English

Hyperfine spectra of CH3F nuclear spin conversion

Chemical Physics 2009-11-06 v1 Atomic Physics

Abstract

A theoretical model of hyperfine spectra of nuclear spin conversion of molecular isomers has been developed. The model takes into account the nuclear spin-spin and spin-rotation interactions, as well as the saturation of intramolecular mixing of molecular ortho and para states. The model has been applied to hyperfine spectra of nuclear spin conversion in ^{13}CH3F molecules subjected to an external electric field. Conditions under which the hyperfine structure in the spectra can be resolved have been determined.

Keywords

Cite

@article{arxiv.physics/0004038,
  title  = {Hyperfine spectra of CH3F nuclear spin conversion},
  author = {Pavel L. Chapovsky},
  journal= {arXiv preprint arXiv:physics/0004038},
  year   = {2009}
}

Comments

12 pages + 7 eps figures, REVTEX