Mayer and virial series at low temperature
Abstract
We analyze the Mayer pressure-activity and virial pressure-density series for a classical system of particles in continuous configuration space at low temperature. Particles interact via a finite range potential with an attractive tail. We propose physical interpretations of the Mayer and virial series' radius of convergence, valid independently of the question of phase transition: the Mayer radius corresponds to a fast increase from very small to finite density, and the virial radius corresponds to a cross-over from monatomic to polyatomic gas. Our results have consequences for the search of a low density, low temperature solid-gas phase transition, consistent with the Lee-Yang theorem for lattice gases and with the continuum Widom-Rowlinson model.
Cite
@article{arxiv.1109.6568,
title = {Mayer and virial series at low temperature},
author = {Sabine Jansen},
journal= {arXiv preprint arXiv:1109.6568},
year = {2012}
}
Comments
36 pages, 1 figure