English

Mayer and virial series at low temperature

Mathematical Physics 2012-06-19 v2 math.MP

Abstract

We analyze the Mayer pressure-activity and virial pressure-density series for a classical system of particles in continuous configuration space at low temperature. Particles interact via a finite range potential with an attractive tail. We propose physical interpretations of the Mayer and virial series' radius of convergence, valid independently of the question of phase transition: the Mayer radius corresponds to a fast increase from very small to finite density, and the virial radius corresponds to a cross-over from monatomic to polyatomic gas. Our results have consequences for the search of a low density, low temperature solid-gas phase transition, consistent with the Lee-Yang theorem for lattice gases and with the continuum Widom-Rowlinson model.

Keywords

Cite

@article{arxiv.1109.6568,
  title  = {Mayer and virial series at low temperature},
  author = {Sabine Jansen},
  journal= {arXiv preprint arXiv:1109.6568},
  year   = {2012}
}

Comments

36 pages, 1 figure

R2 v1 2026-06-21T19:12:40.256Z