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We demonstrate that a bichromatic standing-wave laser field can exert a significantly larger force on a molecule than ordinary radiation pressure. Our experiment measures the deflection of a pulsed supersonic beam of CaF molecules by a…

Atomic Physics · Physics 2018-08-22 S. E. Galica , L. Aldridge , D. J. McCarron , E. E. Eyler , P. L Gould

A procedure for calculation of rotation-vibration states of medium sized molecules is presented. It combines the advantages of variational calculations and perturbation theory. The vibrational problem is solved by diagonalizing a…

Chemical Physics · Physics 2015-04-13 A. I. Pavlyuchko , S. N. Yurchenko , Jonathan Tennyson

We consider the use of pulse-shaped broadband femtosecond lasers to optically cool rotational and vibrational degrees of freedom of molecules. Since this approach relies on cooling rotational and vibrational quanta by exciting an electronic…

Atomic Physics · Physics 2017-09-13 Chien-Yu Lien , Scott R. Williams , Brian Odom

Sympathetic cooling of molecular ions through the Coulomb interaction with laser-cooled atomic ions is an efficient tool to prepare translationally cold molecules without, ideally, affecting the internal state of the molecular ions.…

Quantum Physics · Physics 2026-04-20 J. Martin Berglund , Michael Drewsen , Christiane P. Koch

We have developed and experimentally demonstrated an improved electrostatic deflector for the spatial separation of molecules according to their dipole-moment-to-mass ratio. The device features a very open structure that allows for…

Chemical Physics · Physics 2017-07-25 Jens S. Kienitz , Karol Długołecki , Sebastian Trippel , Jochen Küpper

Microscopic control over polar molecules with tunable interactions would enable realization of novel quantum phenomena. Using an applied electric field gradient, we demonstrate layer-resolved state preparation and imaging of ultracold…

We consider the problem of discriminating macromolecular structures in an electron microscope, through a specific beam shaping technique. Our approach is based on maximizing the which-molecule information extracted from the state of each…

The equations of motion for the molecular rotation are derived for vibrationally cold dimers that are polarized by off-resonant laser light. It is shown that, by eliminating electronic and vibrational degrees of freedom, a quantum master…

Quantum Physics · Physics 2009-11-10 A. Adelswaerd , S. Wallentowitz , W. Vogel

Single molecule imaging is one of the main target areas of X-ray free electron lasers. It relies on the possibility of orienting the large number of low counting statistics 2D diffraction patterns taken at random orientations of identical…

Atomic and Molecular Clusters · Physics 2012-11-30 Zoltan Jurek , Gyula Faigel

Experiments and computer simulations are carried out to investigate ordering principles in a granular gas which phase separates under vibration. The densities of the dilute and the dense phase are found to follow a lever rule. A Maxwell…

Soft Condensed Matter · Physics 2015-03-03 James P. D. Clewett , Jack Wade , R. M. Bowley , Stephan Herminghaus , Michael R. Swift , Marco G. Mazza

A method of slowing, accelerating, cooling, and bunching molecules and neutral atoms using time-varying electric field gradients is demonstrated with cesium atoms in a fountain. The effects are measured and found to be in agreement with…

Atomic Physics · Physics 2009-10-31 Jason A. Maddi , Timothy P. Dinneen , Harvey Gould

Quantum process tomography is used to fully characterize the evolution of the quantum vibrational state of atoms. Rubidium atoms are trapped in a shallow optical lattice supporting only two vibrational states, which we charcterize by…

Quantum Physics · Physics 2007-05-23 S. H. Myrskog , J. K. Fox , M. W. Mitchell , A. M. Steinberg

We consider bosonic dipolar molecules in an optical lattice prepared in a mixture of different rotational states. The 1/r^3 interaction between molecules for this system is produced by exchanging a quantum of angular momentum between two…

Strongly Correlated Electrons · Physics 2009-11-11 Ryan Barnett , Dmitry Petrov , Mikhail Lukin , Eugene Demler

We introduce a new optical tool - a "two-dimensional optical centrifuge", capable of aligning molecules in extreme rotational states. Unlike the conventional centrifuge, which confines the molecules in the plane of their rotation, its…

Chemical Physics · Physics 2016-05-18 A. A. Milner , A. Korobenko , V. Milner

Atomic vibrations control all thermally activated processes in materials including diffusion, heat transport, phase transformations, and surface chemistry. Recent developments in monochromated, aberration-corrected scanning transmission…

Materials Science · Physics 2020-01-08 Kartik Venkatraman , Barnaby D. A. Levin , Katia March , Peter Rez , Peter A. Crozier

In this study, we apply the monitoring master equation describing decoherence of internal states to an optically active molecule prepared in a coherent superposition of nondegenerate internal states interacting with thermal photons at low…

Quantum Physics · Physics 2013-11-19 Farhad Taher Ghahramani , Afshin Shafiee

The recent progress towards production of near-ground state quantum-degenerate molecules raises the issue of how such "small" molecules behave in an optical lattice. In this Letter we show that the coupling of the molecular orientation to…

Other Condensed Matter · Physics 2007-07-09 J. R. Holt , J. M. F. Gunn

We, based on the photoassociation of fermion atoms into bosonic molecules, propose a scheme to create the steady entanglement between the atom state and the molecule state inside an optical lattice. The stability of entanglement state is…

Quantum Physics · Physics 2007-05-23 P. Zhang , H. T. Quan , C. P. Sun

We measure molecular vibrations with femtometer precision using time-resolved x-ray absorption spectroscopy. For a demonstration, a Raman process excites the A$_{1g}$ mode in gas-phase SF$_6$ molecules with an amplitude of $\approx50$ fm,…

We demonstrate Doppler-free saturated absorption spectroscopy of cold molecular radicals formed by laser ablation inside a cryogenic buffer gas cell. By lowering the temperature, congested regions of the spectrum can be simplified, and by…