Related papers: Hyperfine spectra of CH3F nuclear spin conversion
A complete theoretical model of the nuclear spin conversion in 13CH3F induced by intramolecular ortho-para state mixing is proposed. The model contains parameters determined from the level-crossing spectra of the 13CH3F spin conversion.…
Theoretical model of the coherent control of nuclear spin isomers by microwave radiation has been developed. Model accounts the M-degeneracy of molecular states and molecular center-of-mass motion. The model has been applied to the 13CH3F…
Except for ortho- and para-H2, very little is known about nuclear spin isomers (or spin modifications) of molecules. The main reason is the lack of practical enrichment techniques. Recently a few enrichment methods were developed, which…
We investigate the microwave spectra of ultracold alkali metal dimers in magnetic, electric and combined fields, taking account of the hyperfine structure due to the nuclear spins. We consider the molecules 41K87Rb and 7Li133Cs, which are…
Among the possible types of magnetic dipole interactions in molecular systems, couplings between nuclear motion and the nuclear spin have probably received the least attention in molecular spectroscopy. Although very small in comparison to…
The nuclear spin--rotation interaction in the hyperfine structure of the hydrogen molecular ion is investigated. The interaction constants are determined and are found to differ in sign and magnitude compared to another theory, but they are…
Enrichment of nuclear spin isomers of molecules by infrared radiation resonant to molecular rovibrational transition is considered. Special attention is given to the enrichment by light-induced crossing of far separated ortho and para…
A theoretical model of nuclear spin conversion in molecules controlled by an external electromagnetic radiation resonant to rotational transition has been developed. It has been shown that one can produce an enrichment of spin isomers and…
We demonstrate ionization of a molecule with the bias voltage of a Scanning Tunnelling Microscope (STM) resulting in a coexistence of a neutral and ionic molecules, i.e. radical (paramagnetic) and non-radical (diamagnetic) states. This…
The study of hyperfine interactions in optically excited fullerenes has recently acquired importance within the context of nuclear spin entanglement for quantum information technology. We here report a first-principles pseudopotential study…
Spin polarized states in nuclear matter with an effective nucleon-nucleon interaction are studied for a wide range of isospin asymmetries and densities. Based on a Fermi liquid theory, it is shown that there are a few possible scenarios of…
Optically active spin defects in solids offer promising platforms to investigate nuclear spin clusters with high sensitivity and atomic-site resolution. To leverage near-surface defects for molecular structure analysis in chemical and…
We study theoretically the spin fluctuations of nuclei in quantum dots. We employ the central spin model which accounts for the hyperfine interaction of the nuclei with the electron spin. We present an analytical solution in the frame of…
Theoretical investigations of the hyperfine structure of the hydrogen molecular ion (one electron and two protons) are discussed. The nuclear spin-rotation interaction has been found to be of the same sign as in the hydrogen molecule and…
Nuclear spins and paramagnetic centers in a solid randomly group to form clusters featuring nearly-degenerate, hybrid states whose dynamics are central to processes involving nuclear spin-lattice relaxation and diffusion. Their…
Hybridized nuclear and electron spin excitation in a MnCO$_3$ crystal, a weakly-anisotropic antiferromagnet, has been investigated. In this material, the hyperfine interaction is strong enough to form a nuclear spin wave. We measure the…
The symmetrized contribution of E-type spin-rotation interaction to conversion between spin modifications of E- and A_1-types in molecules with C_{3v}-symmetry is considered. Using the high-J descending of collisional broadening for…
Hyperfine interactions, magnetic interactions between the spins of electrons and nuclei, in graphene and related carbon nanostructures are studied. By using a combination of accurate first principles calculations on graphene fragments and…
We report on a new phenomenon of molecular nuclear spin isomers conversion in the field of resonant laser radiation. It is based on the isomer-selective optical excitation and the difference of conversion rates for excited and unexcited…
The rotational and hyperfine spectrum of the $X^1\Sigma^+ \rightarrow B^3\Pi_1$ transition in TlF molecules was measured using laser-induced fluorescence from both a thermal and a cryogenic molecular beam. Rotational and hyperfine constants…