通过定向分子库仑爆炸进行气相结构异构体识别
化学物理
2019-02-20 v1
摘要
通过关联飞秒激光诱导库仑爆炸后产生的原子碎片离子的发射角，识别了四种二氟碘苯和两种二羟基溴苯异构体的气相结构。通过在库仑爆炸事件前利用一维激光诱导绝热定向将各分子最可极化轴限定于探测平面内，从而便利了结构测定。对于由两种二氟碘苯异构体组成的分子靶标，每种构成结构还可被单独挑出并区分。
引用
@article{arxiv.1902.06974,
title = {Gas-phase structural isomer identification by Coulomb explosion of aligned molecules},
author = {Michael Burt and Kasra Amini and Jason W. L. Lee and Lars Christiansen and Rasmus R. Johansen and Yuki Kobayashi and James D. Pickering and Claire Vallance and Mark Brouard and Henrik Stapelfeldt},
journal= {arXiv preprint arXiv:1902.06974},
year = {2019}
}
备注
13 pages, 4 figures. Published as a communication in the Journal of Chemical Physics