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We develop a model for predicting fine- and hyperfine intensities in the direct photoionization of molecules based on the separability of electron and nuclear spin states from vibrational-electronic states. Using spherical tensor algebra,…

Chemical Physics · Physics 2016-08-24 Matthias Germann , Stefan Willitsch

Highly excited eigenstates of atoms and ions with open f shell are chaotic superpositions of thousands, or even millions of Hartree-Fock determinant states. The interaction between dielectronic and multielectronic configurations leads to…

Atomic Physics · Physics 2015-06-17 V. A. Dzuba , V. V. Flambaum , G. F. Gribakin , C. Harabati , M. G. Kozlov

In molecular photofragmentation processes by soft X-rays, a number of ionic fragments can be produced, each having a different abundance and correlation with the emitted electron kinetic energy. For investigating these fragmentation…

Atomic Physics · Physics 2007-05-23 G. Pruemper , K. Ueda

This work presents our theoretical study of the dissociative recombination (DR) of the closed-shell diatomic system CF$^+$ based on an approach recently applied to the CH$^+$ molecule. Our extended treatment uses the UK R-matrix theory and…

Photoionization and its inverse, electron-ion recombination, are key processes that influence many astrophysical plasmas (and gasses), and the diagnostics that we use to analyse the plasmas. In this review we provide a brief overview of the…

Solar and Stellar Astrophysics · Physics 2023-03-21 D. John Hillier

High-resolution photoionization experiments were carried out using beams of Be-like C$^{2+}$, N$^{3+}$, and O$^{4+}$ ions with roughly equal populations of the $^1$S ground-state and the $^3$P$^o$ manifold of metastable components. The…

Earth and Planetary Astrophysics · Physics 2012-03-30 A Müller , S Schippers , R. A. Phaneuf , A. L. D. Kilcoyne , H. Bräuning , A. S. Schlachter , M. Lu , B. M. McLaughlin

Modifications of photoionization arising from resonant electron-electron correlations between neighbouring atoms in an atomic sample are studied. The sample contains atomic species A and B, with the ionization potential of A being smaller…

Atomic Physics · Physics 2015-06-04 B. Najjari , C. Müller , A. B. Voitkiv

The photodissociation cross section of the molecular ion HeH$^+$ was calculated within the Born-Oppenheimer approximation for a parallel, a perpendicular, and an isotropic orientation of the molecular axis with respect to the field,…

Atomic Physics · Physics 2015-05-13 Irina Dumitriu , Alejandro Saenz

The feasibility of complete photoionization experiments, in which the full set of photoionization matrix elements are determined, using multiphoton ionization schemes with polarization-shaped pulses has recently been demonstrated [Hockett…

Atomic Physics · Physics 2015-07-22 P. Hockett , M. Wollenhaupt , C. Lux , T. Baumert

A detailed theory-versus-experiment comparison is worked out for H$_2^+$ intense laser dissociation, based on angularly resolved photodissociation spectra recently recorded in H.Figger's group. As opposite to other experimental setups, it…

Quantum Physics · Physics 2009-11-10 Vassili Serov , Arne Keller , Osman Atabek , Nicolas Billy

Photoionization of an atom via interatomic correlations to N neighboring atoms may be strongly enhanced due to constructive interference of quantum pathways. The ionization proceeds via resonant photoexcitation of a neighbor atom and…

Atomic Physics · Physics 2015-05-30 Carsten Müller , Mihai A. Macovei , Alexander B. Voitkiv

We present state-selective measurements on the NH$_2^{+}$ + H$^{+}$ and NH$^{+}$ + H$^{+}$ + H dissociation channels following single-photon double ionization at 61.5 eV of neutral NH$_{3}$, where the two photoelectrons and two cations are…

We investigate K-shell ionization of N$_2$ at 40 keV photon energy. Using a COLTRIMS reaction microscope we determine the vector momenta of the photoelectron, the Auger electron and both N$^+$ fragments. These fully differential data show…

Rovibrational energies, wave functions, and Raman transition moments are reported for the lowest-energy states of the H$_3^+$ molecular ion including the magnetic couplings of the proton spins and molecular rotation in the presence of a…

Chemical Physics · Physics 2024-10-29 Gustavo Avila , Ayaki Sunaga , Stanislav Komorovsky , Edit Matyus

We calculate the photoionization with excitation-to photoionization ratios for atomic helium and heliumlike ions at intermediate values of the photon energies. The final state interactions between the electrons are included in the lowest…

Quantum Physics · Physics 2009-11-13 E. G. Drukarev , E. Z. Liverts , M. Ya. Amusia , R. Krivec , V. B. Mandelzweig

We investigate photon merging and splitting processes in inhomogeneous, slowly varying electromagnetic fields. Our study is based on the three-photon polarization tensor following from the Heisenberg-Euler effective action. We put special…

High Energy Physics - Phenomenology · Physics 2016-04-28 Holger Gies , Felix Karbstein , Nico Seegert

We present a study of multiphoton dissociative ionization from molecules. By solving the time-dependent Schr\"{o}dinger equation for H$_2^+$ and projecting the solution onto double continuum scattering states, we observe the correlated…

Atomic Physics · Physics 2012-07-03 C B Madsen , F Anis , L B Madsen , B D Esry

Realistic modeling of stellar spectra requires accurate radiative opacity coefficients. Owing to the fragmentary nature of existing data from rigorous quantum-mechanical calculations, photoionization coefficients based on the…

Solar and Stellar Astrophysics · Physics 2026-04-22 René D. Rohrmann

We propose a new model for treating solid-phase photoprocesses in interstellar ice analogues. In this approach, photoionization and photoexcitation are included in more detail, and the production of electronically-excited (suprathermal)…

Three-body recombination is a prime example of the fundamental interaction between three particles. Due to the complexity of this process it has resisted a comprehensive description. Experimental investigations have mainly focussed on the…