Related papers: Cold Molecule Spectroscopy for Constraining the Ev…
We have measured the frequency splitting between the $(2S, F=1/2)$ and $(2S, F=3/2)$ hyperfine sublevels in atomic deuterium by an optical differential method based on two-photon Doppler-free spectroscopy on a cold atomic beam. The result…
Accurate $EF{}^1\Sigma^+_g-X{}^1\Sigma^+_g$ transition energies in molecular hydrogen were determined for transitions originating from levels with highly-excited vibrational quantum number, $v=11$, in the ground electronic state.…
The CH radical offers a sensitive way to test the hypothesis that fundamental constants measured on earth may differ from those observed in other parts of the universe. The starting point for such a comparison is to have accurate laboratory…
[O III]$\lambda\lambda$4960,5008 doublet are often the strongest narrow emission lines in starburst galaxies and quasi-stellar objects (QSOs), and thus are a promising probe to possible variation of the fine-structure constant $\alpha$ over…
We propose a new spectroscopic method for measuring weak transitions in cold and trapped atoms, which exploits the long interaction times and tight confinement offered by dark optical traps together with an electron shelving technique to…
We present a detailed analysis of an application of frequency modulation (FM) spectroscopy in the high modulation depth limit. We have recently completed and reported a measurement of the Stark shift in the indium $5p_{1/2}\rightarrow…
We describe an instrument which can be used to analyze complex chemical mixtures at high resolution and high sensitivity. Molecules are collisionally cooled with helium gas at cryogenic temperatures (~ 4-7 K), and subsequently detected…
HOCO$^+$ is a polar molecule that represents a useful proxy for its parent molecule CO$_2$, which is not directly observable in the cold interstellar medium. This cation has been detected towards several lines of sight, including massive…
The Stark effect provides a powerful method to shift the spectra of molecules, atoms and electronic transitions in general, becoming one of the simplest and most straightforward way to tune the frequency of quantum emitters by means of a…
We report deep Green Bank Telescope spectroscopy in the redshifted HI 21cm and OH 18cm lines from the $z = 0.765$ absorption system towards PMN J0134-0931. A comparison between the "satellite" OH 18cm line redshifts, or between the…
Hydroxyl (OH) is expected to be abundant in diffuse interstellar molecular gas as it forms along with $H_2$ under similar conditions and within a similar extinction range. We have analyzed absorption measurements of OH at 1665 MHz and 1667…
Measuring the hyperfine structure (HFS) of long-lived $^3P_2$ states of divalent atoms may offer the opportunity of extracting relatively unexplored nuclear magnetic octupole and electric hexadecapole moments. Here, using relativistic…
The hyperfine structure of atoms and ions is widely used in fundamental and applied research. Accurate knowledge of hyperfine splitting values is essential for quantum metrology applications as well as for improving the performance of…
Femtosecond coherent multidimensional spectroscopy is demonstrated for an ultracold gas. For this, a setup for phase modulation spectroscopy is used to probe the $3^2\mathrm{S}_{1/2} - 2^2\mathrm{P}_{1/2, 3/2}$ transition in an 800…
Precision determination of the hyperfine splitting of cadmium ions is essential to study space-time variation of fundamental physical constants and isotope shifts. In this work, we present the precision frequency measurement of the…
High-resolution spectroscopy on the $A^2\Pi$ - $X^2\Sigma^+$ electronic system of $^{138}$Ba$^{19}$F is performed using a cold molecular beam produced by a buffer gas source. The hyperfine structure in both $X^2\Sigma^+$ ground and $A^2\Pi$…
We present precise, sub-wavelength optical intensity measurement using a single trapped $^{87}$Rb atom as a sensor. The intensity is measured by the scalar ac Stark shift it produces on the $F=1 \rightarrow F'=2$ hyperfine transition of the…
We utilize two-photon high-precision microwave spectroscopy of $ng\rightarrow(n+2)g$ transitions to precisely measure the high-angular-momentum $g$-series quantum defect of $^{85}$Rb. Samples of cold Rydberg atoms in the $ng$ state are…
We used a Cs atomic fountain frequency standard to measure the Stark shift on the ground state hyperfine transiton frequency in cesium (9.2 GHz) due to the electric field generated by the blackbody radiation. The measures relative shift at…
We use accurate quantum mechanical calculations to analyze the effects of parallel electric and magnetic fields on collision dynamics of OH(2Pi) molecules. It is demonstrated that spin relaxation in 3He-OH collisions at temperatures below…