相关论文: Chemical Rates on Small Grains and PAHs: C^+ Recom…
We have analyzed ALMA Cycle 5 data in Band 4 toward three low-mass young stellar objects (YSOs), IRAS 03235+3004 (hereafter IRAS 03235), IRAS 03245+3002 (IRAS 03245), and IRAS 03271+3013 (IRAS 03271), in the Perseus region. The HC$_{3}$N…
Fragmentation is an important decay mechanism for polycyclic aromatic hydrocarbons (PAHs) under harsh interstellar conditions and represents a possible formation pathway for small molecules such as H2, C2H2, C2H4. Our aim is to investigate…
Column density ratios of complex organic molecules are generally constant across protostellar systems with some low-level scatter. However, the scatter in formamide (NH$_2$CHO) to methanol (CH$_3$OH) column density ratio is one of the…
We study the changes in physical and chemical conditions during the collapse of a pre--protostellar core, starting from initial conditions appropriate to a dense molecular cloud and proceeding to the ``completely depleted'' limit. We follow…
Interstellar complex organic molecules (iCOMs) can be loosely defined as chemical compounds with at least six atoms in which at least one is carbon. The observations of iCOMs in star-forming regions have shown that they contain an important…
Molecular hydrogen being unobservable in cold molecular clouds, the column density measurements of molecular gas currently rely either on dust emission observation in the far-IR or on star counting. (Sub-)millimeter observations of numerous…
Rate constants for the potentially important interstellar N(4S) + CH(X2{\Pi}r) reaction have been measured in a continuous supersonic flow reactor over the range 56 K < T < 296 K using the relative rate technique employing both the N(4S) +…
We report the discovery of a threshold in the HI column density of Galactic gas clouds below which the formation of the cold phase of HI is inhibited. This threshold is at $N_{HI} = 2 \times 10^{20}$ per cm$^{2}$; sightlines with lower HI…
We present new analytic theory and radiative transfer computations for the atomic to molecular (HI-to-H2) transitions, and the build-up of atomic-hydrogen (HI) gas columns, in optically thick interstellar clouds, irradiated by…
Formic acid (HCOOH) and carbon dioxide (CO2) are simple species that have been detected in the interstellar medium. The solid-state formation pathways of these species under experimental conditions relevant to prestellar cores are primarily…
We present a detailed theoretical study of the rotational excitation of CH$^+$ due to reactive and nonreactive collisions involving C$^+(^2P)$, H$_2$, CH$^+$, H and free electrons. Specifically, the formation of CH$^+$ proceeds through the…
Airborne and space-based low-resolution spectroscopy in the 1980s discovered tantalizing quantitative relationships between the gas phase C/O abundance ratio in planetary nebulae (PNe) and the fractions of total far-infrared luminosity…
PAHs constitute a major component of the interstellar medium carbon budget, locking up to 10--20% of the elemental carbon. Sequential fragmentation induced by energetic photons leads to the formation of new species, including fullerenes.…
While most chemical reactions in the interstellar medium take place in the gas phase, those occurring on the surfaces of dust grains play an essential role. Chemical models based on rate equations including both gas phase and grain surface…
We investigate the impact of high optical depth on the HI saturation observed in the Perseus molecular cloud by using Arecibo HI emission and absorption measurements toward 26 radio continuum sources. The spin temperature and optical depth…
Polycyclic Aromatic Hydrocarbons (PAHs) are key diagnostics of the physical conditions in the interstellar medium and are widely used to trace star formation in the mid-infrared (mid-IR). The relative strengths of mid-IR PAH emission…
Context: In the laboratory, hydrogen peroxide (HOOH) was proven to be an intermediate product in the solid-state reaction scheme that leads to the formation of water on icy dust grains. When HOOH desorbs from the icy grains, it can be…
Many chemical models of dense interstellar clouds predict that the majority of gas-phase elemental nitrogen should be present as N2, with an abundance approximately five orders of magnitude less than that of hydrogen. As a homonuclear…
We present a new gas-grain chemical model to constrain the effect of grain size distribution on molecular abundances in starless and pre-stellar cores. We introduce grain-size dependence simultaneously for cosmic-ray (CR)-induced desorption…
Star formation rates in galaxies are frequently estimated using the Balmer line fluxes. However, these can be systematically underestimated because dust competes for the absorption of Lyman continuum photons in the ionized gas. Here we…