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We determine the structure and energetics of complexes of the linear OCS molecule with small numbers of para-hydrogen molecules, N=1-8, using zero temperature quantum Monte Carlo methods. Ground state calculations are carried out with…

Atomic and Molecular Clusters · Physics 2009-11-10 F. Paesani , R. E. Zillich , K. B. Whaley

The electronic structure of Pr$_{1-x}$Ca$_x$MnO$_3$ has been investigated using a combination of first-principles calculations, X-ray photoelectron spectroscopy (XPS), X-ray absorption spectroscopy (XAS), electron-energy loss spectroscopy…

Being motivated by recent experimental studies, we investigate magnetic structures of the Mo pyrochlores $A_2$Mo$_2$O$_7$ ($A$= Y, Nd, and Gd) and their impact on the electronic properties. The latter are closely related with the behavior…

Strongly Correlated Electrons · Physics 2009-11-07 I. V. Solovyev

By a combination of Hartree-Fock simulations, exact diagonalization, and perturbative calculations, we investigate the ground-state properties of disorder-free circular quantum dots formed in a graphene monolayer. Taking the reference…

Mesoscale and Nanoscale Physics · Physics 2011-11-01 Tomi Paananen , Reinhold Egger

By molecular dynamics simulations and free energy calculations based on Monte Carlo method, the detailed balance between Pt cluster isomers was investigated. For clusters of n<=50, stationary equilibrium is achieved in 100 ns in the…

Chemical Physics · Physics 2014-12-16 Zheng-Zhe Lin

Both even- and odd-numbered neutral carbon clusters Cn (n = 2-10) are systematically studied using the energy minimization method and the modified Brenner potential for the carbon-carbon interactions. Many stable configurations were found…

Materials Science · Physics 2009-11-13 D. P. Kosimov , A. A. Dzhurakhalov , F. M. Peeters

Using a diverse set of 100 oligothiophenes, extrapolated oligomer and polymer HOMO, LUMO and HOMO-LUMO gaps are shown to be accurately estimated from the computed values of the trimer HOMO, trimer LUMO and trimer HOMO-LUMO gaps. These…

Applied Physics · Physics 2017-07-03 Ilana Y. Kanal , Steven G. Owens , Andrey B. Sharapov , Geoffrey R. Hutchison

We describe the ground- and excited-state electronic structure of bulk MnO and NiO, two prototypical correlated electron materials, using coupled cluster theory with single and double excitations (CCSD). As a corollary, this work also…

We discuss a novel technique of manipulating X-ray images of galaxy clusters to reveal the nature of small-scale density/temperature perturbations in the intra cluster medium (ICM). As we show, this technique can be used to differentiate…

Cosmology and Nongalactic Astrophysics · Physics 2016-08-24 E. Churazov , P. Arevalo , W. Forman , C. Jones , A. Schekochihin , A. Vikhlinin , I. Zhuravleva

The accurate determination of the preferred ${\rm Si}_{12}{\rm C}_{12}$ isomer is important to guide experimental efforts directed towards synthesizing SiC nano-wires and related polymer structures which are anticipated to be highly…

Metal-organic frameworks (MOFs) are highly interesting and tunable materials. By incorporating spatial defects into their atomic structure, MOFs can be finetuned to exhibit precise chemical functionalities, extending their applicability in…

Materials Science · Physics 2025-04-08 Pieter Dobbelaere , Sander Vandenhaute , Veronique Van Speybroeck

Using spin polarized density functional theory (DFT) based calculations, combined with ab-initio molecular dynamics simulation, we carry out a systematic investigation of the bimetallic Ni$_{13-n}$Ag$_n$ nano clusters, for all compositions.…

Materials Science · Physics 2017-05-04 Soumendu Datta , A. K. Raychaudhuri , Tanusri Saha-Dasgupta

The quasiparticle band structures of nonmagnetic monoxides, MO (M=Mg, Ca, Ti, and V), are calculated by the GW approximation. The band gap and the width of occupied oxygen 2p states in insulating MgO and CaO agree with experimental…

Materials Science · Physics 2009-11-07 Atsushi Yamasaki , Takeo Fujiwara

We present XMM-Newton studies of the total mass, gas density, temperature and entropy profiles in nearby hot and cool clusters, together with follow-up observations of distant clusters from the SHARC Survey. The observed structural and…

Astrophysics · Physics 2007-05-23 M. Arnaud , G. W. Pratt , E. Pointecouteau

We report on the structure and adsorption properties of Pd$_n$ ($n=1-4$) clusters supported on the rutile TiO$_2$ (110) surfaces with the possible presence of a surface oxygen vacancy or a subsurface Ti-interstitial atom. As predicted by…

Materials Science · Physics 2012-04-12 Jin Zhang , Anastassia N. Alexandrova

A crystalline form of LiBC is known which has been predicted to be superconducting, with a Tc comparable to that of MgB_2. In both compounds, superconductivity is enhanced by the presence of two electronic bands, one of which is close to a…

Atomic and Molecular Clusters · Physics 2007-05-23 G. M. Lombardo , A. Grassi , G. Forte , G. G. N. Angilella , R. Pucci , N. H. March

The variational cluster approximation proposed by Potthoff is applied to the calculation of the single-particle spectral function of the transition metal oxides MnO, CoO and NiO. Trial self-energies and the numerical value of the…

Strongly Correlated Electrons · Physics 2009-11-13 R. Eder

We have performed full-relativistic density functional theory calculations to study the geometry and binding energy of different isomers of free platinum clusters Pt$_{n}$ ($n=4-6$) within the spin multiplicities from singlet to nonet. The…

Atomic and Molecular Clusters · Physics 2016-07-06 Ali Sebetci

We present a study on the inference of cosmological and astrophysical parameters using stacked galaxy cluster profiles. Utilizing the CAMELS-zoomGZ simulations, we explore how various cluster properties--such as X-ray surface brightness,…

We present an analytic ansatz to find the effective electrostatic potential and Coulomb correlations in multicenter problems, specifically homogeneous and doped clusters of metal atoms. The approach is based on a quasi-classical…

Chemical Physics · Physics 2007-05-23 F. Despa , R. S. Berry