相关论文: Astronomical identification of CN-, the smallest o…

For decades astronomers and astrophysicists believed that only positively charged ions were worthy of relevance in drawing the networks for possible chemical reactions in the interstellar medium, as well as in modeling the physical…

Astronomical evolution mechanism of small size polycyclic aromatic hydrocarbon (PAH) was analyzed using the first principles quantum-chemical calculation. Starting model molecule was benzene (C6H6), which would be transformed to (C5H5) due…

We report on the first detection of C3N- and C5N- towards the cold dark core TMC-1 in the Taurus region, using the Yebes 40 m telescope. The observed C3N/C3N- and C5N/C5N- abundance ratios are 140 and 2, respectively; that is similar to…

We analyze the quantum-mechanical rotational excitation/de-excitation spectrum and cross sections of CN molecules during low and high-energy collisions with protons, H+. The problem is of significant importance in astrophysics of the early…

We present the results of a search for the negative ion C4H- in various dark clouds, low mass star-forming regions and photon-dominated regions (PDRs). We have also searched for C6H-, C2H- and CN- in some of the sources. The millimeter-wave…

Using data from the GOTHAM (GBT Observations of TMC-1: Hunting for Aromatic Molecules) survey, we report the first astronomical detection of the C10H- anion. The astronomical observations also provided the necessary data to refine the…

A first-principle theoretical approach to study the process of radiative electron attachment is developed and applied to the negative molecular ions CN$^-$, C$_4$H$^-$, and C$_2$H$^-$. Among these anions, the first two have already been…

The studies of the complex organic molecular lines towards the hot molecular cores at millimeter and submillimeter wavelengths provide instructive knowledge about the chemical complexity in the interstellar medium (ISM). We present the…

We report new observations of molecular anions with the Yebes 40m and IRAM 30m telescopes toward the cold dense clouds TMC-1 CP, Lupus-1A, L1527, L483, L1495B, and L1544. We detected for the first time C3N- and C5N- in Lupus-1A and C4H- and…

Cyanogen (NCCN) is the simplest member of the dicyanopolyynes group, and has been proposed as a major source of the CN radical observed in cometary atmospheres. Although not detected through its rotational spectrum in the cold interstellar…

The C-star envelope IRC+10216 harbors a rich variety of molecules, with more than 80 detected to date. During the course of a $\lambda$ 3 mm survey of IRC+10216 carried out with the IRAM 30-m telescope we have detected various weak lines,…

The amide-related molecules are essential for the formation of the other complex bio-molecules and an understanding of the prebiotic chemistry in the interstellar medium (ISM). We presented the first detection of the rotational emission…

We present high angular resolution ($\sim$ 3$''$) and sensitive 1.3 mm continuum, cyanogen (CN) and vinyl cyanide (C$_2$H$_3$CN) line observations made with the Submillimeter Array (SMA) toward one of most highly obscured objects of the W51…

Observations with Cassini's Electron Spectrometer discovered negative ions in Titan's ionosphere, at altitudes between 1400 and 950 km. Within the broad mass distribution extending up to several thousand amu, two distinct peaks were…

We report the first detection in the interstellar medium of $N$-cyanomethanimine (H$_2$CNCN), the stable dimer of HCN of highest energy, and the most complex organic molecule identified in space containing the prebiotically relevant NCN…

The cyano radical (CN), one of the first detected interstellar molecular species, is a key molecule in many astrochemical chains. Particularly, it is detected towards molecular cores, the birth places of the stars, and it is known that it…

Cassini discovered a plethora of neutral and ionised molecules in Titan's ionosphere including, surprisingly, anions and negatively charged molecules extending up to 13,800 u/q. In this letter we forward model the Cassini electron…

Reactions occurring on the ice-covered surfaces of interstellar dust grains are considered to be among the most important sources of complex species in the interstellar medium. Despite this, molecules such as cyanamide, NH2CN, are largely…

Detecting anions in space has relied on a strong collaboration between theoretical and laboratory analyses to measure rotational spectra and spectroscopic constants to high accuracy. The advent of improved quantum chemical tools operating…

Fragments of small solar system bodies entering Earth's atmosphere have possibly been important contributors of organic compounds to the early Earth. The cyano radical (CN) emission from meteors is considered as potentially one of the most…