结合Fe(II)阳离子配合物与分数还原态TCNQ的导电自旋交叉化合物
材料科学
2016-04-22 v2
摘要
展示了与Fe(II)配合阳离子子系统相关的导电性和自旋交叉转变（SCO）的自由基阴离子盐 [Fe{HC(pz)3}2](TCNQ)3 已被合成并进行了结构表征。发现了由SCO转变引发的直流电阻率的显著变化和EPR信号的强烈展宽。增强的EPR线宽以TCNQ与Fe(II)自旋子系统之间的交叉弛豫来解释。
引用
@article{arxiv.1604.05852,
title = {The conducting spin-crossover compound combining Fe(II) cation complex with TCNQ in a fractional reduction state},
author = {Yuri N. Shvachko and Denis V. Starichenko and Aleksander V. Korolyov and Eduard B. Yagubskii and Alexander I. Kotov and Lev I. Buravov and Konstantin A. Lyssenko and Vladimir N Zverev and Olga G. Shakirova and Ludmila G. Lavrenova},
journal= {arXiv preprint arXiv:1604.05852},
year = {2016}
}