相关论文: Limitations of Self-Assembly at Temperature 1

Multi-component self-assembly mixtures offer the possibility of encoding multiple target structures with the same set of interacting components. Selective retrieval of one of the stored structures has been attempted by preparing an initial…

There are many exotic thermodynamic processes that are hard to study in nature. Here, we synthesize a structured environment to explore the extremes of thermodynamics. We present an engine running at extreme temperatures of above ten…

A particular, two-dimensional, tiling model, composed by the so called Wang tiles has been studied at finite temperature by Monte Carlo numerical simulations. In absence of any thermal bath the Wang tiles give the opportunity of building a…

There is evidence that the self-assembly of complex molecular systems often proceeds hierarchically, by first building subunits that later assemble in larger entities, in a process that can repeat multiple times. Yet, our understanding of…

Based on the foundations of thermodynamics and the equilibrium conditions for the coexistence of two phases in a magnetic Ising-like system, we show, first, that there is a critical point where the isothermal susceptibility diverges and the…

In the self-assembly process which drives the formation of cellular membranes, micelles, and capsids, a collection of separated subunits spontaneously binds together to form functional and more ordered structures. In this work, we study the…

We use the partition functions on S^1 x S^n of various conformal field theories in four and six dimensions in the limit of vanishing coupling to study the high temperature thermodynamics. Certain modular properties exhibited by the…

We prove that for any infinite countable amenable group $G$, any $\epsilon > 0$ and any finite subset $K\subset G$, there exists a tiling (partition of $G$ into finite "tiles" using only finitely many "shapes"), where all the tiles are $(K;…

Strand displacement and tile assembly systems are designed to follow prescribed kinetic rules (i.e., exhibit a specific time-evolution). However, the expected behavior in the limit of infinite time--known as thermodynamic equilibrium--is…

Self-assembly, the process by which interacting components form well-defined and often intricate structures, is typically thought of as a spontaneous process arising from equilibrium dynamics. When a system is driven by external…

We show that coupled autonomous thermal machines, in the presence of three heat reservoirs and following a global linear-irreversible description, provide a unified framework to accommodate the variety of expressions for the efficiency at…

Thermal corrections have an important effect on moduli stabilization leading to the existence of a maximal temperature, beyond which the compact dimensions decompactify. In this note, we discuss generality of our earlier analysis and apply…

If particles interact according to isotropic pair potentials that favor multiple length scales, in principle a large variety of different complex structures can be achieved by self-assembly. We present, motivate, and discuss a conjecture…

We present new simulation results for the specific heat in a classical model of a binary mixture glass-former in two dimensions. We show that in addition to the formerly observed specific heat peak there is a second peak at lower…

In recent years, much attention has been paid to the development of techniques which transfer trapped particles to very low temperatures. Here we focus our attention on a heating mechanism which contributes to the finite temperature limit…

In this paper, we investigate the computability of thermodynamic invariants at zero temperature for one-dimensional subshifts of finite type. In particular, we prove that the residual entropy (i.e., the joint ground state entropy) is an…

Perhaps the two most significant theoretical questions about the programming of self-assembling agents are: (1) necessary and sufficient conditions to produce a unique terminal assembly, and (2) error correction. We address both questions,…

The configurational entropy is among the key observables to characterize experimentally the formation of a glass. Physically, it quantifies the multiplicity of metastable states in which an amorphous material can be found at a given…

We show how to construct non-equilibrium thermodynamics for systems too small to be considered thermodynamically in a traditional sense. Through the use of a non-equilibrium ensemble of many replicas of the system which can be viewed as a…

Under the Ansatz that the occupation times of a system with finitely many states are given by the Gibbs distribution, an effective temperature is uniquely determined (up to a choice of scale), and may be computed de novo, without any…