English

Liquid-vapor transition in a model of a continuum particle system with finite-range modified Kac pair potential

Mathematical Physics 2025-10-30 v1 Statistical Mechanics math.MP Probability

Abstract

We prove the existence of a phase transition in dimension d>1d>1 in a continuum particle system interacting with a pair potential containing a modified attractive Kac potential of range γ1\gamma^{-1}, with γ>0\gamma>0. This transition is "close", for small positive γ\gamma, to the one proved previously by Lebowitz and Penrose in the van der Waals limit γ0\gamma\downarrow0. It is of the type of the liquid-vapor transition observed when a fluid, like water, heated at constant pressure, boils at a given temperature. Previous results on phase transitions in continuum systems with stable potentials required the use of unphysical four-body interactions or special symmetries between the liquid and vapor. The pair interaction we consider is obtained by partitioning space into cubes of volume γd\gamma^{-d}, and letting the Kac part of the pair potential be uniform in each cube and act only between adjacent cubes. The "short-range" part of the pair potential is quite general (in particular, it may or may not include a hard core), but restricted to act only between particles in the same cube. Our setup, the "boxed particle model", is a special case of a general "spin" system, for which we establish a first-order phase transition using reflection positivity and the Dobrushin--Shlosman criterion.

Keywords

Cite

@article{arxiv.2510.24825,
  title  = {Liquid-vapor transition in a model of a continuum particle system with finite-range modified Kac pair potential},
  author = {Qidong He and Ian Jauslin and Joel Lebowitz and Ron Peled},
  journal= {arXiv preprint arXiv:2510.24825},
  year   = {2025}
}

Comments

39 pages, 3 figures