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We study the exchange interactions and resulting magnetic phases in the honeycomb cobaltates. For a broad range of trigonal crystal fields acting on Co2+ ions, the low-energy pseudospin-1/2 Hamiltonian is dominated by bond-dependent Ising…

强关联电子 · 物理学 2020-07-23 Huimei Liu , Jiri Chaloupka , Giniyat Khaliullin

Due to the dominant Kitaev exchange interactions, the cobaltate, Na$_{3}$Co$_{2}$SbO$_{6}$, has been considered to be approximate to the Kitaev quantum spin liquid (QSL). Here, we investigate both magnetic dilution and chemical pressure…

We report results of 51V NMR experiments on a high-quality powder sample of volborthite Cu3V2O7(OH)2/2H2O, a spin-1/2 Heisenberg antiferromagnet on a distorted kagome lattice. Following the previous experiments in magnetic fields $B$ below…

We study the magnetic susceptibility of mixed-valent La2-xSrxCoO4 single crystals in the doping range of 0.5<= x <= 0.8 for temperatures up to 1000 K. The magnetism below room temperature is described by paramagnetic Co2+ in the high-spin…

强关联电子 · 物理学 2012-04-04 N. Hollmann , M. W. Haverkort , M. Benomar , M. Cwik , M. Braden , T. Lorenz

Using 23Na NMR measurements on sodium cobaltates at intermediate dopings (0.44<=x<=0.62), we establish the qualitative change of behavior of the local magnetic susceptibility at x*=0.63-0.65, from a low x Pauli-like regime to the high x…

强关联电子 · 物理学 2009-11-13 G. Lang , J. Bobroff , H. Alloul , G. Collin , N. Blanchard

The interplay between crystal electric field splitting of d states and Hund's rule exchange energy in cobalt-based perovskites offers a promising avenue for inducing spin-state transitions. This study reports a new body-centered tetragonal…

The honeycomb cobaltate Na$_2$Co$_2$TeO$_6$ has recently been proposed as a candidate material for hosting field-induced quantum spin liquid (QSL) behavior. Here, we present a comprehensive thermodynamic study of its low-temperature,…

Structural, impedance, ferroelectric and magnetic properties were examined in multiferroic Bi_{2}Fe_{4(1-x)}Co_{4x}O_{9} (0$\leq$x$\leq$0.02) ceramics synthesized via solid-state reaction method. X-ray diffraction analysis and Rietveld…

材料科学 · 物理学 2016-05-06 S. R. Mohapatra , B. Sahu , M. Chandrasekhar , P. Kumar , S. D. Kaushik , S. Rath , A. K. Singh

We study theoretically low-temperature phases of a recently synthesized compound Sr$_2$CoO$_3$F under pressure. The analysis combining LDA+DMFT and a strong-coupling effective model points to the existence of not only normal paramagnetic…

强关联电子 · 物理学 2019-05-15 Juan Fernández Afonso , Andrii Sotnikov , Atsushi Hariki , Jan Kuneš

Spin-state ordering - a periodic pattern of ions with different spin-state configurations along a crystal lattice - is a rare phenomenon, and its possible interrelation with other electronic degrees of freedom remains little explored. Here…

强关联电子 · 物理学 2024-03-27 E. Granado , C. W. Galdino , B. D. Moreno , G. King , D. C. Freitas

The magnetic field dependent phase diagram of the ferroelectric material ${\rm Ho}_{1-x}Y_{x}MnO_{3}$ has been investigated for x = 0, 0.6, and 0.8 for fields directed along both the ab in-plane and c-axis basal plane directions. Dielectric…

强关联电子 · 物理学 2009-11-11 R. Vasic , H. Zhou , E. Jobiliong , C. R. Wiebe , J. S. Brooks

The magnetic properties of the double perovskite oxide $Sr_{2}$FeMo$O_{6}$ are analyzed using a mixed-spin Ising model with spins $\left( \frac{1}{2},\frac{5}{2}\right) $ in the presence of a random crystal field $\Delta$ and exchange…

The nanoscopic magneto-electronic phase separation in doped La1-xSrxCoO3 perovskites was studied with local probes. The phase separation is directly observed by M\"ossbauer spectroscopy in the studied doping range of 0.05 <= x <= 0.25 both…

By means of muon spin rotation and relaxation ($\mu^+$SR) techniques, we have investigated the magnetism of quasi one-dimensional (1D) cobalt oxides $AE_{n+2}$Co$_{n+1}$O$_{3n+3}$ ($AE$=Ca, Sr and Ba, $n$=1, 2, 3, 5 and $\infty$), in which…

强关联电子 · 物理学 2009-11-11 J. Sugiyama , H. Nozaki , J. H. Brewer , E. J. Ansaldo , T. Takami , H. Ikuta , U. Mizutani

The magnetic, electric and thermal properties of the ($Ln_{1-y}$Y$_{y}$)$_{0.7}$Ca$_{0.3}$CoO$_3$ perovskites ($Ln$~=~Pr, Nd) were investigated down to very low temperatures. The main attention was given to a peculiar metal-insulator…

强关联电子 · 物理学 2015-05-18 J. Hejtmánek , E. Šantavá , K. Knížek , M. Maryško , Z. Jirák T. Naito , H. Sasaki , H. Fujishiro

$\gamma$-triclinic and $\alpha$-monoclinic polymorphs of CoV$_{2}$O$_{6}$ are two of the few known transition metal ion based materials that display stepped $1/3$ magnetization plateaus at low temperatures. Neutron diffraction [M. Markkula…

We present measurements of the magnetic susceptibility and of the thermal expansion of a LaCoO$_3$ single crystal. Both quantities show a strongly anomalous temperature dependence. Our data are consistently described in terms of a…

强关联电子 · 物理学 2009-11-07 C. Zobel , M. Kriener , D. Bruns , J. Baier , M. Gr"uninger , T. Lorenz , P. Reutler , A. Revcolevschi

A study of the modifications of the magnetic properties of Ho$_{2-x}$Y$_x$Sn$_2$O$_7$ upon varying the concentration of diamagnetic Y$^{3+}$ ions is presented. Magnetization and specific heat measurements show that the Spin Ice ground-state…

强关联电子 · 物理学 2010-11-01 G. Prando , P. Carretta , S. R. Giblin , J. Lago , S. Pin , P. Ghigna

In the scientific description of unconventional transport properties of oxides (spin-dependent transport, superconductivity etc.), the spin-state degree of freedom plays a fundamental role. Because of this, temperature- or magnetic…

材料科学 · 物理学 2014-11-12 M. Rotter , Z. -S. Wang , A. T. Boothroyd , D. Prabhakaran , A. Tanaka , M. Doerr

The structural, magnetic and transport properties of the layered RBaCo$_2$O$_{5.5}$ cobaltites are sensitive to the oxygen stoichiometry. In this present study, we report the presence of a low-temperature magnetic glassy state in…

强关联电子 · 物理学 2020-03-18 Archana Kumari , C. Dhanasekhar , A. K. Das