相关论文: Observation of the Accelerated Diffusion in Nanopa…
Using Raman scattering, the solid solution nanoparticles of paradibrombenzol/paradihlorbenzol are investigated. It is found that in a spectrum of nanoparticles of solid solution frequencies of spectral lines are reduced in comparison with…
We measured the small frequencies Raman spectrum of the paradihlorobenzene and paradihlorobenzene solid solution nanoparticles with the size about 100 nanometers. Values of frequencies of lines decrease. The size of nanoparticles was…
We have obtained experimentally the low frequency Raman spectra of p-dihlorbenzol nanoparticles. Nanoparticle sizes are determined with the help of electron microscope. It was found that in the lattice vibration spectra from 70 nm the…
Influence of decrease of the sizes of crystallites of para-dichlorbenzol on Raman spectrums is studied. Lattice oscillations frequencies are calculated. On this basis the modification of lattice parameters for particles smaller than 5$\mu $…
Using a method of a Raman effect of light the heterodiffusion in molecular crystals is investigated by the example of p-dichlorobenzene in a p-dibromobenzene. The installation diagram and a procedure of a determination of diffusivities…
Allocation of molecules of para-dichlorbenzol in equimolar single crystals of para-dichlorbenzol with p-dibromobenzene solid solutions grown by the Bridgmen's method is studied. It is shown, that the mutual concentration of builders…
Raman spectrums of nanoparticles of a p-dibromobenzene with size of 300 nanometers and 50 nanometers are measured. It is found that frequencies of lines of stretching vibrations of C-Br at reduction of the sizes of nanoparticles below 300…
We measured low-frequency Raman spectra of paradibromobenzene nanoparticles. With the reduction of the nanoparticles size frequencies of lines become smaller and the doubling of the most intensive lines takes place. Additional lines with…
We have measured spectra of lattice fluctuations in p-dihlorbenzol nanoparticles of ~300nm size. Calculations of lattice frequencies and of these fluctuations in nanoparticles are done. It is shown that with reduction of nanoparticles sizes…
Distribution of centrosymmetrical molecules of an impurity (p-diclorobenzene) in monocrystals of solid solutions in two different matrixes with centrosymmetrical (p-dibrombenzene) and noncentrosymmetrical (p-bromchlorbenzene) molecules by…
We perform molecular dynamic simulations of liquid nanoparticles deposited on a disordered substrate. The motion of the nanoparticle is characterised by a 'stick and roll' diffusive process. Long simulation times ($\simeq \mu s$), analysis…
Investigation of organic molecular films by a method Raman of a spectroscopy is carried out. It is shown, that values of frequencies of lines in a spectrum of the lattice oscillations of the molecular films are depressed in comparison with…
We discuss the diffusion phenomenon in the parabolic and hyperbolic regimes. New effects related to the finite velocity of the diffusion process are predicted, that can partially explain the strange behavior associated to adsorption…
Diffusive shock acceleration (DSA) by relativistic shocks is thought to generate the $dN/dE\propto E^{-p}$ spectra of charged particles in various astronomical relativistic flows. We show that for test particles in one dimension (1D),…
Calculations of frequencies of the lattice and surface oscillations of organic nano-crystals are carried out. As the sample the para-dichlorobenzol has been chosen. Change of spectra of oscillations from the sizes of nano-particles is…
Laser fragmentation of Al nanoparticles in liquid isopropanol is experimentally studied. Nanoparticles are characterized by Transmission Electron Microscopy and measuring disk centrifuge. As the result, the size of Al nanoparticles is…
The mixed crystal of a para-dibromobenzene with a para-chloronitrobenzene is investigated at concentration of components from 0% up to 60% of a para-chloronitrobenzene by the method of Low-Frequency Raman spectroscopy. It is shown, that in…
This article presents a numerical simulation of solvent diffusion in transition metal dichalcogenide based nanomaterials during solvothermal reaction, leading to layer exfoliation and, consequently, a reduction in the average nanoparticle…
Raman spectroscopies are carried out by the Method polarizable examinations of the lattice oscillations of p-chloronitrobenzene at temperature 293 K. The led matching of spectrums of p-chloronitrobenzene with p-bromochlorobenzene and…
The experiment was conducted to synthesize carbon nanospheres of different sizes by controlling the temperature in polycondensation reaction of glucose under hydrothermal process. The surface morphology, structural, optical, and thermal…