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Quantum interference can profoundly affect charge transport in single molecules, but experiments can usually measure only the conductance at the Fermi energy. Because in general the most pronounced features of the quantum interference are…

Based on density-functional theory calculations, we report a detailed study of the single-molecule charge-transport properties for a series of recently synthesized biphenyl-dithiol molecules [D. Vonlanthen et al., Angew. Chem., Int. Ed. 48,…

介观与纳米尺度物理 · 物理学 2012-03-16 M. Bürkle , J. K. Viljas , A. Mishchenko , D. Vonlanthen , G. Schön , M. Mayor , T. Wandlowski , F. Pauly

The rational design of single molecule electrical components requires a deep and predictive understanding of structure-function relationships. Here we explore the relationship between chemical substituents and the conductance of…

The solid-state structures of organic charge transfer (CT) salts are critical in determining their mode of charge transport, and hence their unusual electrical properties, which range from semiconducting through metallic to superconducting.…

介观与纳米尺度物理 · 物理学 2016-01-05 Andrea Vezzoli , Iain Grace , Carly Brooke , Kun Wang , Colin J. Lambert , Bingqian Xu , Richard J. Nichols , Simon J. Higgins

The electron transport properties of ZnO nano-wires coupled by two aluminium electrodes were studied by {\it ab initio} method based on non-equilibrium Green's function approach and density functional theory. A clearly rectifying…

介观与纳米尺度物理 · 物理学 2015-05-18 Zijiang Yang , Langhui Wan , Yunjin Yu , Yadong Wei , Jian Wang

The effect of substitution atoms on the energy spectrum and the electrical conductivity of graphene was investigated in a Lifshitz one-electron tight-binding model. It is established that the ordering of impurity atoms results in a gap in…

强关联电子 · 物理学 2020-03-05 S. P. Repetsky , I. G. Vyshyvana , S. P. Kruchinin , R. M. Melnyk , A. P. Polishchuk

Electronic conductance through a single molecule is sensitive towards its structural orientation between two electrodes, owing to the distribution of molecular orbitals and their coupling to the electrode levels, that are governed by…

介观与纳米尺度物理 · 物理学 2023-08-11 Koushik R. Das , Sudipta Dutta

We present a theoretical study of the electronic transport through single-molecule junctions incorporating a Pt6 metal cluster bound within an organic framework. We show that the insertion of this molecule between a pair of electrodes leads…

介观与纳米尺度物理 · 物理学 2013-02-27 Linda A. Zotti , Edmund Leary , Maria Soriano , Juan Carlos Cuevas , Juan Jose Palacios

We have modeled transport properties of nanostructures using the Green's function method within the framework of the density-functional theory. The scheme is computationally demanding so that numerical methods have to be chosen carefully. A…

计算物理 · 物理学 2007-05-23 Paula Havu , Ville Havu , Martti J. Puska , Mikko H. Hakala , Adam S. Foster , Risto M. Nieminen

Electrical and thermal transport properties of C60 molecules are investigated with density-functional-theory based calculations. These calculations suggest that the optimum contact geometry for an electrode terminated with a single-Au atom…

介观与纳米尺度物理 · 物理学 2015-06-05 G. Géranton , C. Seiler , A. Bagrets , L. Venkataraman , F. Evers

We examine electron transport through a single-molecule magnet Mn12 bridged between Au electrodes using the first-principles method. We find crucial features which were inaccessible in model Hamiltonian studies: spin filtering and a strong…

材料科学 · 物理学 2015-05-14 Salvador Barraza-Lopez , Kyungwha Park , Victor Garcia-Suarez , Jaime Ferrer

Electronic transport is theoretically investigated in laterally confined semiconductor superlattices using the formalism of non-equilibrium Green's functions. The transport properties are calculated for nanowire superlattices of varying…

介观与纳米尺度物理 · 物理学 2014-04-25 Thomas Grange

By choosing an electron gas resting instead of drifting in the laboratory coordinate system as the initial state, the first order perturbation calculation of the previous paper (Phys. Stat. Sol. (b) 198, 785(1996)) is revised and extended…

统计力学 · 物理学 2009-10-30 Hang-Sheng Wu , Xian-Xiang Huang , Qi-Ming Weng

We present a Green's function based treatment of the effects of electron-phonon coupling on transport through a molecular quantum dot in the quantum limit. Thereby we combine an incomplete variational Lang-Firsov approach with a…

介观与纳米尺度物理 · 物理学 2015-05-19 T. Koch , J. Loos , A. Alvermann , A. R. Bishop , H. Fehske

The conductance of a molecular junction is commonly determined by either charge-transfer-doping, where alignment of the Fermi energy to the molecular levels is achieved, or tunnelling through the tails of molecular resonances within the…

介观与纳米尺度物理 · 物理学 2016-08-31 R. Gutierrez , G. Fagas , K. Richter , F. Grossmann , R. Schmidt

Quantum transport through single molecules is very sensitive to the strength of the molecule-electrode contact. Here, we investigate the behavior of a model molecular junction weakly coupled to external electrodes in the case where charging…

介观与纳米尺度物理 · 物理学 2009-11-11 Bo Song , Dmitry A. Ryndyk , Gianaurelio Cuniberti

We explore the effect of molecular size on injected carrier transport. We have fabricated and characterized field effect transistors (FETs) on optically transparent single crystals of tetracene, the molecule of which is comprised of four…

凝聚态物理 · 物理学 2007-05-23 V. Y. Butko , X. Chi , A. P. Ramirez

We report transport measurements through a single-molecule magnet, the Mn12 derivative [Mn12O12(O2C-C6H4-SAc)16(H2O)4], in a single-molecule transistor geometry. Thiol groups connect the molecule to gold electrodes that are fabricated by…

介观与纳米尺度物理 · 物理学 2009-11-11 H. B. Heersche , Z. de Groot , J. A. Folk , H. S. J. van der Zant , C. Romeike , M. R. Wegewijs , L. Zobbi , D. Barreca , E. Tondello , A. Cornia

Quantum interference (QI) in molecular transport junctions can lead to dramatic reductions of the electron transmission at certain energies. In a recent work [Markussen et al., Nano Lett. 2010, 10, 4260] we showed how the presence of such…

介观与纳米尺度物理 · 物理学 2017-09-13 Troels Markussen , Robert Stadler , Kristian S. Thygesen

Using a semiclassical Boltzmann transport equation (BTE) approach, we derive analytical expressions for electric and thermoelectric transport coefficients of graphene in the presence and absence of a magnetic field. Scattering due to…

材料科学 · 物理学 2017-04-26 Arpan Kundu , Majed Alrefae , Timothy S. Fisher