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We use density functional theory (DFT) to investigate the electronic structure and chemical properties of gold nanoparticles. Different structural families of clusters are compared. For up to 60 atoms we optimize structures using DFT-based…

We present a force-biased Monte Carlo (FMC) method for structural modeling of transition metal clusters of Fe, Ni, and Cu with 5 to 60 atoms. By employing the Finnis-Sinclair potential for Fe and the Sutton-Chen potential for Ni and Cu, the…

Materials Science · Physics 2017-12-06 Dil K. Limbu , Parthapratim Biswas

Nuclear clustering describes the appearance of structures resembling smaller nuclei such as alpha particles (4He nuclei) within the interior of a larger nucleus. While clustering is important for several well-known examples, much remains to…

The properties of hydrogen at warm dense matter (WDM) conditions are of high importance for the understanding of astrophysical objects and technological applications such as inertial confinement fusion. In this work, we present extensive…

Plasma Physics · Physics 2023-06-12 Tobias Dornheim , Maximilian Böhme , Zhandos Moldabekov , Jan Vorberger

Using the embedded-atom method, the structure of small copper clusters on Au(111) electrodes has been investigated both by static and dynamic calculations. By varying the size of roughly circular clusters, the edge energy per atom is…

Materials Science · Physics 2007-05-23 M. G. Del Popolo , E. P. M. Leiva , W. Schmickler

Electronic structures of 13-atom Rh clusters with three possible high-symmetry geometries are studied using the discrete-variational local-spin-density-functional method. The ground state is found to be the icosahedral structure, and a…

Condensed Matter · Physics 2007-05-23 Yang Jinlong , F. Toigo , Wang Kelin , Zhang Manhong

The spectra of quantum dots of different geometry (``quantum ring'', ``quantum cylinder'', ``spherical square-well'' and ``parabolic confinement'') are studied. The stochastic variational method on correlated Gaussian basis functions and a…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 K. Varga , P. Navratil , J. Usukura , Y. Suzuki

We have investigated energies and spectroscopic properties such as lifetimes, $g_J$ factors, and hyperfine structure constants of the neutral atoms P through Mc belonging to Group-15, singly ionized atoms S$^+$ through Lv$^+$ of Group-16…

Atomic Physics · Physics 2023-06-29 H. X. Liu , Y. M. Yu , B. B. Suo , Y. Liu , B. K. Sahoo

We numerically examine divergences of the total energy in metallic systems of approximate many-body theories using Hartree--Fock as a reference, including perturbative (M\oller-Plesset, MP), coupled cluster (CC) and configuration…

Chemical Physics · Physics 2012-08-31 James J. Shepherd , Andreas Grüneis

Theoretical studies on M$_{13}$ (M = Fe, Co, Ni) and M$_{13}$Pt$_n$ (for $n$ = 3, 4, 5, 20) clusters including the spin-orbit coupling are done using density functional theory. The magnetic anisotropy energy (MAE) along with the spin and…

The lowest energy configurations of close-packed clusters up to N=110 atoms with stacking faults are studied using the Monte Carlo method with Metropolis algorithm. Two types of contact interactions, a pair-potential and a many-atom…

Atomic and Molecular Clusters · Physics 2009-11-10 K. Manninen , J. Akola , M. Manninen

The multi-configuration Dirac-Hartree-Fock method was employed to calculate the total and excitation energies, oscillator strengths and hyperfine structure constants for low-lying levels of Sm I. In the first-order perturbation…

Atomic Physics · Physics 2015-09-16 Fuyang Zhou , Yizhi Qu , Jiguang Li , Jianguo Wang

We report on the magnetic properties of Co$\_x$Pt$\_{1-x}$ clusters embedded in various matrices. Using a careful analysis of magnetization curves and ZFC susceptibility measurements, we determine the clusters magnetic anisotropy energy…

Materials Science · Physics 2016-08-16 Stanislas Rohart , Cécile Raufast , Luc Favre , Estela Bernstein , Edgar Bonet , Véronique Dupuis

The adsorption profiles and electronic structures of Pt$_n$ (n = 1--4) clusters on stoichiometric, reduced and reconstructed rutile TiO$_2$(110) surfaces were systematically studied using on site d-d Coulomb interaction corrected hybrid…

Strongly Correlated Electrons · Physics 2011-01-06 Veysel Celik , Hatice Unal , Ersen Mete , Sinasi Ellialtioglu

Spin-polarized DFT has been used to perform a comprehensive study of the geometric structures and electronic properties for isolated M4X4 nano-clusters between their two stable isomers - a planar rhombus-like 2D structure and a cubane-like…

Mesoscale and Nanoscale Physics · Physics 2015-12-29 Soumendu Datta , Badiur Rahaman

There has long been a discrepancy between the size distributions of Ar$_n^+$ clusters measured by different groups regarding whether or not magic numbers appear at sizes corresponding to the closure of icosahedral (sub-)shells. We show that…

Atomic and Molecular Clusters · Physics 2019-12-04 Michael Gatchell , Paul Martini , Lorenz Kranabetter , Bilal Rasul , Paul Scheier

The structure and magnetic properties of Co clusters, comprising from 26 to 2700 atoms, self-organized or not on the graphene/Ir(111) moir\'e, were studied in situ with the help of scanning tunneling microscopy and X-ray magnetic circular…

Geometry, electronic structure, and magnetic properties of TMNan (TM=Cr-Ni; n = 4-7) clusters are studied within a gradient corrected density functional theory (DFT) framework. Two complementary approaches, the first adapted to all-electron…

Materials Science · Physics 2017-09-13 Kalpataru Pradhan , Prasenjit Sen , J. Ulises Reveles , Shiv N. Khanna

The present work reports results from systematic multiconfiguration Dirac-Hartree-Fock calculations of isotope shifts for several well-known transitions in neutral magnesium. Relativistic normal and specific mass shift factors as well as…

Atomic Physics · Physics 2016-07-13 Livio Filippin , Michel Godefroid , Jörgen Ekman , Per Jönsson

The spectroscopic properties of the odd-odd isotopes $^{124-132}$Cs have been studied within the interacting boson-fermion-fermion model based on the Gogny-D1M energy density functional framework. Major ingredients to build the interacting…

Nuclear Theory · Physics 2020-01-15 K. Nomura , R. Rodríguez-Guzmán , L. M. Robledo
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