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We demonstrate a novel approach to the structural and electronic property modification of perovskites, focusing on Pr$_2$CuO$_4$, an undoped parent compound of a class of electron-doped copper-oxide superconductors. Currents were passed…

We report the observation of the pressure-induced high-spin to low-spin transition in FeS using new high-pressure synchrotron x-ray emission spectroscopy techniques. The transition is evidenced by the disappearance of the low-energy…

We report a comprehensive neutron diffraction study of the crystal structure and magnetic order in a series of single-crystal and powder samples of SrFeO$_{3-\delta}$ in the vacancy range $0 \leq \delta \leq 0.23$. The data provide detailed…

强关联电子 · 物理学 2015-06-05 M. Reehuis , C. Ulrich , A. Maljuk , Ch. Niedermayer , B. Ouladdiaf , A. Hoser , T. Hofmann , B. Keimer

Synchrotron X-ray diffraction investigations of two single crystals of Na_xCoO_2 from different batches with composition x = 0.525-0.530 reveal homogeneous incommensurate sodium ordering with propagation vector (0.53 0.53 0) at…

强关联电子 · 物理学 2010-07-16 R. Feyerherm , E. Dudzik , S. Valencia , A. U. B. Wolter , C. J. Milne , S. Landsgesell , D. Alber , D. N. Argyriou

High-pressure electrical resistivity measurements up to 3.0GPa have been performed on EuFe2As2 single crystals with residual resistivity ratios RRR=7 and 15. At ambient pressure, a magnetic / structural transition related to FeAs-layers is…

超导电性 · 物理学 2015-05-19 N. Kurita , M. Kimata , K. Kodama , A. Harada , M. Tomita , H. S. Suzuki , T. Matsumoto , K. Murata , S. Uji , T. Terashima

The ferroelectric to paraelectric phase transition of multiferroic CaMnTi$_2$O$_6$ has been investigated at high pressures and ambient temperature by second harmonic generation (SHG), Raman spectroscopy, and powder and single-crystal x-ray…

Optical conductivity s(w) of PrRu4P12 has been studied under high pressure to 14 GPa, at low temperatures to 8 K, and at photon energies 12 meV-1.1 eV. The energy gap in s(w) at ambient pressure, caused by a metal-insulator transition due…

Motivated by the intriguing properties of the Shastry-Sutherland compound SrCu2(BO3)2 under pressure, with a still debated intermediate plaquette phase appearing at around 20 kbar and a possible deconfined critical point at higher pressure…

Oxygen stoichiometry is one of the most important elements in determining the physical properties of transition metal oxides (TMOs). A small fractional change in the oxygen content, resulting in the variation of valence state of the…

We present the magnetic and structural properties of [Cu(pyrazine)$_{0.5}$(glycine)]ClO$_4$ under applied pressure. As previously reported, at ambient pressure this material consists of quasi-two-dimensional layers of weakly coupled…

The effects of pressure on the superconducting properties of a Bi-based layered superconductor La2O2Bi3Ag0.6Sn0.4S6, which possesses a four-layer-type conducting layer, have been studied through the electrical resistance and magnetic…

Mm-sized LiMn$_{1-x}$Fe$_x$PO$_4$ single crystals with $0\leq x \leq 1$ were grown by means of the traveling floating-zone technique at elevated Argon pressure of 30~bar. For the various doping levels, the growth process was optimized with…

强关联电子 · 物理学 2017-02-07 Christoph Neef , Hubert Wadepohl , Hans-Peter Meyer , Rüdiger Klingeler

Cu2OSeO3 is known as a unique example of insulating multiferroic compounds with skyrmion spin texture, which is characterized by the chiral cubic crystal structure at ambient pressure. Recently, it has been reported that this compound shows…

强关联电子 · 物理学 2020-11-18 E. Nishibori , S. Karatsu , C. Terakura , N. Takeshita , M. Kinoshita , S. Ishiwata , Y. Tokura , S. Seki

We report a first-order phase transition at T_M=357 K in single crystal Ca_2RuO_4, an isomorph to the superconductor Sr_2RuO_4. The discontinuous decrease in electrical resistivity signals the near destruction of the Mott insulating phase…

强关联电子 · 物理学 2009-10-31 C. S. Alexander , G. Cao , V. Dobrosavljevic , E. Lochner , S. McCall , J. E. Crow , R. P. Guertin

We have investigated the electronic structure of Sr2IrO4 within the density-functional theory using the generalized gradient approximation while taking into account strong Coulomb correlations in the framework of the fully relativistic…

强关联电子 · 物理学 2023-10-13 V. N. Antonov , D. A. Kukusta , L. V. Bekenov

High pressure in-situ synchrotron X-ray diffraction experiments were performed on Ag2Te up to 42.6 GPa at room temperature and four phases were identified. Phase I ({\beta}-Ag2Te) transformed into phase II at 2.4 GPa, and phase III and…

材料科学 · 物理学 2015-05-01 Zhao Zhao , Shibing Wang , Haijun Zhang , Wendy L. Mao

We report results of ab initio constant-pressure molecular dynamics simulations of sulfur compression leading to structural transition and pressure-induced amorphization. Starting from the orthorhombic S-I phase composed of S$_8$ ring…

无序系统与神经网络 · 物理学 2015-06-19 Dušan Plašienka , Roman Martoňák

We studied the crystal structure of TiOCl up to pressures of $p$=25~GPa at room temperature by x-ray powder diffraction measurements. Two pressure-induced structural phase transitions are observed: At $p_{c1}$$\approx$15~GPa emerges an…

X-ray diffraction experiments under pressure in a diamond anvil cell have been performed to gauge any response of the crystalline lattice of URu2Si2 to the "hidden order" or antiferromagnetic transitions, the latter of which is accessible…

强关联电子 · 物理学 2010-09-29 J. R. Jeffries , N. P. Butch , J. J. Hamlin , S. V. Sinogeikin , W. J. Evans , M. B. Maple

Rattling-induced superconductivity in the {\beta}-pyrochlore oxide KOs2O6 is investigated under high pressure up to 5 GPa. Resistivity measurements in a high-quality single crystal reveal a gradual decrease in the superconducting transition…

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