Uniform electron gases
Chemical Physics
2012-02-07 v1 Other Condensed Matter
Strongly Correlated Electrons
Abstract
We show that the traditional concept of the uniform electron gas (UEG) --- a homogeneous system of finite density, consisting of an infinite number of electrons in an infinite volume --- is inadequate to model the UEGs that arise in finite systems. We argue that, in general, a UEG is characterized by at least two parameters, \textit{viz.} the usual one-electron density parameter and a new two-electron parameter . We outline a systematic strategy to determine a new density functional across the spectrum of possible and values.
Cite
@article{arxiv.1202.1092,
title = {Uniform electron gases},
author = {Peter M. W. Gill and Pierre-François Loos},
journal= {arXiv preprint arXiv:1202.1092},
year = {2012}
}
Comments
8 pages, 2 figures, 5 tables