中文

A Simplified Approach to Optimally Controlled Quantum Dynamics

化学物理 2009-10-30 v2

摘要

A new formalism for the optimal control of quantum mechanical physical observables is presented. This approach is based on an analogous classical control technique reported previously[J. Botina, H. Rabitz and N. Rahman, J. chem. Phys. Vol. 102, pag. 226 (1995)]. Quantum Lagrange multiplier functions are used to preserve a chosen subset of the observable dynamics of interest. As a result, a corresponding small set of Lagrange multipliers needs to be calculated and they are only a function of time. This is a considerable simplification over traditional quantum optimal control theory[S. shi and H. Rabitz, comp. Phys. Comm. Vol. 63, pag. 71 (1991)]. The success of the new approach is based on taking advantage of the multiplicity of solutions to virtually any problem of quantum control to meet a physical objective. A family of such simplified formulations is introduced and numerically tested. Results are presented for these algorithms and compared with previous reported work on a model problem for selective unimolecular reaction induced by an external optical electric field.

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引用

@article{arxiv.physics/9610015,
  title  = {A Simplified Approach to Optimally Controlled Quantum Dynamics},
  author = {Jair Botina and Herschel Rabitz and Naseem Rahman},
  journal= {arXiv preprint arXiv:physics/9610015},
  year   = {2009}
}

备注

Revtex, 29 pages (incl. figures)