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相关论文: Infrared study of the phonon modes in PrMnO$_3$ an…

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We report on near normal far- and mid-infrared emission and reflectivity of NdMnO3 perovskite from room temperature to sample decomposition above 1800 K. At 300 K the number infrared active phonons is in close agreement with the 25…

The Raman-active phonons in perovskite-like LaMn1-xCoxO3 (x = 0, 0.2, 0.3, 0.4, and 1.0) were studied by measuring Raman spectra at temperatures of 295 and 5 K. The changes in the spectra with Co doping are correlated with the decrease of…

We present results of our study of polarized Raman scattering and infrared reflectivity of rhombohedral ceramic La_1-ySr_yMn_1-xM_xO_3 manganites in the temperature range between 77 and 320K. In our samples, a part of the Mn atoms is…

强关联电子 · 物理学 2009-11-11 A. Dubroka , J. Humlicek , M. V. Abrashev , Z. V. Popovic , F. Sapina , A. Cantarero

We report an investigation of perovskite-type LaNiO3 thin films by Raman scattering in both various scattering configurations and as a function of temperature. The room-temperature Raman spectra and the associated phonon mode assignment…

材料科学 · 物理学 2010-07-30 N. Chaban , M. Weber , S. Pignard , J. Kreisel

We have used a shell model to study the phonon dynamics of multiferroic manganites RMnO3 (R= Tb, Dy, Ho). The calculated phonon dynamical properties, crystal structure, Raman frequencies and specific heat are found to be in good agreement…

材料科学 · 物理学 2010-04-06 Renu Choithrani , Mala N. Rao , S. L. Chaplot , N. K. Gaur , R. K. Singh

We report a systematic investigation of orthorhombic perovskite-type RCrO3 powder samples by Raman scattering for nine different rare earth R3+ cations (R = Y, La, Pr, Sm, Gd, Dy, Ho, Yb, Lu). The room-temperature Raman spectra and the…

材料科学 · 物理学 2012-02-13 M. Weber , J. Kreisel , P. A. Thomas , M. Newton , K. Sardar , R. I. Walton

We report on the high-temperature evolution of far- and mid- infrared reflectivity and emissivity spectra of ambient orthorhombic ErMnO3 from 12 K to sample decomposition above 1800 K. At low temperatures the number of phonons agrees with…

The temperature dependence of phonon excitations and the presence of spin phonon coupling in polycrystalline Pr2NiMnO6 samples were studied using micro-Raman spectroscopy and magnetometry. Magnetic properties show a single…

材料科学 · 物理学 2011-01-17 K. D. Truong , M. P. Singh , S. Jandl , P. Fournier

We present a rationalization of the Raman spectra of orthorhombic and rhombohedral, stoichiometric and doped, manganese perovskites. In particular we study RMnO3 (R= La, Pr, Nd, Tb, Ho, Er, Y and Ca) and the different phases of Ca or Sr…

材料科学 · 物理学 2009-11-07 L. Martin-Carron , A. de Andres , M. J. Martinez-Lope , M. T. Casais , J. A. Alonso

Infrared-active phonons in LaMnO_{3+\delta} were studied by means of the reflection and transmission spectroscopy from 50 to 800 cm^{-1} at room temperature. Powder and ceramic samples of the phases of Pnma-2 (\delta=0.02), Pnma-1…

We have measured near normal incidence far infrared (FIR) reflectivity spectra of a single crystal of TbMnO3 from 10K to 300K in the spectral range of 50 cm$^{-1}$ to 700 cm$^{-1}$. Fifteen transverse optic (TO) and longitudinal optic (LO)…

材料科学 · 物理学 2015-05-13 Pradeep Kumar , Surajit Saha , C. R. Serrao , A. K. Sood , C. N. R. Rao

We report on TmMnO3 far infrared emissivity and reflectivity spectra from 1910 K to 4 K. At the highest temperature the number of infrared bands is lower than that predicted for centrosymmetric P63/mmc (D6h4) (Z=2) space group due high…

We present Raman and terahertz absorbance spectra of methylammonium lead halide single crystals (MAPbX3, X = I, Br, Cl) at temperatures between 80 and 370 K. These results show good agreement with density-functional-theory phonon…

We conduct first-principles theoretical studies to investigate the temperature-dependent phonon properties of orthorhombic SrZrO$_3$ (SZO) perovskite. Our calculations include the quasiharmonic approximation, in which we explored mode…

材料科学 · 物理学 2023-09-06 P. K. Verma

Lattice dynamics for several ordered supercells with composition PbMg1/3Nb2/3O (PMN) were calculated with first-principles frozen phonon methods. Nominal symmetries of the supercells studied are reduced by lattice instabilities. Lattice…

材料科学 · 物理学 2009-11-10 S. A. Prosandeev , E. Cockayne , E. P. Burton

The polarized Raman spectra of orthorhombic RMnO3 series (R=La,Pr,Nd,Sm,Eu,Gd,Tb,Dy,Ho,Y) were studied at room temperature. The variation of phonon frequencies with R ionic radius rR as a whole confirms the commonly accepted Raman line…

材料科学 · 物理学 2007-05-23 M. N. Iliev , M. V. Abrashev , J. Laverdiere , S. Jandl , M. M. Gospodinov , Y. -Q. Wang , Y. -Y. Sun

The polarized Raman spectra of layered ruthenates of the Srn+1RunO3n+1 (n=1,2,3) Ruddlesden-Popper series were measured between 10 and 300 K. The phonon spectra of Sr3Ru2O7 and Sr4Ru3O10 confirmed earlier reports for correlated rotations of…

High pressure x-ray diffraction (XRD) measurements on RMnO3 (R=Dy, Ho and Lu) reveals that varying structural changes occurs for different R ions. Large lattice changes (orthorhombic strain) occur in DyMnO3 and HoMnO3 while the Jahn-Teller…

强关联电子 · 物理学 2014-04-01 T. Wu , T. A. Tyson , H. Chen , P. Gao , T. Yu , Z. Chen , Z. Liu , K. H. Ahn , X. Wang , S. -W. Cheong

We calculated the infrared conductivity spectrum of orbitally ordered LaMnO$_3$ in phonon frequency and overtone frequency ranges. We considered orbital exchange, Jahn-Teller electron-phonon coupling, and phonon--phonon coupling. The…

强关联电子 · 物理学 2021-06-30 Purevdorj Munkhbaatar , Kim Myung-Whun

We report an infrared reflection spectroscopy study of La$_{1/2}$Ca$_{1/2}$MnO$_3$ over a broad frequency range and temperature interval which covers the transitions from the high temperature paramagnetic to ferromagnetic and, upon further…

强关联电子 · 物理学 2009-11-10 A. P. Litvinchuk , M. N. Iliev , M. Pissas , C. W. Chu
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