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Precision spectroscopy on cold molecules can potentially enable novel tests of fundamental laws of physics and alternative determination of some fundamental constants. Realizing this potential requires a thorough understanding of the…

Atomic Physics · Physics 2013-05-29 Dimitar Bakalov , Vladimir I. Korobov , Stephan Schiller

The electromagnetic interactions of electrons and muons can be described to very high accuracy within the framework of standard theory, in particular within the hydrogen-like muonium atom. Therefore precision measurements allow to test…

Atomic Physics · Physics 2016-09-08 Klaus Jungmann

High precision radio-frequency, microwave and infrared spectroscopic measurements of the antihydrogen molecular ion $\bar{H}_{2}^{-}$ ($\bar{p}\bar{p}e^{+}$) compared with its normal matter counterpart provide direct tests of the CPT…

Atomic Physics · Physics 2018-07-30 Edmund G. Myers

Recently we reported a high precision optical frequency measurement of the (v,L):(0,2)->(8,3) vibrational overtone transition in trapped deuterated molecular hydrogen (HD+) ions at 10 mK temperature. Achieving a resolution of 0.85…

Atomic Physics · Physics 2017-02-20 J. Biesheuvel , J. -Ph. Karr , L. Hilico , K. S. E. Eikema , W. Ubachs , J. C. J. Koelemeij

A theoretical model of hyperfine spectra of nuclear spin conversion of molecular isomers has been developed. The model takes into account the nuclear spin-spin and spin-rotation interactions, as well as the saturation of intramolecular…

Chemical Physics · Physics 2009-11-06 Pavel L. Chapovsky

Understanding the hydration and diffusion of ions in water at the molecular level is a topic of widespread importance. The ammonium ion (NH$_4^+$) is an exemplar system that has received attention for decades because of its complex…

Computational Physics · Physics 2025-01-14 Jianqing Guo , Liying Zhou , Andrea Zen , Angelos Michaelides , Xifan Wu , Enge Wang , Limei Xu , Ji Chen

The fine structure of hydrogen energy was calculated by using the usual momentum-wavefunction relation directly, rather than establishing the well-known Dirac wave equation. As the results, the energy levels are completely the same as that…

General Physics · Physics 2007-05-23 H. Y. Cui

The spin-averaged structure function of the neutron, F_2^n, is extracted from recent deuteron data, taking into account the small but significant corrections due to nuclear effects in the deuteron. At small x, the F_2D/F_2p ratio measured…

Nuclear Theory · Physics 2010-02-17 W. Melnitchouk , A. W. Thomas

The theoretical aspects of spin-rotation coupling are presented. The approach is based on the general covariance principle. It is shown that the gyrogravitational ratio of the bare spin-1/2 and the spin-1 particles is equal unity. That is…

Atomic Physics · Physics 2009-08-03 Igor M. Pavlichenkov

We report progress on nuclear structure functions, especially on their nuclear modifications and a new tensor structure function for the deuteron. To understand nuclear structure functions is an important step toward describing nuclei and…

High Energy Physics - Phenomenology · Physics 2016-04-20 S. Kumano

In this work, we calculate the hyperfine-structure constants of the $^{45}$Sc$^{+}$ ion using a relativistic hybrid approach that combines configuration-interaction and coupled-cluster singles-and-doubles methods. Magnetic-dipole and…

Atomic Physics · Physics 2026-05-12 Yong-Bo Tang , Yu-Shan Zhang , Kai Wang

We investigate the leading systematic effects in ro-vibrational spectroscopy of the molecular hydrogen ions H2+ and HD+, in order to assess their potential for the realization of optical clocks that would be sensitive to possible variations…

Atomic Physics · Physics 2017-02-20 Jean-Philippe Karr

Improved values of hyperfine coefficients related to the electronic spin-orbit and electron-nucleus spin-spin tensor interactions in the HD$^+$ molecular ion are obtained through numerical calculation of relativistic corrections at the…

Atomic Physics · Physics 2022-11-09 Mohammad Haidar , Vladimir I. Korobov , Laurent Hilico , Jean-Philippe Karr

An effective Hamiltonian without symmetry restriction has been developed to model the rotational and fine structure of two nearly degenerate electronic states of an open-shell molecule. In addition to the rotational Hamiltonian for an…

Chemical Physics · Physics 2018-04-18 Jinjun Liu

We determine the Zemach moments of hydrogen and deuterium for the first time using only the world data on elastic electron-proton and electron-deuteron scattering. Such moments are required for the calculation of the nuclear corrections to…

Nuclear Theory · Physics 2014-11-18 J. L. Friar , Ingo Sick

We derive relations between spin-dependent nuclear and nucleon g_1 and g_2 structure functions within the nuclear impulse approximation, which are valid at all Q^2, and in both the resonance and deep inelastic regions. We apply the…

Nuclear Theory · Physics 2008-11-26 S. A. Kulagin , W. Melnitchouk

We develop a model for predicting fine- and hyperfine intensities in the direct photoionization of molecules based on the separability of electron and nuclear spin states from vibrational-electronic states. Using spherical tensor algebra,…

Chemical Physics · Physics 2016-08-24 Matthias Germann , Stefan Willitsch

A method for precise calculation of the energy corrections due to second order electric quadrupole interactions, as well as mixed electric quadrupole-vacuum polarization in the framework of the dynamic hyperfine structure in heavy muonic…

Atomic Physics · Physics 2019-04-10 Niklas Michel , Natalia S. Oreshkina

Recent laboratory experiments have measured fusion cross sections at center-of-mass energies low enough for the effects of atomic and molecular electrons to be important. To extract the cross section for bare nuclei from these data (as…

Nuclear Theory · Physics 2009-10-28 T. D. Shoppa , M. Jeng , S. E. Koonin , K. Langanke , R. Seki

The hydrogen-like muonium atom ($\mu^+e^-$) consists of a positive muon ($\mu^+$) and an electron ($e^-$). Since it was first observed by Hughes et al. in 1960, a series of precision experiments could be carried out testing bound state…

Atomic Physics · Physics 2016-09-08 K. Jungmann