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We present the magnetic properties of three recently synthesized binuclear molecular complexes [NiNd], [NiGd] and [ZnGd] investigated by dc magnetization and proton nuclear magnetic resonance (NMR) measurements. The high-temperature…

介观与纳米尺度物理 · 物理学 2011-12-01 P. Khuntia , M. Mariani , A. V. Mahajan , A. Lascialfari , F. Borsa , T. D. Pasatoiu , M. Andruh

We present a joint experimental and theoretical characterization of the magnetic properties of coordination clusters with an antiferromagnetic core of four magnetic ions. Two different compounds are analyzed, with Co and Mn ions in the…

化学物理 · 物理学 2021-09-16 Simona Achilli , Claire Besson , Xu He , Pablo Ordejòn , Carola Meyer , Zeila Zanolli

The organometallic ring molecules Fe_6 and Fe_10 are leading examples of a class of nanoscopic molecular magnets, which have been of intense recent interest both for their intrinsic magnetic properties and as candidates for the observation…

介观与纳米尺度物理 · 物理学 2009-10-31 B. Normand , X. Wang , X. Zotos , Daniel Loss

The understanding of coercivity mechanism in high performance Nd-Fe-B permanent magnets relies on the analysis of the magnetic properties of all phases present in the magnets. By adding Cu in such compounds, a new Nd6Fe13Cu grain boundary…

We report the structural, magnetic and thermodynamic properties of the double perovskite compound La2CuIrO6 from X-ray, neutron diffraction, neutron depolarization, dc magnetization, ac susceptibility, specific heat, muon-spin-relaxation…

We have investigated the magnetic properties of carbon powders which consist of nanodisks, nanocones, and a small fraction of carbon-black particles. Magnetization measurements were carried out using a superconducting quantum interference…

介观与纳米尺度物理 · 物理学 2015-06-04 Jozef Cernak , Geir Helgesen , Jozef Kovac , Arne T. Skjeltorp , Josef Voltr

Magnetic excitations in a weakly coupled spin dimers and chains compound Cu2Fe2Ge4O13 are measured by inelastic neutron scattering. Both structure factors and dispersion of low energy excitations up to 10 meV energy transfer are well…

强关联电子 · 物理学 2009-11-11 T. Masuda , A. Zheludev , B. Sales , S. Imai , K. Uchinokura , S. Park

High-field electron paramagnetic resonance (HFEPR) spectra were collected at several frequencies for single crystal [Zn3.91Ni0.09(hmp)4(dmb)4Cl4] (1), where dmb is 3,3-dimethyl-1-butanol and hmp is the monoanion of 2-hydroxymethylpyridine.…

介观与纳米尺度物理 · 物理学 2007-05-23 En-Che Yang , Cem Kirman , Jon Lawrence , Lev N. Zakharov , Arnold L. Rheingold , Stephen Hill , David N. Hendrickson

We have studied the magnetic properties of Ba_2FeNbO_6 and Ba_2MnNbO_6. it is seen that Ba_2FeNbO_6 is an antiferromagnet with a weak ferromagnetic behaviour at 5K while Ba_2MnNbO_6 shows two magnetic transitions one at 45 K and the other…

The synthesis of molecular magnets has undergone rapid progress in recent years. Each of the identical molecular units can contain as few as two and up to several dozens of paramagnetic ions (spins). Although these materials appear as…

强关联电子 · 物理学 2009-11-11 J. Schnack

Nuclear magnetic resonance (NMR) and nuclear quadrupole resonance (NQR) of Cu have been measured in a coupled spin dimers and chains compound Cu2Fe2Ge4O13. Cu NQR has also been measured in an isostructural material Cu2Sc2Ge4O13 including…

强关联电子 · 物理学 2013-02-19 Jun Kikuchi , Shiro Nagura , Kazumasa Murakami , Takatsugu Masuda , Guenther J. Redhammer

We investigate the structural and magnetic properties of the new quantum magnet BaCuTe$_2$O$_6$. This compound is synthesized for the first time in powder and single crystal form. Synchrotron X-ray and neutron diffraction reveal a cubic…

Magnetism of a very thin antiferromagnetic (AFM) surface CuO has been investigated with the partially oxidized nanocomposites of Cu-CuCl, ~ 200 nm. The samples are characterized by X-ray diffraction, X-ray photoelectron spectroscopy,…

材料科学 · 物理学 2009-11-11 Qi Li , Shi-Wei Zhang , Yan Zhang , Chinping Chen

The magnetism of double perovskites is a complex phenomenon, determined from intra- or interatomic magnetic moment interactions, and strongly influenced by geometry. We take advantage of the complementary length and time scales of the muon…

We investigate the magnetic properties of a range of low-dimensional ferromagnets using a combination of first-principles calculations and atomistic spin dynamics simulations. This approach allows us to evaluate the ground state and finite…

材料科学 · 物理学 2016-11-26 Lars Bergqvist , Andrea Taroni , Anders Bergman , Corina Etz , Olle Eriksson

We report the results of magnetic susceptibility $\chi$ and $^1$H nuclear magnetic resonance (NMR) measurements on a three-dimensional hyper-honeycomb lattice compound [(C$_2$H$_5$)$_3$NH]$_2$Cu$_2$(C$_2$O$_4$)$_3$ (CCCO). The average value…

57Fe Mossbauer spectroscopy measurements were performed on a powdered CuFe2Ge2 sample that orders antiferromagnetically at ~ 175 K. Whereas a paramagnetic doublet was observed above the Neel temperature, a superposition of paramagnetic…

材料科学 · 物理学 2018-03-14 Sergey L. Bud'ko , Na Hyun Jo , Savannah S. Downing , Paul C. Canfield

We report on a 59Co NMR investigation of the trigonal cobaltate Ca3Co2O6 carried out on a single crystal, providing precise determinations of the electric field gradient and chemical shift tensors, and of the internal magnetic fields at the…

强关联电子 · 物理学 2015-05-20 G. Allodi , R. De Renzi , S. Agrestini , C. Mazzoli , M. R. Lees

Sr$_2$CuTeO$_6$ presents an opportunity for exploring low-dimensional magnetism on a square lattice of $S=1/2$ Cu$^{2+}$ ions. We employ ab initio multi-reference configuration interaction calculations to unravel the Cu$^{2+}$ electronic…

Fine powders of micron- and submicron-sized particles of undoped Cu2O semiconductor, with three different sizes and morphologies have been synthesized by different chemical processes. These samples include nanospheres 200 nm in diameter,…

材料科学 · 物理学 2010-05-11 Chinping Chen , Lin He , Lin Lai , Hua Zhang , Jing Lu , Lin Guo , Yadong Li
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