular orbital (two-center-two-electron (2c2e) bonding). There are, however, different kinds of chemical bonding. The I3-…
Searches for the permanent electric dipole moments (EDMs) of molecules, atoms, nucleons and nuclei provide powerful probes of CP violation both within and beyond the Standard Model (BSM). The interpretation of experimental EDM limits…
The observed baryon asymmetry of the universe (BAU) cannot be explained by the known sources of charge-parity (CP)-violation in the Standard Model (SM). A non-zero permanent electric-dipole-moment (EDM) for fundamental particles, nuclei or…
The first three electronically excited states in the alkaline-earth-metal atoms magnesium, calcium, and strontium comprise the (nsnp) triplet P^o_J (J=0,1,2) fine-structure manifold. All three states are metastable and are of interest for…
We study the hydrogen atom eigenstate energy and wave function in the Rindler space. The probability distribution is tilted because the electric field of the nucleus is no longer spherically symmetric. The hydrogen atom therefore cannot be…
We introduce four new molecules -- YbRb, YbCs, YbSr$^+$, and YbBa$^+$ -- that may prove fruitful in experimental searches for the electric dipole moment (EDM) of the electron. These molecules can, in principle, be prepared at extremely low…