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Charge transport in crystalline organic semiconductors is intrinsically limited by the presence of large thermal molecular motions, which are a direct consequence of the weak van der Waals inter-molecular interactions. These lead to an…

材料科学 · 物理学 2018-06-18 S. Fratini , D. Mayou , S. Ciuchi

Charge transport in organic semiconductors is notoriously extremely sensitive to the presence of disorder, both internal and external (i.e. related to the interactions with the dielectric layer), especially for n-type materials. Internal…

Charge transport in organic semiconductors is notoriously extremely sensitive to the presence of disorder, both intrinsic and extrinsic, especially for n-type materials. Intrinsic dynamic disorder stems from large thermal fluctuations both…

Bloch-Boltzmann transport theory fails to describe the carrier diffusion in current crystalline organic semiconductors, where the presence of large-amplitude thermal molecular motions causes substantial dynamical disorder. The charge…

材料科学 · 物理学 2020-01-08 S. Fratini , S. Ciuchi

We have investigated the charge carrier transport in organic molecular semiconductors. It has been found that mobility is a function of electric field and temperature due to hopping conduction. Several theoretical models for charge…

材料科学 · 物理学 2007-05-23 Ajit Kumar Mahapatro , Subhasis Ghosh

We explore the charge transport mechanism in organic semiconductors based on a model that accounts for the thermal intermolecular disorder at work in pure crystalline compounds, as well as extrinsic sources of disorder that are present in…

材料科学 · 物理学 2012-12-10 S. Ciuchi , S. Fratini

One of the basic assumptions in organic field-effect transistors, the most fundamental device unit in organic electronics, is that charge transport occurs two-dimensionally in the first few molecular layers near the dielectric interface.…

Electron coupling to intra- and inter-molecular vibrational modes is investigated in models appropriate to single crystal organic semiconductors, such as oligoacenes. Focus is on spectral and transport properties of these systems beyond…

强关联电子 · 物理学 2015-05-28 C. A. Perroni , V. Marigliano Ramaglia , V. Cataudella

We present a model of charge transport in organic molecular semiconductors based on the effects of lattice fluctuations on the quantum coherence of the electronic state of the charge carrier. Thermal intermolecular phonons and librations…

其他凝聚态物理 · 物理学 2009-11-11 J. -D. Picon , M. N. Bussac , L. Zuppiroli

The charge transport in some organic semiconductors demonstrates nonlinear properties and further universal power-law scaling with both bias and temperature. The physical origin of this behavior is investigated here using variable range…

介观与纳米尺度物理 · 物理学 2014-12-16 Ling Li , Nianduan Lu , Ming Liu

We analyze the quantum transport properties of MAPbI3 within a tight-binding model. Charge carriers are strongly scattered by the Fr\"ohlich interaction with longitudinal optical phonon modes. This limits their mobilities at room…

The charge carrier transport in metal phthallocyanine based disordered thin films has been investigated. Charge carrier mobility in these disordered thin films strongly depends on the electric field and temperature due to hopping…

无序系统与神经网络 · 物理学 2015-06-25 Ajit Kumar Mahapatro , Subhasis Ghosh

We study the model of a molecular switch comprised of a molecule with a soft vibrational degree of freedom coupled to metallic leads. In the presence of strong electron-ion interaction, different charge states of the molecule correspond to…

介观与纳米尺度物理 · 物理学 2008-12-18 Fabio Pistolesi , Yaroslav M. Blanter , Ivar Martin

The nonlocal electron-phonon couplings in organic semiconductors responsible for the fluctuation of intermolecular transfer integrals has been the center of interest recently. Several irreconcilable scenarios coexist for the description of…

材料科学 · 物理学 2021-08-04 Weitang Li , Jiajun Ren , Zhigang Shuai

General properties of the transport of charge carriers (electrons and holes) in disordered organic materials are discussed. It was demonstrated that the dominant part of the total energetic disorder in organic material is usually provided…

材料科学 · 物理学 2013-03-20 S. V. Novikov

In a one dimensional lattice thermal fluctuations destroy the long-range order making particles of the lattice move on a scale much larger than the lattice spacing. We discuss the assumption that this motion may be responsible for the…

软凝聚态物质 · 物理学 2015-05-13 A. V. Plyukhin

We use first-principle Quantum Monte-Carlo (QMC) simulations and numerical exact diagonalization to analyze the low-frequency charge carrier mobility within a simple tight-binding model of molecular organic semiconductors on a…

材料科学 · 物理学 2025-07-23 Pavel Buividovich , Johann Ostmeyer , Alessandro Troisi

General properties of the hopping transport of charge carriers in amorphous organic and inorganic materials are discussed. We consider the case where the random energy landscape in the materials is strongly spatially correlated. This is a…

材料科学 · 物理学 2020-02-24 S. V. Novikov

In many organic molecules the strong coupling of excess charges to vibrational modes leads to the formation of polarons, i.e., a localized state of a charge carrier and a molecular deformation. Incoherent hopping of polarons along the…

介观与纳米尺度物理 · 物理学 2015-05-13 Benjamin B. Schmidt , Matthias H. Hettler , Gerd Schön

There is compelling evidence that charge carriers in organic semiconductors (OSs) self-localize in nano-scale space because of dynamic disorder. Yet, some OSs, in particular recently emerged high-mobility organic molecular crystals, feature…

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