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We present magnetic susceptibility measurements on MgV$_2$O$_5$, a compound in which the vanadium oxide planes have the same topology as in CaV$_2$O$_5$. The most striking property is that there is an energy gap of about 15 K, much smaller…

强关联电子 · 物理学 2009-10-31 P. Millet , C. Satto , J. Bonvoisin , B. Normand , K. Penc , M. Albrecht , F. Mila

We have synthesized and characterized a new spin-1/2 Heisenberg antiferromagnetic ladder: bis 5-iodo-2-aminopyridinium tetrabromocuprate(II) dihydrate. X-ray diffraction studies show the structure of the compound to consist of well isolated…

凝聚态物理 · 物理学 2009-10-31 C. P. Landee , M. M. Turnbull , C. Galeriu , J. Giantsidis , F. M. Woodward

We have performed ab-initio calculations of the electronic structure and exchange couplings in the layered vanadates CaV2O5 and MgV2O5. Based on our results we provide a possible explanation of the unusual magnetic properties of these…

强关联电子 · 物理学 2009-10-31 M. A. Korotin , V. I. Anisimov , T. Saha-Dasgupta , I. Dasgupta

Structural analysis of a layered manganese tungstate diaminoalkane hybrid series suggests that this compound forms a spin-5/2 spin-ladder structure. We use X-ray diffraction, electron microscopy and x-ray absorption spectroscopy results to…

材料科学 · 物理学 2007-05-23 B. Ingham , J. L. Tallon , S. V. Chong , R. -S. Liu , L. -Y. Jang

We argue that in the quarter-filled ladder compound NaV_2O_5 the quasi-one-dimensional spin system is strongly coupled to a low-energy antiferroelectric mode of the excitonic type. This mode results from the interplay between the electron…

强关联电子 · 物理学 2007-05-23 M. V. Mostovoy , J. Knoester , D. I. Khomskii

We investigate weakly coupled quarter-filled ladders with model parameters relevant for NaV_2O_5 using density-matrix renormalization group calculations on an extended Hubbard model coupled to the lattice. NaV2O5 exhibits…

强关联电子 · 物理学 2009-11-11 B. Edegger , H. G. Evertz , R. M. Noack

A new X-ray diffraction study of the one-dimensional spin-Peierls compound \alpha-NaV_2O_5 reveals a centrosymmetric (Pmmn) crystal structure with one type of V site, contrary to the previously postulated non-centrosymmetric P2_1mn…

凝聚态物理 · 物理学 2009-10-31 H. Smolinski , C. Gros , W. Weber , U. Peuchert , G. Roth , M. Weiden , C. Geibel

A comprehensive theoretical and experimental study is presented of the magnetic susceptibility versus temperature \chi(T) of spin S = 1/2 two- and three-leg Heisenberg ladders and ladder oxide compounds. Extensive quantum Monte Carlo…

The low-temperature electronic and magnetic properties of NH$_4$V$_2$O$_5$, an isoelectronic analog of the spin-ladder compound $\alpha'$-NaV$_2$O$_5$, are investigated using DFT+$U$ calculations. Two charge-ordering patterns - zigzag and…

强关联电子 · 物理学 2025-08-20 Dm. M. Korotin

We present a detailed analysis of light scattering experiments performed on the quarter-filled spin ladder compound $\alpha^\prime$-NaV$_{2}$O$_{5}$ for the temperature range 5 K$\le$T$\le$300 K. This system undergoes a phase transition…

强关联电子 · 物理学 2009-10-31 M. Fischer , P. Lemmens , G. Els , G. Güntherodt , E. Sherman , E. Morre , C. Geibel , F. Steglich

Small single crystals of Rb$_3$Ni$_2$(NO$_3$)$_7$ were obtained by crystallization from anhydrous nitric acid solution of rubidium nitrate and nickel nitrate hexahydrate. The basic elements of the crystal structure of this new compound are…

We investigate weakly coupled spin-1/2 ladders in a magnetic field. The work is motivated by recent experiments on the compound (C5H12N)2CuBr4 (BPCB). We use a combination of numerical and analytical methods, in particular the density…

We report the synthesis and the magnetic susceptibility of (pipdH)2Cu1-xZnxBr4, which is a nonmagnetic impurity-doped S=1/2 spin ladder system. The samples were synthesized from a solution by using a slow evaporation method. Samples were…

材料科学 · 物理学 2013-07-15 C. Yokoyama , E. Matsuoka , H. Sugawara , T. Sakurai , W. Zhang , S. Okubo , H. Ohta , H. Kikuchi

This response on a Comment on Reference 2 discusses the space group Fmm2 determination of the low temperature structure of NaV2O5. We show that while conventional crystallography is consistent with 'zig-zag' charge ordering of half of the…

强关联电子 · 物理学 2009-10-31 J. L. de Boer , G. Maris , A. Meetsma , J. Baas , T. T. M. Palstra

Magnetic properties of the silver vanadium phosphate Ag(2)VOP(2)O(7) are studied by means of magnetic susceptibility measurements and electronic structure calculations. In spite of the layered crystal structure suggesting 1D or 2D magnetic…

强关联电子 · 物理学 2008-03-27 Alexander A. Tsirlin , Ramesh Nath , Christoph Geibel , Helge Rosner

We present microscopic estimates for the spin-spin and spin-speudospin interactions of the quarter-filled ladder compound NaV2O5, obtained by exactly diagonalizing appropriate clusters of the underlying generalized Hubbard Hamiltonian. We…

强关联电子 · 物理学 2007-05-23 Claudius Gros , Gennady Y. Chitov

We investigate weakly coupled spin-1/2 ladders in a magnetic field. The work is motivated by recent experiments on the compound $\mathrm{(C_5H_{12}N)_2CuBr_4}$ (BPCB). We use a combination of numerical and analytical methods, in particular…

强关联电子 · 物理学 2012-01-26 Pierre Bouillot

We have successfully synthesized single crystals, solved the crystal structure, and studied the magnetic properties of a new family of copper halides (C$_4$H$_{14}$N$_2$)Cu$_2X_6$ ($X$= Cl, Br). These compounds crystallize in an…

材料科学 · 物理学 2023-06-28 P. Biswal , S. Guchhait , S. Ghosh , S. N. Sarangi , D. Samal , Diptikant Swain , Manoranjan Kumar , R. Nath

The charge ordering transition in the layer compound NaV2O5 is studied by means of exact diagonalization methods for finite systems. The 2-leg ladders of the V-Trellis lattice are associated with one spin variable of the vanadium…

强关联电子 · 物理学 2009-11-07 A. Langari , M. A. Martin-Delgado , P. Thalmeier

We have studied the electronic structure of the spin-gapped system CsV$_2$O$_5$ by means of an ab initio calculation. Our analysis and a re-examination of the susceptibility data indicate that the behavior of this system is much closer to…

凝聚态物理 · 物理学 2009-11-07 Roser Valenti , T. Saha-Dasgupta
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