English

Uniform electron gases

Chemical Physics 2012-02-07 v1 Other Condensed Matter Strongly Correlated Electrons

Abstract

We show that the traditional concept of the uniform electron gas (UEG) --- a homogeneous system of finite density, consisting of an infinite number of electrons in an infinite volume --- is inadequate to model the UEGs that arise in finite systems. We argue that, in general, a UEG is characterized by at least two parameters, \textit{viz.} the usual one-electron density parameter ρ\rho and a new two-electron parameter η\eta. We outline a systematic strategy to determine a new density functional E(ρ,η)E(\rho,\eta) across the spectrum of possible ρ\rho and η\eta values.

Keywords

Cite

@article{arxiv.1202.1092,
  title  = {Uniform electron gases},
  author = {Peter M. W. Gill and Pierre-François Loos},
  journal= {arXiv preprint arXiv:1202.1092},
  year   = {2012}
}

Comments

8 pages, 2 figures, 5 tables

R2 v1 2026-06-21T20:15:18.356Z