Quantifying nonclassicality in qubit systems via positive operator-valued measures

We introduce an operational measure of nonclassicality for qubit systems based on the violation of Kolmogorov consistency conditions in sequential measurements. In contrast to previous work by Milz et al.~\cite{Milz-2020}, who characterized classicality via NCGD maps, and Sakuldee et al.~\cite{Sakuldee-2022a, Sakuldee-2022b}, who studied quantum correlations under measurement disturbance, our witness explicitly quantifies nonclassicality in terms of the POVM unsharpness parameter $a_z$. For projective measurements on an initially diagonal state, the witness vanishes identically, showing that such measurements cannot reveal nonclassicality. However, by generalizing to positive operator-valued measures (POVMs), we find that non-projective measurements can reveal nonclassicality even for diagonal initial states. We derive explicit expressions for the witness for general initial states, including coherences, and show that its maximum value is $1/4$, which is a new result achieved for unbiased POVMs, maximal dephasing, and equal initial populations. Our results connect Kolmogorov consistency, Leggett-Garg inequalities, and POVMs, providing an experimentally accessible tool for detecting nonclassicality in qubit systems with potential applications in quantum technology certification.