中文

Entropy density functional theory for inhomogeneous fluids

软凝聚态物质 2026-06-26 v1 统计力学

摘要

We present an exact variational scheme for the physics of inhomogeneous classical fluids in thermal equilibrium. A joint metadensity minimization principle is proven for the one-body density and the global interparticle distance distribution. The theory bypasses the inhomogeneous two-body density and thus remains computationally simple. A universal excess entropy functional accounts for all many-body correlations in arbitrary pairwise interacting systems. The framework is relevant for neural functional machine learning, for soft matter design, and for predicting structural correlation functions via entropic test-particle and meta-Ornstein-Zernike routes.

引用

@article{arxiv.2606.28240,
  title  = {Entropy density functional theory for inhomogeneous fluids},
  author = {Matthias Schmidt},
  journal= {arXiv preprint arXiv:2606.28240},
  year   = {2026}
}