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The detection of high gas-phase abundances of SO2 and SO in the cold envelope of an intermediate mass protostar suggests that these molecules might form on icy dust grains and subsequently desorb to the gas phase by non-thermal desorption…

CO2 ice is one of the most abundant components in ice-coated interstellar ices besides H2O and CO, but the most favorable path to CO2 ice is still unclear. Molecular dynamics calculations on the ultraviolet photodissociation of different…

化学物理 · 物理学 2015-06-17 Carina Arasa , Marc C. van Hemert , Ewine F. van Dishoeck , Geert-Jan Kroes

Nonthermal desorption of molecules from icy grain surfaces is required to explain molecular line observations in the cold gas of star-forming regions. Chemical desorption is one of the nonthermal desorption processes and is driven by the…

星系天体物理 · 物理学 2022-03-02 Kenji Furuya , Yasuhiro Oba , Takashi Shimonishi

The morphology of water ice in the interstellar medium is still an open question. Although accretion of gaseous water could not be the only possible origin of the observed icy mantles covering dust grains in cold molecular clouds, it is…

Photodissociation is the dominant removal process of molecules in any region exposed to intense ultraviolet (UV) radiation. This includes diffuse and translucent interstellar clouds, dense photon-dominated regions, high velocity shocks, the…

天体物理仪器与方法 · 物理学 2015-02-10 Ewine F. van Dishoeck , Ruud Visser

Desorption of H2O films ranging from 53 nanometres to 101 micrometre thicknesses have been investigated using a quartz-crystal microbalance (QCM) and temperature-programmed desorption. Three desorption stages are observed belonging to…

材料科学 · 物理学 2022-10-12 A. Rosu-Finsen , B. Chikani , C. G. Salzmann

The interactions of atomic and molecular hydrogen with bare interstellar dust grain surfaces are important for understanding H2 formation at relatively high temperatures (>20 K). We investigate the diffusion of physisorbed H atoms and the…

星系天体物理 · 物理学 2019-11-14 Masashi Tsuge , Tetsuya Hama , Yuki Kimura , Akira Kouchi , Naoki Watanabe

Dynamics of adsorption and desorption of (4S)-N on amorphous solid water are analyzed using molecular dynamics simulations. The underlying potential energy surface was provided by machine-learned interatomic potentials. Binding energies…

星系天体物理 · 物理学 2020-09-22 Germán Molpeceres , Viktor Zaverkin , Johannes Kästner

Ultraviolet photodesorption of molecules from icy interstellar grains can explain observations of cold gas in regions where thermal desorption is negligible. This non-thermal desorption mechanism should be especially important where UV…

Solid O2 has been proposed as a possible reservoir for oxygen in dense clouds through freeze-out processes. The aim of this work is to characterize quantitatively the physical processes that are involved in the desorption kinetics of CO-O2…

天体物理学 · 物理学 2009-11-13 K. Acharyya , G. W. Fuchs , H. J. Fraser , E. F. van Dishoeck , H. Linnartz

The study of the formation of molecular hydrogen on low temperature surfaces is of interest both because it allows to explore elementary steps in the heterogeneous catalysis of a simple molecule and because of the applications in…

化学物理 · 物理学 2008-11-21 G. Vidali , V. Pirronello , L. Li , J. Roser , G. Manico , R. Mehl , A. Lederhendler , H. B. Perets , J. R. Brucato , O. Biham

We model the temperature and chemical structure of molecular clouds as a function of depth into the cloud, assuming a cloud of constant density n illuminated by an external FUV (6 eV < E < 13.6 eV) flux G_0 (scaling factor in multiples of…

天体物理学 · 物理学 2011-02-11 David Hollenbach , Michael J. Kaufman , Edwin A. Bergin , Gary J. Melnick

In regions where stars form, variations in density and temperature can cause gas to freeze-out onto dust grains forming ice mantles, which influences the chemical composition of a cloud. The aim of this paper is to understand in detail the…

太阳与恒星天体物理 · 物理学 2017-11-08 S. Cazaux , R. Martin-Domenech , Y. J. Chen , G. M. Munoz Caro , C. Gonzalez Diaz

We present the modeling results of deuterium fractionation of water ice, H2, and the primary deuterium isotopologues of H3+ adopting physical conditions associated with the star and planet formation process. We calculated the deuterium…

星系天体物理 · 物理学 2015-06-23 Jeong-Eun Lee , Edwin A. Bergin

Non-thermal desorption of inter- and circum-stellar ice mantles on dust grains, in particular ultraviolet photon-induced desorption, has gained importance in recent years. These processes may account for the observed gas phase abundances of…

星系天体物理 · 物理学 2019-05-08 C González Díaz , H Carrascosa de Lucas , S Aparicio , G M Muñoz Caro , N-E Sie , L-C Hsiao , Y-J Chen

Molecular clouds are the cold regions of the Milky Way where stars form. They are enriched by rather complex molecules. Many of these molecules are believed to be synthesized on the icy surfaces of the interstellar submicron-sized dust…

CO$_2$ is a major component of the icy mantles surrounding dust grains in planet and star formation regions. Understanding its photodesorption is crucial for explaining gas phase abundances in the coldest environments of the interstellar…

Non-thermal desorption from icy grains containing H$_2$CO has been invoked to explain the observed H$_2$CO gas phase abundances in ProtoPlanetary Disks (PPDs) and Photon Dominated Regions (PDRs). Photodesorption is thought to play a key…

We study the photo-desorption occurring in H$_2$O:CO:NH$_3$ ice mixtures irradiated with monochromatic (550 and 900 eV) and broad band (250--1250 eV) soft X-rays generated at the National Synchrotron Radiation Research Center (Hsinchu,…

Understanding the history and evolution of small bodies, such as dust grains and comets, in planet-forming disks is very important to reveal the architectural laws responsible for the creation of planetary systems. These small bodies in…

星系天体物理 · 物理学 2018-10-10 Alexey Potapov , Cornelia Jäger , Thomas Henning