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A new iron pnictide LiFeP superconductor was found. The compound crystallizes into a Cu2Sb structure containing an FeP layer showing superconductivity with maximum Tc of 6K. This is the first 111 type iron pnictide superconductor containing…

超导电性 · 物理学 2015-05-14 Z. Deng , X. C. Wang , Q. Q. Liu , S. J. Zhang , Y. X. Lv , J. L. Zhu , R. C. Yu , C. Q. Jin

We present a brief review of the present day situation with studies of high-temperature superconductivity in iron pnictides and chalcogenides. Recent discovery of superconductivity with T_c > 30 K in A_xFe_{2-x/2}Se_2 (A=K,Cs,Tl,...)…

超导电性 · 物理学 2012-08-14 M. V. Sadovskii , E. Z. Kuchinskii , I. A. Nekrasov

We have synthesized CuFeAs, a new iron-pnictide compound with a layered tetragonal Cu2Sb type structure (space group P4/nmm: a = b = 3.7442(2) {\AA} and c = 5.8925(4) {\AA}) that is identical to that of 111-type iron-based superconductors.…

超导电性 · 物理学 2015-09-07 Gohil S Thakur , Zeba Haque , L C Gupta , A K Ganguli

The recent discovery of superconductivity in the iron-based layered pnictides with T_c ranging between 26 and 56K generated enormous interest in the physics of these materials. Here, we review some of the peculiarities of the…

In the studies of iron-pnictides, a key question is whether their bad-metal state from which the superconductivity emerges lies in close proximity with a magnetically ordered insulating phase. Recently it was found that at low temperatures,…

From first principles calculations we unravel surprisingly strong interactions between arsenic ions in iron-pnictides, the strength of which is controlled by the Fe-spin state. Reducing the Fe-magnetic moment, weakens the Fe-As bonding, and…

超导电性 · 物理学 2009-02-19 T. Yildirim

Once again the condensed matter world has been surprised by the discovery of yet another class of high temperature superconductors. The discovery of iron-pnictide (FeAs) and chalcogenide (FeSe) based superconductors with a $T_c$ of up to 55…

超导电性 · 物理学 2015-05-13 G. A. Sawatzky , I. S. Elfimov , J. van den Brink , J. Zaanen

The first-principles electronic structure calculations made substantial contribution to study of high $T_c$ iron-pnictide superconductors. By the calculations, LaFeAsO was first predicted to be an antiferromagnetic semimetal, and the novel…

材料科学 · 物理学 2017-08-23 Zhong-Yi Lu , Fengjie Ma , Tao Xiang

Structural features of newly found perovskite-based iron pnictide oxide system have been systematically studied. Compared to REFePnO system, perovskite-based system tend to have lower Pn-Fe-Pn angle and higher pnictogen height owing to low…

超导电性 · 物理学 2010-06-14 H. Ogino , S. Sato , Y. Matsumura , N. Kawaguchi , K. Ushiyama , Y. Katsura , S. Horii , K. Kishio , J. Shimoyama

We have synthesized a quaternary fluoroarsenide SrFeAsF with the ZrCuSiAs-type structure (P4/nmm, a = 0.3999 and c = 0.8973 nm), which is composed of an alternately stacked (FeAs)- and (SrF)+ layers, analogous to the FeAs-based…

超导电性 · 物理学 2008-11-10 Satoru Matsuishi , Yasunori Inoue , Takatoshi Nomura , Masahiro Hirano , Hideo Hosono

The superconducting state of iron pnictides and chalcogenides exists at the border of antiferromagnetic order. Consequently, these materials could provide clues about the relationship between magnetism and unconventional superconductivity.…

超导电性 · 物理学 2015-03-19 Rong Yu , Pallab Goswami , Qimiao Si , Predrag Nikolic , Jian-Xin Zhu

A new layered oxypnictide (Fe2P2)(Sr4Sc2O6) have been synthesized by solid-state reaction. This material has an alternating layer stacking structure of anti-fluorite Fe2P2 and perovskite-based Sr4Sc2O6 oxide layers. Space group of the…

超导电性 · 物理学 2009-06-06 H. Ogino , Y. Matsumura , Y. Katsura , K. Ushiyama , S. Horii , K. Kishio , J. Shimoyama

Superconductivity in a novel class of layered materials, Ti-based pnictide oxides, was recently discovered. These compounds have attracted interest since they combine features of copper oxide and iron pnictide superconductors. Here the…

超导电性 · 物理学 2014-06-10 Bernd Lorenz , Arnold M. Guloy , Paul C. W. Chu

One of the unifying concepts in the iron-pnictide superconductors, both for the mechanism of magnetic ordering and of unconventional order parameter character, has been the electron and hole Fermi surfaces that are approximately nested.…

超导电性 · 物理学 2010-04-05 K. -W. Lee , W. E. Pickett

A new layered iron arsenide NaFeAs isostructural with the superconducting lithium analogue, displays evidence for the coexistence of superconductivity and magnetic ordering.

Structure and composition of iron chalcogenides have a delicate relationship with magnetism and superconductivity. In this report we investigate the iron sulfide layered tetragonal phase (t-FeS), and compare with three-dimensional hexagonal…

The response of the worldwide scientific community to the discovery in 2008 of superconductivity at Tc = 26 K in the Fe-based compound LaFeAsO_{1-x}F_x has been very enthusiastic. In short order, other Fe-based superconductors with the same…

超导电性 · 物理学 2015-03-17 David C. Johnston

The magnetic and structural properties of the recently discovered pnictogen/chalcogen-free superconductor LaFeSiH ($T_c\simeq10$~K) have been investigated by $^{57}$Fe synchrotron M{\"o}ssbauer source (SMS) spectroscopy, x-ray and neutron…

Electrical-resistivity and magnetic-susceptibility measurements under hydrostatic pressure up to p = 2.75 GPa have been performed on superconducting LiFeP. A broad superconducting (SC) region exists in the temperature - pressure (T-p) phase…

超导电性 · 物理学 2010-07-14 K. Mydeen , E. Lengyel , Z. Deng , X. C. Wang , C. Q. Jin , M. Nicklas

We report superconductivity in the novel 112-type iron-based compound Ca1-xLaxFeAs2. Single-crystal X-ray diffraction analysis revealed that the compound crystallizes in a monoclinic structure (space group P21), in which Fe2As2 layers…

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