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Surface enhanced Raman scattering (SERS) in nanoscale hotspots has been placed great hopes upon for identification of minimum chemical traces and in-situ investigation of single molecule structures and dynamics. However, previous work…

光学 · 物理学 2016-09-19 Jing Long , Hui Yi , Hongquan Li , Tian Yang

This study examines the Raman scattering and charge transfer properties of molecules adsorbed on the surface of a tetrahedral Au$_{120}$ nanoparticle based on the time-dependent density functional tight-binding (TD-DFTB) method. We study…

化学物理 · 物理学 2024-09-18 Sajal Kumar Giri , George C. Schatz

Europium-doped lutetium-oxide (Eu:Lu2O3) nanoparticles were synthesized using a combustion technique and a co-precipitation technique, and their properties were compared. Surface-modification utilizing small silane molecules and long chain…

材料科学 · 物理学 2011-06-21 Haoyan Wei , Zachary Cleary , Sang Park , Keerthesinghe Senevirathne , Hergen Eilers

The experimental limitations in the signal enhancement and spatial resolution in spectroscopic imaging have been always a challenging task in the application of near-field spectroscopy for nanostructured materials in the sub-diffraction…

材料科学 · 物理学 2018-06-11 A. K. Sivadasan , Avinash Patsha , Achyut Maity , Tapas Kumar Chini , Sandip Dhara

Surface-enhanced coherent anti-Stokes Raman scattering (SE-CARS) takes advantage of surface plasmon resonances supported on metallic nanostructures to amplify the coherent Raman response of target molecules. While these metallic antennas…

光学 · 物理学 2022-09-07 Shamsul Abedin , Yong Li , Abid Anjum Sifat , Khokan Roy , Eric Olaf Potma

Cathodoluminescence spectroscopy has been performed on silver nanoparticles in a scanning electron microscopy setup. Peaks appearing in the visible range for particles fabricated on silicon substrate are shown to arrive from excitation of…

光学 · 物理学 2009-06-08 Pratik Chaturvedi , Keng Hsu , Anil Kumar , James C. Mabon , Nicholas Fang

Although fluorescence is the prevailing labeling technique in biosensing applications, sensitivity improvement is still a striving challenge. We show that coating standard microscope slides with nanoroughened silver films provides a high…

仪器与探测器 · 物理学 2013-07-29 Eric Le Moal , Sandrine Lévêque-Fort , Marie-Claude Pottier , Emmanuel Fort

For a transparent projection screen based on metallic nanoparticle's localized surface plasmon resonance (LSPR), in the ideal case the metallic nanoparticles dispersed in a transparent matrix only selectively scatter red, green and blue…

应用物理 · 物理学 2019-03-27 Yiyang Ye , Rongyue Liu , Zhigang Song , T. P. Chen

High resolution low frequency Raman scattering measurements from embedded AgAu nanoparticles unveil efficient scattering by harmonics of both the quadrupolar and the spherical modes. Comparing the experimental data with theoretical…

介观与纳米尺度物理 · 物理学 2009-06-02 S. Adichtchev , S. Sirotkin , G. Bachelier , L. Saviot , S. Etienne , B. Stephanidis , E. Duval , A. Mermet

Transient absorption and Raman scattering measurements on noble metal nanoparticles offer complimentary information on their vibrational modes and mechanical interactions with their surroundings. We have developed a comprehensive modeling…

介观与纳米尺度物理 · 物理学 2024-10-29 Rachel Gelfand , Matthew Pelton

Gold nanoflowers are known for their use as efficient host for surface enhanced Raman scattering of organic dye molecules. In this article, gold nanoflowers have been synthesised and rhodamine 6 G (R6G) molecules have been used as probe…

Clear influence of particle size, surfactants and dispersion medium on surface plasmon resonance (SPR) features of Ag nanoparticles (NPs), synthesized in thermal decomposition method, in the broad range of ultraviolet (UV) radiation,…

应用物理 · 物理学 2020-01-29 Vikash Sharma , Divya Verma , Gunadhor Singh Okram

Resonantly enhanced Raman scattering in dielectric nanostructures has been recently proven to be an effcient tool for developing nanothermometry and experimental determination of their mode- composition. In this paper, we develop a rigorous…

光学 · 物理学 2018-02-14 Kristina Frizyuk , Mehedi Hasan , Alex Krasnok , Andrea Alu , Mihail Petrov

Surface enhanced Raman scattering (SERS) exploits surface plasmons induced by the incident field in metallic nanostructures to significantly increase the Raman intensity. Graphene provides the ideal prototype two dimensional (2d) test…

介观与纳米尺度物理 · 物理学 2013-04-03 F. Schedin , E. Lidorikis , A. Lombardo , V. G. Kravets , A. K. Geim , A. N. Grigorenko , K. S. Novoselov , A. C. Ferrari

The long-range action of surface-enhanced Raman scattering (SERS) is probed via distance-dependent measurements of molecular Raman spectra. To this end, identical SERS substrates composed of irregular silver nanoisland arrays were covered…

材料科学 · 物理学 2015-06-12 V. I. Kukushkin , A. B. Van'kov , I. V. Kukushkin

Optical field localization at plasmonic tip-sample nanojunctions has enabled high spatial resolution chemical analysis through tip-enhanced linear optical spectroscopies, including Raman scattering and photoluminescence. Here, we illustrate…

光学 · 物理学 2021-10-01 Chih-Feng Wang , Patrick Z. El-Khoury

Plasmonic nanoparticles from unconventional materials can improve or even bring some novel functionalities into the disciplines inherently related to plasmonics such as photochemistry or (spectro)electrochemistry. They can, for example,…

In this article, we address the optomechanical effects in surface-enhanced resonant Raman scattering (SERRS) from a single molecule in a nano-particle on mirror (NPoM) nanocavity by developing a quantum master equation theory, which…

We demonstrate that the emission of light by fluorescent molecules in the proximity of periodic arrays of nanoantennas or plasmonic crystals can be strongly modified when the arrays are covered by a dielectric film. The coupling between…

光学 · 物理学 2009-01-14 G. Vecchi , V. Giannini , J. Gómez Rivas

In analogy to cavity optomechanics, enhancing specific sidebands of a Raman process with narrowband optical resonators would allow for parametric amplification, entanglement of light and molecular vibrations, and reduced transduction noise.…

光学 · 物理学 2023-01-09 Ilan Shlesinger , Isabelle M. Palstra , A. Femius Koenderink