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Dispersion interactions such as the van der Waals interaction between atoms or molecules derive from quantum fluctuations of the electromagnetic field and can be understood as the exchange of virtual photons between the interacting…

Quantum Physics · Physics 2015-06-11 Harald R. Haakh , Stefan Scheel

We consider the interatomic van der Waals interaction energy between two neutral ground-state atoms moving in the vacuum space with the same uniform acceleration. We assume the acceleration orthogonal to their separation, so that their…

Quantum Physics · Physics 2013-07-25 Antonio Noto , Roberto Passante

Ubiquitous Van der Waals interactions between atoms and molecules are important for many molecular and solid structures. These systems are often studied from first principles using the Density Functional Theory (DFT). However, the commonly…

Materials Science · Physics 2009-11-13 Pier Luigi Silvestrelli

The van der Waals interaction between neutral atoms is typically studied using stationary perturbation theory for the short-distance (London) limit, while long-distance (Casimir-Polder) results are usually derived via semiclassical,…

Quantum Physics · Physics 2025-12-30 L. Saba , C. D. Fosco

Van der Waals forces as interactions between neutral and polarisable particles act at small distances between two objects. Their theoretical origin lies in the electromagnetic interaction between induced dipole moments caused by the vacuum…

Chemical Physics · Physics 2019-06-05 Johannes Fiedler , Clas Persson , Mathias Boström , Stefan Y. Buhmann

Using a recently obtained (general) formula for the interaction energy between an excited and a ground-state atom (Sherkunov Y 2007 Phys. Rev. A 75 012705), we consider the interaction energy between two such atoms near the interface…

Quantum Physics · Physics 2008-04-10 Marin-Slobodan Tomas

Using the general expressions for level shifts obtained from the master equation for a small system interacting with a large one considered as a reservoir, we calculate the dispersive potentials between an atom and a wall in the dipole…

Quantum Physics · Physics 2009-11-13 T. N. C. Mendes , C. Farina

In a framework for long-range density-functional theory we present a unified full-field treatment of the asymptotic van der Waals interaction for atoms, molecules, surfaces, and other objects. The only input needed consists of the electron…

Condensed Matter · Physics 2009-10-31 Erika Hult , Henrik Rydberg , Bengt I. Lundqvist , David C. Langreth

We consider the van der Waals interaction of an excited atom and a ground state atom across a vacuum-medium interface under the circumstances of the resonant coupling of the excited atom to a surface polariton mode of the system. We…

Quantum Physics · Physics 2015-05-13 Marin-Slobodan Tomas

Van der Waals interactions are ubiquitous and they play an important role for the stability of materials. Current understanding of this type of coupling is based on linear response theory, while optical nonlinearities are rarely considered…

Materials Science · Physics 2024-08-27 Dai-Nam Le , Pablo Rodriguez-Lopez , Lilia M. Woods

In the ultra-cold regime Van der Waals forces between neutral atoms can be represented by short range effective interactions. We show that universal low energy scaling features of the underlying vdW long range force stemming from two photon…

Other Condensed Matter · Physics 2015-05-20 E. Ruiz Arriola

The Lifshitz theory of the van der Waals force is extended for the case of an atom (molecule) interacting with a plane surface of an uniaxial crystal or with a long solid cylinder or cylindrical shell made of isotropic material or uniaxial…

Quantum Physics · Physics 2009-11-11 E. V. Blagov , G. L. Klimchitskaya , V. M. Mostepanenko

Van der Waals interactions between two neutral but polarizable systems at a separation $R$ much larger than the typical size of the systems are at the core of a broad sweep of contemporary problems in settings ranging from atomic, molecular…

High Energy Physics - Phenomenology · Physics 2017-06-14 Nora Brambilla , Vladyslav Shtabovenko , Jaume Tarrús Castellà , Antonio Vairo

The paper discusses a model of Van der Waals crystals in which band-gap structures do not form. An effect of strong and chaotic electron-electron repulsion, which was excluded from consideration in the traditional approach, is taken into…

Superconductivity · Physics 2007-05-23 V. N. Bogomolov

In some respects, a cluster consisting of many atoms may be regarded as a single large atom. Knowing the dielectric properties of such a cluster permits one to evaluate the form of the van der Waals (dispersion) interactions between two…

Soft Condensed Matter · Physics 2009-11-07 M. M. Calbi , S. M. Gatica , D. Velegol , M. W. Cole

We present a time-dependent quantum calculation of the van der Waals interaction between a pair of dissimilar atoms, one of which is initially excited while the other one is in its ground state. For small detuning, the interaction is…

Quantum Physics · Physics 2015-09-15 Manuel Donaire , Romain Guérout , Astrid Lambrecht

We study the interaction between a neutral atom or molecule and a conductor-patched dielectric surface. We model this system by a perfectly reflecting disc lying atop of a non-dispersive dielectric half-space, both interacting with the…

Quantum Physics · Physics 2015-06-11 Claudia Eberlein , Robert Zietal

A generalization of the quantum van der Waals equation of state for a multi-component system in the grand canonical ensemble is proposed. The model includes quantum statistical effects and allows to specify the parameters characterizing…

The electrostatic interaction between an excited atom and a diatomic ground state molecule in an arbitrary rovibrational level at large mutual separations is investigated with a general second-order perturbation theory, in the perspective…

Quantum Physics · Physics 2017-04-11 M. Lepers , R. Vexiau , N. Bouloufa , O. Dulieu , V. Kokoouline

We show how the image method can be used together with a recent method developed by C. Eberlein and R. Zietal to obtain the dispersive van der Waals interaction between an atom and a perfectly conducting surface of arbitrary shape. We…

High Energy Physics - Theory · Physics 2015-06-03 Reinaldo de Melo e Souza , W. J. M. Kort-Kamp , C. Sigaud , C. Farina