相关论文: Synthesis of Silver Colloids: Experiment and Compu…
We present results of computational modeling of the formation of uniform spherical silver particles prepared by rapid mixing of ascorbic acid and silver-amine complex solutions in the absence of a dispersing agent. Using an accelerated…
The recently developed two-stage growth model of synthesis of monodispersed polycrystalline colloidal particles is utilized and improved to explain growth of uniform cadmium sulfide spheres. The model accounts for the coupled processes of…
Silver nanocrystals have been prepared by reacting silver nitrate with ascorbic acid in aqueous solution containing a low concentration of a commercial polynaphtalene sulphonate polymer (Daxad 19). Various crystalline morphologies have been…
It has been experimentally established in numerous cases that precipitation of monodispersed colloids from homogeneous solutions is a complex process. Specifically, it was found that in many systems nuclei, produced rapidly in a…
Formation of monodispersed colloidal particles is a complex process: nuclei, produced rapidly in a supersaturated solution, grow to nanosize primary particles, which then aggregate (coagulate) to form much larger final colloids. This paper…
Monodispersed spherical cadmium sulfide particles were used as a model system in order to explain the size selection in the formation of colloids by aggregation of nanosize subunits. Several procedures of mixing the reactants were employed…
Aiming at spherical and monodisperse silver nanoparticles with diameters up to 100 nm, the potential of heterogeneous nucleation of silver particles was explored. Gold seed particles, mainly produced with a spark discharge generator, were…
The paper presents the results of investigation of the structure of porous condensates of Ag-NaCl and Cu-NaCl composition; chemical and phase compositions and dimensions of nanoparticles, produced from the vapour phase by EBPVD method.…
We present an innovative template-free water-based sol-gel method to produce uniform mesoporous silica beads of millimeter size, which have tunable size, stiffness and porosity, and could be used for adsorption applications. Our protocol…
In this experiment, the authors reviewed the principles and methods for the synthesis and characterization of gold-silver nanocrystals and proposed two possible synthesis mechanisms for Gold and Silver Composite Nanocrystals. Gold…
Truly spherical silver nanoparticles are of great importance for fundamental studies including plasmonic applications, but the direct synthesis in aqueous media is not feasible. Using the commonly employed copper-based etching processes,…
Ample experimental evidence has been accumulated demonstrating that the formation of monodispersed colloids proceeds through a more complex mechanism, than the generally excepted diffusional "burst nucleation" process. Instead, the…
While nanoalloys are of paramount scientific and practical interests, the main processes leading to their formation are still poorly understood. Key structural features in the alloy systems, including crystal phase, chemical ordering, and…
We present modeling approaches to explain mechanisms of control of uniformity (narrow distribution) of sizes and shapes in synthesis of nanosize crystals and micron-size colloids. We consider those situations when the nanocrystals are…
The properties of silver nanoparticles (AgNPs) are affected by various parameters, making optimisation of their synthesis a laborious task. This optimisation is facilitated in this work by concurrent use of a T-junction microfluidic system…
On the basis of the physico-chemical principles underlying silver-staining of proteins, which are recalled in this paper, several methods of silver-staining of proteins after SDS electrophoresis in polyacrylamide gels or isoelectric…
Metal nanoparticles have a substantial impact across different fields of science, such as photochemistry, energy conversion, and medicine. Among the commonly used nanoparticles, silver nanoparticles are of special interest due to their…
A model for formation of helical multishell gold nanowires is proposed and is confirmed with the quantum mechanical molecular dynamics simulations. The model can explain the magic number of the helical gold nanowires in the multishell…
In this paper, experiments on the deposition of silver nanoclusters are analysed numerically using improved DSMC method. These experiments were made in the Institute of Thermophysics SB RAS recent years, in the context of the development of…
A Laser-stimulated synthesis of large silver nanoaggregates consisting of hundreds to thousands of nanoparticles is investigated. It is shown that the morphology of the synthesized nanostructures can be controlled with light and monitored…