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We consider the the van der Waals force involving excited atoms in general environments, constituted by magnetodielectric bodies. We develop a dynamical approach studying the dynamics of the atoms and the field, mutually coupled. When only…

Quantum Physics · Physics 2017-02-24 Pablo Barcellona , Roberto Passante , Lucia Rizzuto , Stefan Yoshi Buhmann

Initially, we make a detailed historical survey of van der Waals forces, collecting the main references on the subject. Then, we review a method recently proposed by Eberlein and Zietal to compute the dispersion van der Waals interaction…

Quantum Physics · Physics 2016-07-25 Reinaldo de Melo e Souza , W. J. M. Kort-Kamp , C. Sigaud , C. Farina

A new scheme for the computation of dispersive interactions from first principles is presented. This cost-effective approach relies on a Wannier function representation compatible with density function theory descriptions. This is an…

Materials Science · Physics 2025-02-04 Diem Thi-Xuan Dang , Dai-Nam Le , Lilia M. Woods

Noncovalent van der Waals (vdW) interactions are responsible for a wide range of phenomena in matter. Popular density-functional methods that treat vdW interactions use disparate physical models for these intricate forces, and as a result…

Materials Science · Physics 2020-04-15 Jan Hermann , Alexandre Tkatchenko

We establish a general relation between dispersion forces. First, based on QED in causal media, leading-order perturbation theory is used to express both the single-atom Casimir-Polder and the two-atom van der Waals potentials in terms of…

Quantum Physics · Physics 2007-06-12 Stefan Yoshi Buhmann , Hassan Safari , Dirk-Gunnar Welsch , Ho Trung Dung

In this work the induced van der Waals interaction between a pair of neutral atoms or molecules is considered by use of a statistical mechanical method. Commonly this interaction is obtained by standard quantum mechanical perturbation…

Quantum Physics · Physics 2015-05-20 Johan S. Høye

The van der Waals dispersion interaction between two chiral molecules in the presence of arbirary magnetoelectric media is derived using perturbation theory. To be general, the molecular polarisabilities are assumed to be of electric,…

Quantum Physics · Physics 2020-06-24 Hassan Safari , Pablo Barcellona , Stefan Yoshi Buhmann , Akbar Salam

We consider the resonant van der Waals interaction between two correlated identical two-level atoms (at least one of which being excited) within the framework of macroscopic cavity quantum electrodynamics in linear, dispersing and absorbing…

Quantum Physics · Physics 2018-05-09 Saeideh Esfandiarpour , Robert Bennett , Hassan Safari , Stefan Yoshi Buhmann

We present an approach for computing long-range van der Waals (vdW) interactions between complex molecular systems and arbitrarily shaped macroscopic bodies, melding atomistic treatments of electronic fluctuations based on density…

Mesoscale and Nanoscale Physics · Physics 2017-07-05 Prashanth S. Venkataram , Jan Hermann , Alexandre Tkatchenko , Alejandro W. Rodriguez

Neutral atoms interact through a van der Waals potential which asymptotically falls off as r^{-6}. In ultracold gases, this interaction can be described to a good approximation by the atom-atom scattering length. However, corrections arise…

Other Condensed Matter · Physics 2009-11-13 Ryan M. Kalas , D. Blume

We calculate the non-retarded dispersion force exerted on an electrically polarizable quantum particle by a perfectly conducting toroid, which is one of the most common objects exhibiting a non-trivial topology. We employ a convenient…

Quantum Physics · Physics 2021-08-26 P. P. Abrantes , Yuri França , Reinaldo de Melo e Souza , F. S. S. da Rosa , C. Farina

The method recently developed to include Van der Waals interactions in the Density Functional Theory by using the Maximally-Localized Wannier functions, is improved and extended to the case of atoms and fragments weakly bonded (physisorbed)…

Other Condensed Matter · Physics 2009-11-13 Pier Luigi Silvestrelli , Karima Benyahia , Sonja Grubisic Francesco Ancilotto , Flavio Toigo

We introduce a class of variational wavefunctions that capture the long-range interaction between neutral systems (atoms and molecules) without changing the diagonal of the density matrix of each monomer. The corresponding energy…

Chemical Physics · Physics 2019-03-26 Derk P. Kooi , Paola Gori-Giorgi

We consider a multiatomic system where the nuclei are assumed to be point charges at fixed positions. Particles interact via Coulomb potential and electrons have pseudo-relativistic kinetic energy. We prove the van der Waals-London law,…

Mathematical Physics · Physics 2022-11-16 Jean-Marie Barbaroux , Michael Hartig , Dirk Hundertmark , Semjon Vugalter

We discuss different physical effects related to the uniform acceleration of atoms in vacuum, in the framework of quantum electrodynamics. We first investigate the van der Waals/Casimir-Polder dispersion and resonance interactions between…

Quantum Physics · Physics 2017-08-24 M. Lattuca , J. Marino , A. Noto , R. Passante , L. Rizzuto , S. Spagnolo , W. Zhou

We consider potential-based interactions between beams (or fibers) and shells (or membranes) using a coarse-grained approach with focus on van der Waals attraction and steric repulsion. The involved 6D integral over volumes of a beam and a…

Numerical Analysis · Mathematics 2026-03-02 Aleksandar Borković , Michael H. Gfrerer , Roger A. Sauer

Van der Waals torque determines the relative rotational motion between anisotropic objects, being of relevance to low-dimensional systems. Here we demonstrate a substantial torque between anisotropic two-dimensional materials that arises…

Computational Physics · Physics 2024-12-17 Zepu Kou , Yuquan Zhou , Zonghuiyi Jiang , Alexandre Tkatchenko , Xiaofei Liu

The atomic dipole polarizability, $\alpha$, and the van der Waals (vdW) radius, $R_{\rm vdW}$, are two key quantities to describe vdW interactions between atoms in molecules and materials. Until now, they have been determined independently…

Chemical Physics · Physics 2018-11-07 Dmitry V. Fedorov , Mainak Sadhukhan , Martin Stöhr , Alexandre Tkatchenko

We study theoretically the van der Waals interaction between two atoms out of equilibrium with isotropic electromagnetic field. We demonstrate that at large interatomic separations, the van der Waals forces are resonant, spatially…

Quantum Physics · Physics 2018-05-09 Yury Sherkunov

We obtain analytically the exact non-retarded dispersive interaction energy between an atom and a perfectly conducting disc. We consider the atom in the symmetry axis of the disc and assume the atom is predominantly polarizable in the…

High Energy Physics - Theory · Physics 2016-03-09 Reinaldo de Melo e Souza , W. J. M. Kort-Kamp , C. Sigaud , C. Farina