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Metal nanoparticles are excellent light absorbers. The absorption processes create highly excited electron-hole pairs and recently there has been interest in harnessing these hot charge carriers for photocatalysis and solar energy…

介观与纳米尺度物理 · 物理学 2017-06-13 Gregory V. Hartland , Lucas V. Besteiro , Paul Johns , Alexander O. Govorov

We find that the spontaneous and collective emissions have a strong influence on the excitation of two-level absorbers (atoms, molecules) interacting in resonance with the plasmonic mode near the metal nanoparticle. The spontaneous and…

光学 · 物理学 2024-07-25 Igor E. Protsenko , Alexander V. Uskov , Nikolay V. Nikonorov

Assemblies of closely separated gold nanoparticles exhibit a strong collective plasmonic response due to coupling of the plasmon modes of the individual nanostructures. In the context of self-assembly of nanoparticles, closed packed 2D…

材料科学 · 物理学 2021-08-05 Rituraj Borah , Sammy W. Verbruggen

In this work we show how to maximize absorption of plasmonic nanoparticles in terms of size, geometry and material. For that reason the interaction of nanoparticles with light was decomposed into different effects. We determined that the…

光学 · 物理学 2025-02-07 Matej Bubaš , Jordi Sancho-Parramon

The question whether the linear absorption spectra of metal clusters can be interpreted as density oscillations (collective ``plasmons'') or can only be understood as transitions between distinct molecular states is still a matter of debate…

原子与分子团簇 · 物理学 2009-11-07 S. Kümmel , K. Andrae , P. -G. Reinhard

The plasmonic properties of sphere-like bcc Na nanoclusters ranging from Na$_{15}$ to Na$_{331}$ have been studied by real-time time-dependent local density approximation calculations. The optical absorption spectrum, density response…

介观与纳米尺度物理 · 物理学 2013-10-29 Jian-Hao Li , Michitoshi Hayashi , Guang-Yu Guo

We aim to clarify the role that absorption plays in nonlinear optical processes in a variety of metallic nanostructures and show how it relates to emission and conversion efficiency. We define a figure of merit that establishes the…

The physical and chemical properties of metal nanoparticles differ significantly from those of free metal atoms as well as from the properties of bulk metals, and therefore, they may be viewed as a transition regime between the two physical…

适应与自组织系统 · 物理学 2007-05-23 Horacio G. Rotstein , Amy Novick-Cohen , Rina Tannenbaum

Surface and volume plasmons excited in a metal cluster by moving electron and corresponding inelastic scattering spectra are studied based on the hydrodynamic approach. Along with the bulk losses traditionally taken into account, the…

等离子体物理 · 物理学 2016-04-20 V. B. Gildenburg , V. A. Kostin , I. A. Pavlichenko

A new type of resonant light absorption by a small particle (nanocluster) is reported. The problem cannot be described within the commonly used dipole scattering approximation and should be studied with methods based upon the exact Mie…

光学 · 物理学 2016-09-08 Michael I. Tribelsky

In numerous applications of energy harvesting via transformation of light into heat the focus recently shifted towards highly absorptive materials featuring nanoplasmons. It is currently established that noble metals-based absorptive…

光学 · 物理学 2013-01-22 Gustav Edman Jonsson , Vladimir Miljkovic , Alexandre Dmitriev

The effect of optical radiation on the rate of aggregation of nanoscopic particles is studied in metal aerosols. It has been shown that under light exposure, polydisperse metal aerosols can aggregate up to two orders faster due to the size…

化学物理 · 物理学 2010-10-07 Sergei V. Karpov , Ivan L. Isaev

Hot charge carrier extraction from metallic nanostructures is a very promising approach for applications in photo-catalysis, photovoltaics and photodetection. One limitation is that many metallic nanostructures support a single plasmon…

The combination of nanodiamonds with plasmonic metal particles is being explored for synergic effects that can enhance biosensing and antibacterial treatments, energy harvesting, photocatalysis, and quantum centres. Here we systematically…

We show theoretically that coherent light can be completely absorbed in a two-dimensional or three-dimensional metallic nanostructure by matching the frequency and field pattern of an incident wave to that of a localized surface plasmon…

光学 · 物理学 2015-05-30 Heeso Noh , Yidong Chong , A. Douglas Stone , Hui Cao

We theoretically investigate optical absorption of molecules embedded nearby metallic antennas by using discrete dipole approximation method. It is found that the spectral peak of the absorption is shifted due to the radiation-induced…

介观与纳米尺度物理 · 物理学 2015-10-01 Yoshiki Osaka , Nobuhiko Yokoshi , Hajime Ishihara

Enhanced optical absorption of molecules in the vicinity of metallic nanostructures is key to a number of surface-enhanced spectroscopies and of great general interest to the fields of plasmonics and nano-optics. Yet, experimental access to…

A unique property of metal nanoclusters is the "superatom" shell structure of their delocalized electrons. The electronic shell levels are highly degenerate and therefore represent sharp peaks in the density of states. This can enable…

超导电性 · 物理学 2015-12-17 Avik Halder , Vitaly V. Kresin

We show that a stack of metal-dielectric nanolayers, in addition to the long- and short-range plasmons, guides also an entire family of modes strongly confined within the multilayer - the bulk plasmon modes. We propose the classification…

光学 · 物理学 2007-06-13 Ivan Avrutsky , Ildar Salakhutdinov , Justin Elser , Viktor Podolskiy

Metallic nanoparticles embedded in dielectrics permit enhanced capture of light at specific wavelengths through excitation of plasmons, i.e. the quanta of coherent and collective oscillations of large concentrations of nearly free…

材料科学 · 物理学 2010-01-19 J. Trice , C. Favazza , H. Garcia , R. Sureshkumar , R. Kalyanaraman
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