From Molecular Design to Optical Anisotropy: Orientation Control in BODIPY Langmuir-Blodgett Films

Molecular orientation within ultrathin films is a critical factor in controlling their optical and electronic properties for surface-based photonics and optoelectronics. In this study, we examine two amphiphilic boron-dipyrromethene (BODIPY) derivatives, distinguished by the number of hydrophobic alkyl chains, and investigate their organization and optical response using Langmuir--Blodgett deposition. The spatial and orientational distribution of molecules at the nanoscale is determined by combining hyperspectral imaging, photoluminescence radiation pattern analysis, and incidence-angle-resolved absorption spectroscopy. We evidence, both experimentally and based on a new and original theoretical model, the formation of organized monolayers exhibiting either in-plane or perpendicular transition dipole alignment, depending on the molecular symmetry. These results underscore the deep impact of molecular engineering on supramolecular order and anisotropic optical properties at interfaces, providing a robust strategy for the design of functional thin films down to the monolayer level for advanced optical devices.