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A nonlinear phase-field model is developed to simulate corrosion damage. The motion of the electrode$-$ electrolyte interface follows the usual kinetic rate theory for chemical reactions based on the Butler-Volmer equation. The model links…

Chemical Physics · Physics 2024-08-28 M. Makuch , S. Kovacevic , M. R. Wenman , E. Martínez-Pañeda

The requirement for low operational voltage in electrowetting devices, met using thin dielectrics, is usually connected with serious material failure issues. Dielectric breakdown (visible as electrolysis) is frequently evident slightly…

The 2D electrons trapped in vacuum near the atomically thin dielectric (ATD, mono- or $N$-layer film of $h$-BN or transition metal dichalcogenide) are considered. ATD is suspended above the back gate and forms the capacitor which is…

Mesoscale and Nanoscale Physics · Physics 2021-06-01 F. T. Vasko

CdTe-based thin film solar cell has been modeled and enumerated with a thin CuInTe2 (CIT) current booster layer. CdTe-based n-CdS/p-CdTe/p+-CIT/p++-WSe2 heterojunction device has been evaluated for the highest performance. It is revealed…

Electrochemical kinetics at electrode-electrolyte interfaces limit performance of devices including fuel cells and batteries. While the importance of moving beyond Butler-Volmer kinetics and incorporating the effect of electronic density of…

Chemical Physics · Physics 2021-01-06 Rachel Kurchin , Venkatasubramanian Viswanathan

The purpose of this project is to investigate the use of charge couple devices (CCDs) to detect electrons directly. This can be done in transmission electron microscopy (TEM) for electrons over 100 KeV, but for space plasma instruments,…

Instrumentation and Detectors · Physics 2015-10-28 S. R. Mirfayzi

The remarkably low experimental values of the capacitance data of carbon based materials in contact with water solvent needs to be explained from a microscopic theory in order to optimize the efficiency of these materials. We show that this…

Soft Condensed Matter · Physics 2015-06-04 Sahin Buyukdagli , Tapio Ala-Nissila

We consider an electrolyte solution confined by semipermeable membranes in contact with a salt-free solvent. Membranes are uncharged, but since small counter-ions leak-out into infinite salt-free reservoirs, we observe a distance-dependent…

Soft Condensed Matter · Physics 2014-08-19 Salim R. Maduar , Olga I. Vinogradova

The behavior of a non-conductive quasi-planar lipid membrane in an electrolyte and in a static (DC) electric field is investigated theoretically in the nonlinear (Poisson-Boltzmann) regime. Electrostatic effects due to charges in the…

Soft Condensed Matter · Physics 2015-05-18 Falko Ziebert , David Lacoste

In electrochemical systems, an understanding of the underlying transport processes is required to aid in their better design. This includes knowledge of possible near-electrode convective mixing that can enhance measured currents. Here, for…

Fluid Dynamics · Physics 2021-09-15 Nakul Pande , Jeffery A. Wood , Guido Mul , Detlef Lohse , Bastian T. Mei , Dominik Krug

We study small conducting particles and thin films in an oscillating longitudinal electric field. We find the charge, current, and field distribution in the particle, the polarizability and the electric dipole absorption. We account for…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 B. Goodman , R. A. Serota

The influence of a chemically or electrically heterogeneous distribution of interaction sites at a planar substrate on the number density of an adjacent fluid is studied by means of classical density functional theory (DFT). In the case of…

Soft Condensed Matter · Physics 2018-05-25 Maximilian Mußotter , Markus Bier , S. Dietrich

Superconducting thin films and layered crystals display a Nernst signal generated by short-lived Cooper pairs above their critical temperature. Several experimental studies have broadly verified the standard theory invoking Gaussian…

Cupric oxide single crystal thin films were grown by plasma-assisted molecular beam epitaxy. X-ray diffraction, Raman spectrum and in situ reflection high-energy electron diffraction show that the thin films are 2x2 reconstructed with an…

Materials Science · Physics 2017-01-04 K. G. Yang , S. X. Wu , F. M. Yu , W. Q. Zhou , Y. J. Wang , M. Meng , G. L. Wang , Y. L. Zhang , S. W. Li

A model for the extraction of the charge density dependent mobility and variable contact resistance in thin film transistors is proposed by performing a full derivation of the current-voltage characteristics both in the linear and…

A novel hybrid method based on Mie theory and the Discrete Dipole Approximation (DDA) was developed to study the microscopic parameters governing the optical response of tunable photonic crystals (PC). The method is based on a two-step…

A numerical study within the framework of the Poisson-Nernst-Planck equations is conducted to investigate electrostatic screening of charged bio-molecules within synthetic pores having diameters of at least 10 Debye lengths. We show that…

Biological Physics · Physics 2009-11-13 Yang Liu , Jon Sauer , Robert Dutton

We theoretically investigate the response of a superconducting film to line currents flowing in linear wires placed above the film, and we present analytic expressions for the magnetic-field and current distributions based on the critical…

Superconductivity · Physics 2009-11-11 Yasunori Mawatari , John R. Clem

Understanding the electrical double layer (EDL), i.e, the distribution of electrolyte at an electrified interface, in concentrated electrolytes is important for various technologies, such as supercapacitors, batteries and electrocatalysis.…

Soft Condensed Matter · Physics 2026-05-01 Zachary A. H. Goodwin

It has been experimentally observed that weakly conducting suspended films of smectic liquid crystals undergo electroconvection when subjected to a large enough potential difference. The resulting counter-rotating vortices form a very…

patt-sol · Physics 2009-10-30 V. B. Deyirmenjian , Zahir A. Daya , Stephen W. Morris