Related papers: Variational calculations on the hydrogen molecular…
The binding energies of argon dimer are calculated by solving the homogeneous Lippmann-Schwinger integral equation in momentum space. Our numerical analysis using two models of argon-argon interaction developed by Patkowski {\it et al.}…
We present experimental observations of seven vibrational levels $v'=20-26$ of the $1^{3}\Sigma_{g}^{+}$ excited state of Li$_2$ molecules by the photoassociation (PA) of a degenerate Fermi gas of $^6$Li atoms. For each vibrational level,…
Novel methods for diagnostics of molecular hydrogen plasma processes, such as ionization, production of high vibrational levels, dissociation of molecules via excitation to singlet and triplet states and production of metastable states, are…
We consider the application of a basic principle of quantum theory, the tracelessness of a certain class of hamiltonians, to the precision spectroscopy of the molecular hydrogen ions. We show that it is possible to obtain the spin-averaged…
Nonadiabatic corrections in molecules composed of a few atoms are considered. It is demonstrated that a systematic perturbative expansion around the adiabatic solution is possible, with the expansion parameter being the electron-nucleus…
The precise measurement of molecular vibrational transition frequencies is useful in the search for variation in the proton-to-electron mass ratio {\mu}. Homonuclear diatomic molecules are particularly advantageous for precise measurement…
Peculiarities of the intermolecular rovibrational quantum dynamics of the methane-argon complex are studied using a new, ab initio potential energy surface [Y. N. Kalugina, S. E. Lokshtanov, V. N. Cherepanov, and A. A. Vigasin, J. Chem.…
The mutual neutralization of H^+ and H^- ions at low collision energies is studied by means of a molecular close-coupling approach. All degrees of freedom are treated at the full quantum level taking into account also the identity of the…
The nonrelativistic energy together with relativistic and quantum electrodynamic corrections for all the molecular hydrogen isotopologues (D$_2$, T$_2$, HD, HT, DT) were evaluated without expansion in the electron-nucleus mass ratio. The…
Rovibrational transitions in the hydrogen and antihydrogen molecular ions $H_2^+$ and $\overline{H}_2^-$ offer the possibility of testing Lorentz and CPT symmetry to extremely high precision, in principle attaining $O(10^{-17})$. In this…
We compute the energy levels of a 2D Hydrogen atom when a constant magnetic field is applied. With the help of a mixed-basis variational method and a genera lization of virial theorem, which consists in scaling the wave function, we…
A detailed quantitative analysis of the system $(ppe)$ placed in magnetic field ranging from $0 - 4.414 \times 10^{13} G$ is presented. The present study is focused on the question of the existence of the molecular ion $H_2^{+}$ in a…
Improved values of hyperfine coefficients related to the electronic spin-orbit and electron-nucleus spin-spin tensor interactions in the HD$^+$ molecular ion are obtained through numerical calculation of relativistic corrections at the…
The pulsed-field-ionization zero-kinetic-energy photoelectron spectrum of H$_2$ has been recorded in the vicinity of the dissociative-ionization threshold following three-photon excitation via selected rotational levels of the B…
Calculation of the rotation-vibration spectrum of H3+, as well as of its deuterated isotopologues, with near-spectroscopic accuracy requires the development of sophisticated theoretical models, methods, and codes. The present paper reviews…
We present benchmark integrated and differential cross-sections for electron collisions with H$_2$ using two different theoretical approaches, namely, the R-matrix and molecular convergent close-coupling (MCCC). This is similar to…
We combined high-resolution Fourier-transform spectroscopy and large-scale electronic structure calculation to study energy and radiative properties of the high-lying (3)1{\Pi} and (5)1{\Sigma}+ states of the RbCs molecule. The…
The vibrational branching ratios of SrOH for radiative decay to the ground electronic state, $X^{2}\Sigma^{+}$, from the first two electronically excited states, $A^{2}\Pi$ and $B^{2}\Sigma^{+}$, are determined experimentally at the…
The computation of strongly correlated quantum systems is challenging because of its potentially exponential scaling in the number of electron configurations. Variational calculation of the two-electron reduced density matrix (2-RDM)…
We present a quantum mechanical study of the diatomic hydrogen $H(^{2}S)$ and oxygen $O(^{3}P)$ collision and energy transfer for its four molecular symmetry $(X^{2}\Pi, ^{2}\Sigma^{-}, ^{4}\Pi, ^{4}\Sigma^{-})$, which is important for the…