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The microstructural and morphological properties of homoepitaxial (001)ZnTe layers are investigated by x-ray diffuse scattering. High resolution reciprocal space maps recorded close to the ZnTe (004) Bragg peak show different diffuse…

材料科学 · 物理学 2007-05-23 T. Di Luccio , G. Scalia , L. Tapfer , P. Morales , M. Traversa , P. Prete , N. Lovergine

The temperature and zone dependence of the lattice dynamics in Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_{3}$ is characterized using neutron inelastic scattering. A strong correlation between the diffuse and phonon scattering is measured. The lattice…

材料科学 · 物理学 2009-11-10 C. Stock , H. Luo , D. Viehland , J. F. Li , I. Swainson , R. J. Birgeneau , G. Shirane

Introducing structural and/or chemical heterogeneity into otherwise ordered crystals can dramatically alter material properties. Lead-based relaxor ferroelectrics are a prototypical example, with decades of investigation having connected…

We report neutron scattering measurements of the structural correlations associated with the apparent relaxor transition in K$_{1-x}$Li$_x$TaO$_3$ for $x=0.02$ (KLT(0.02)). This compound displays a broad and frequency-dependent peak in the…

材料科学 · 物理学 2015-05-27 C. Stock , P. M. Gehring , G. Xu , D. Lamago , D. Reznik , M. Russina , J. Wen , L. A. Boatner

We analyze scattering of the transverse optic modes by spherically symmetric Polarized Nano Regions (PNR) in the paraelectric phase of relaxor ferroelectrics. Calculations have done in the frame of mean-field model early supposed by E.Iolin…

材料科学 · 物理学 2015-03-17 Eugene Iolin

Some of (1-x)NaNbO_3-(x)ABO_3 perovskite solid solutions exhibit a dramatic diffusion of the dielectric permittivity epsilon' maximum and relaxor-type behavior when the second component concentration exceeds a threshold value x_0. The…

材料科学 · 物理学 2009-11-07 I. P. Raevski , S. A. Prosandeev

Ferroelectric soft mode in Pb(Mg1/3Nb2/3)O3 (PMN) has been clearly resolved by precision Raman scattering measurements for the first time. A polarization direction of the incident laser was chosen along [110] in cubic configuration in order…

材料科学 · 物理学 2009-09-23 Hiroki Taniguchi , Masanori Oishi , Desheng Fu , Mitsuru Itoh

A ferroelectric monoclinic phase of space group $Cm$ ($M_A$ type) has been discovered in 0.65Pb(Mg$_{1/3}$Nb$_{2/3})O_3$-0.35PbTiO$_3$ by means of high resolution synchrotron X-ray diffraction. It appears at room temperature in a single…

材料科学 · 物理学 2009-11-07 Z. -G. Ye , B. Noheda , M. Dong , D. Cox , G. Shirane

The nature of the cubic-like state in the lead-free piezoelectric ceramics 0.5K0.5Na0.5NbO3-0.5Na0.5Bi0.5TiO3 (KNN-50BNT) has been examined in detail by synchrotron x-ray diffraction (SD), selected area electron diffraction (SAED), neutron…

Extended X-ray absorption fine structure (EXAFS) experiments at the Zr K-edge were carried out on perovskite relaxor ferroelectrics BaTi(1-x)Zr(x)O3 (BTZ) (x = 0.25, 0.30, 0.35), and on BaZrO3 for comparison. Structural information up to…

材料科学 · 物理学 2009-11-11 C. Laulhe , F. Hippert , J. Kreisel , M. Maglione , A. Simon , J. L. Hazemann , V. Nassif

Relaxor behavior and lattice dynamics have been studied for a single crystal of K$_{1-x}$Li$_x$TaO$_3$ $(x=0.05)$, where a small amount of a Ca impurity ($\sim 15$~ppm) was incorporated. The dielectric measurements revealed Debye-like…

材料科学 · 物理学 2009-11-11 S. Wakimoto , G. A. Samara , R. K. Grubbs , E. L. Venturini , L. A. Boatner , G. Xu , G. Shirane , S. -H. Lee

Neutron and x-ray scattering studies on relaxor ferroelectric systems Pb(Zn$_{1/3}$Nb$_{2/3}$)O$_3$ (PZN), Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_3$ (PMN), and their solid solutions with PbTiO$_3$ (PT) have shown that inhomogeneities and disorder play…

材料科学 · 物理学 2015-05-13 Guangyong Xu

We propose a simple and solvable mean-field model of the scattering of transverse optic modes by Polarized Nano Regions (PNR) in the paraelectric phase of relaxor ferroelectrics. The PNR is assumed to be a ferroelectric sphere embedded in…

材料科学 · 物理学 2010-07-22 E. Iolin , J. Toulouse

Recently, a new orthorhombic phase has been discovered in the ferroelectric system Pb(Zn1/3Nb2/3)O3-xPbTiO3 (PZN-xPT) for x= 9%, and for x= 8% after the application of an electric field. In the present work, synchrotron x-ray measurements…

材料科学 · 物理学 2009-11-07 D. La-Orauttapong , B. Noheda , Z. -G. Ye , P. M. Gehring , J. Toulouse , D. E. Cox , G. Shirane

Synchrotron x-ray powder diffraction measurements have been performed on unpoled ceramic samples of (1-x)PbMg(1/3)Nb(2/3)O3-xPbTiO3 (PMN-xPT) with 30%<= x<= 39% as a function of temperature around the morphotropic phase boundary (MPB),…

材料科学 · 物理学 2009-11-07 B. Noheda , D. E. Cox , G. Shirane , Z. -G. Ye , J. Gao

The short range ordered magnetic correlations have been studied in half doped La0.5Ca0.5-xSrxMnO3 (x = 0.1, 0.3 and 0.4) compounds by polarized neutron scattering technique. On doping Sr2+ for Ca2+ ion, these compounds with x = 0.1, 0.3,…

材料科学 · 物理学 2015-05-18 I. Dhiman , A. Das , R. Mittal , Y. Su , A. Kumar , A. Radulescu

The resonant scattering and diffraction beamline P09 at PETRA III is designed for X-ray experiments requiring small beams, energy tunability, variable polarization and high photon flux. It is highly flexible in terms of beam size and offers…

仪器与探测器 · 物理学 2014-06-09 J. Strempfer , S. Francoual , D. Reuther , D. K. Shukla , A. Skaugen , H. Schulte-Schrepping , T. Kracht , H. Franz

The origin of ultrahigh piezoelectricity in the relaxor ferroelectric PbZn1/3Nb2/3O3-PbTiO3 was studied with an electric field applied along the [001] direction. The zero-field rhombohedral R phase starts to follow the direct polarization…

材料科学 · 物理学 2009-10-31 B. Noheda , D. E. Cox , G. Shirane , S-E. Park , L. E. Cross , Z. Zhong

Spatial variability of polarization relaxation kinetics in relaxor ferroelectric 0.9Pb(Mg1/3Nb2/3)O3-0.1PbTiO3 is studied using time-resolved Piezoresponse Force Microscopy. Local relaxation attributed to the reorientation of polar…

材料科学 · 物理学 2013-05-29 S. V. Kalinin , B. J. Rodriguez , J. D. Budai , S. Jesse , A. N. Morozovska , A. A. Bokov , Z. -G. Ye

The microstructure and phase transition in relaxor ferroelectric Pb(Mg1/3Nb2/3)O3 (PMN) and its solid solution with PbTiO3 (PT), PMN-xPT, remain to be one of the most puzzling issues of solid state science. In the present work we have…

材料科学 · 物理学 2009-11-07 Z. -G. Ye , Y. Bing , J. Gao , A. A. Bokov , P. Stephens , B. Noheda , G. Shirane