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KCrF3 represents another prototypical orbital-ordered perovskite, where Cr2+ possesses the same electronic configuration of 3d4 as that of strongly Jahn-Teller distorted Mn3+ in many CMR manganites. The crystal and magnetic structures of…

强关联电子 · 物理学 2013-09-30 Y. Xiao , Y. Su , H. -F. Li , C. M. N. Kumar , R. Mittal , J. Persson , A. Senyshyn , K. Gross , Th. Brueckel

Double-perovskite oxides that contain both 3d and 5d transition metal elements have attracted growing interest as they provide a model system to study the interplay of strong electron interaction and large spin-orbit coupling (SOC). Here,…

The electronic transport properties and the magnetic susceptibility were measured in detail in $YBaCo_2O_{5.45}$. Close to the so-called metal-insulator transition, strong effects of resistance relaxation, a clear thermal hysteresis and a…

材料科学 · 物理学 2009-11-13 A. Pautrat , P. Boullay , S. Hebert , V. Caignaert

Magnetic structures and the relationship between spin and charge-orbital orderings of an A-site ordered double-perovskite manganite SmBaMn2O6, an anticipated multiferroic material, were investigated by means of neutron diffraction. The spin…

In this study, we determined the different physical characteristics of nanoscale layered mixed Fe-Co layers of orthoferrite SmFe0.5Co0.5O3 based on magnetic and dielectric measurements.Magnetization analyzes showed that the system was…

材料科学 · 物理学 2018-12-27 Ashish Shukla , Akash Singh , Md. Motin Seikh , Asish K Kundu

Artificial superlattices designed with ferromagnetic Pr0.85Ca0.15MnO3 insulating layer and ferroelectric Ba0.6Sr0.4TiO3 layer were grown on (100) SrTiO3 substrates. The magnetotransport properties were measured with the current…

强关联电子 · 物理学 2009-11-10 P. Murugavel , P. Padhan , W. Prellier

We report on a 59Co NMR investigation of the trigonal cobaltate Ca3Co2O6 carried out on a single crystal, providing precise determinations of the electric field gradient and chemical shift tensors, and of the internal magnetic fields at the…

强关联电子 · 物理学 2015-05-20 G. Allodi , R. De Renzi , S. Agrestini , C. Mazzoli , M. R. Lees

Bulk La_wCoO3 particles with w=1.1, 1.0, 0.9, 0.8, and 0.7 were synthesized using starting materials with varying molar ratios of La2O3 and Co3O4. The resulting particles are characterized as LaCoO3 crystals interfaced with a crystalline…

强关联电子 · 物理学 2015-06-23 A. M. Durand , T. J. Hamil , D. P. Belanger , S. Chi , F. Ye , J. A. Fernandez-Baca , Y. Abdollahian , C. H. Booth

Neutron powder diffraction measurements, combined with magnetization and resistivity data, have been carried out in the doped perovskite La$_{1-x}$Ca$_x$MnO$_3$ ($x=0.47$, 0.50, and 0.53) to elucidate the structural, magnetic, and…

强关联电子 · 物理学 2009-10-31 Q. Huang , J. W. Lynn , R. W. Erwin , A. Santoro , D. C. Dender , V. N. Smolyaninova , K. Ghosh , R. L. Greene

The synthesis, morphology and magneto-transport properties of nanostructure-engineered charge-ordered Pr0.5Ca0.5MnO3 grown on ZnO nanowires are reported. The stability of the charge-ordering can be tuned, but more interestingly the sign of…

材料科学 · 物理学 2011-09-09 R. V. K. Mangalam , Z. Zhang , T. Wu , W. Prellier

We present a detailed magnetic study of the perovskite manganite Pr0.7Ca0.3MnO3 at low temperatures including magnetization and a.c. susceptibility measurements. The data appear to exclude a conventional spin glass phase at low fields,…

强关联电子 · 物理学 2009-10-31 I. G. Deac , J. F. Mitchell , P. Schiffer

Magnetic properties of an antiferromagnetic double perovskite oxide Ba2CaReO6, where Re6+ (5d1) ions with large spin-orbit coupling are arranged on the face-centered-cubic lattice, are investigated using pulsed high magnetic field up to 66…

The samples LaCoO3 with dilute substitutions on cobalt sites have been studied using the resistivity, thermopower and magnetic susceptibility measurements over the temperature range up to ~900 K. The Co-site substitution does not affect the…

材料科学 · 物理学 2010-07-30 J. Hejtmanek , Z. Jirak , K. Knizek , M. Marysko , M. Veverka , C. Autret

This work presents a systematic study of the magnetocaloric effect in the nanostructured perovskite series $La_{0.6}Sr_{0.4}Fe_{1-x}Co_{x}O_3$ (x = 0, 0.2, 0.5, 0.8, and 1.0), synthesized by a pore-wetting method using polymeric membranes…

材料科学 · 物理学 2026-05-14 Fabiana N. Morales Alvarez , Mariano Quintero , Joaquín Sacanell

Magnetometry, electrical transport, and neutron scattering measurements were performed on single crystals of the Fe^{4+}-containing perovskite-related phase Sr_3Fe_2O_7-x as a function of oxygen content. Although both the crystal structure…

强关联电子 · 物理学 2013-06-12 D. C. Peets , J. -H. Kim , P. Dosanjh , M. Reehuis , A. Maljuk , N. Aliouane , C. Ulrich , B. Keimer

Detailed structural measurements were conducted on a new perovskite, ScMnO3, and on orthorhombic LuMnO3. Complementary density functional theory (DFT) calculations were carried out, and predict that ScMnO3 possesses E-phase magnetic order…

强关联电子 · 物理学 2015-06-19 T. Yu , T. A. Tyson , H. Y. Chen , A. M. M. Abeykoon , Y. -S. Chen , K. H. Ahn

Perovskite manganite La0.5Ca0.5-x xMnO3 (LCMO) nanomaterials were elaborated using the sucrose modified auto combustion method. Rietveld refinements of the X-ray diffraction patterns of the crystalline structure confirm a single-phase…

We report x-ray diffraction, resistivity, thermopower, and magnetization of Sr3ErMn4-xGaxO10.5-d, in which A-site ordered tetragonal phase appears above x=1, and reveal that the system exhibits typical properties seen in the…

材料科学 · 物理学 2015-05-27 W. Kobayashi , T. Ishibashi

We report the crystal structure, magnetization and neutron scattering measurements on the double perovskite Ba$_2$YOsO$_6$. The $Fm\overline{3}m$ space group is found both at 290~K and 3.5~K with cell constants $a_0 = 8.3541(4)$~{\AA} and…

Using first-principles calculations we predict that the layered-perovskite metal Bi$_5$Mn$_5$O$_{17}$ is a ferromagnet, ferroelectric, and ferrotoroid which may realize the long sought-after goal of a room-temperature ferromagnetic…

材料科学 · 物理学 2020-10-02 Andrea Urru , Francesco Ricci , Alessio Filippetti , Jorge Iniguez , Vincenzo Fiorentini