Related papers: Persistence Length of Flexible Polyelectrolyte Cha…
We report on a study of the shape of a stiff, charged rod that is subjected to equal and opposite force couples at its two ends. Unlike a neutral elastic rod, which forms a constant curvature configuration under such influences, the charged…
We present a theory for the equilibrium structure of polyelectrolyte solutions. The main element is a simple, new optimization scheme that allows theories such as the random phase approximation (RPA) to handle the harsh repulsive forces…
The charge of a polyelectrolyte (PE) controls myriads of phenomena in biology, biotechnology, and materials science, but still remains elusive from an understanding. Considering the adsorption of counterions on an isolated PE chain, an…
We study the half-chain entanglement entropy in the ground state of the spin-1/2 XX chain across an extended random defect, where the strength of disorder decays with the distance from the interface algebraically as $\Delta_l\sim…
We perform extensive molecular dynamics simulations of a charged polymer in a good solvent in the regime where the chain is collapsed. We analyze the dependence of the gyration radius $R_g $ on the reduced Bjerrum length $\ell_B$ and find…
We perform extensive molecular dynamics simulations of a highly charged flexible polyelectrolyte (PE) chain in a poor solvent for the case when the chain is in a collapsed state and the electrostatic interactions, characterized by the…
We study, via computer simulations, the fluctuations in the net electric charge, in a two dimensional one component plasma (OCP) with uniform background charge density $-e \rho$, in a region $\Lambda$ inside a much larger overall neutral…
Conformations of partially or fully adsorbed semiflexible polymer chains are studied varying both contour length $L$, chain stiffness, $\kappa$, and the strength of the adsorption potential over a wide range. Molecular Dynamics simulations…
We consider dynamics of an isolated polymer chain with a chemically active end-bead on a 2D solid substrate containing immobile, randomly placed chemically active sites (traps). For a particular situation when the end-bead can be…
We theoretically study the polarizability and the interactions of neutral complexes consisting of a semi-flexible polyelectrolyte adsorbed onto an oppositely charged spherical colloid. In the systems we studied, the bending energy of the…
The response of a semiflexible polyelectrolyte chain to stretching in the regimes of moderate and weak screening is studied theoretically, with a special focus on DNA experiments. By using the nonlinear Poisson--Boltzmann description of…
For a self-repelling polymer chain consisting of n segments we calculate the persistence length L(j,n), defined as the projection of the end-to-end vector on the direction of the j`th segment. This quantity shows some pronounced variation…
We show that in a ring-shaped Luttinger Liquid (LL) in contact with an electron reservoir --- the chemical potential in the ring being controlled by a gate voltage $V_g$ --- both the average ring charge and the persistent current in the…
The frequency and shear dependent critical viscosity at a correlation length $\xi=\kappa^{-1}$, has the form $\eta=\eta_{0}\kappa^{-x_{\eta}}G(z_{1},z_{2})$, where $z_{1}$ and $z_{2}$ are the independent dimensionless numbers in the problem…
Light scattering and viscometric measurements on weak polyelectrolytes show two important aspects of counterion condensation, namely, non-monotonic variation in the polyelectrolyte size with the increase in the electrostatic strength, and,…
We prove a functional limit theorem for the rescaled occupation time fluctuations of a $(d,\alpha,\beta)$-branching particle system [particles moving in $\mathbb {R}^d$ according to a symmetric $\alpha$-stable L\'{e}vy process, branching…
The thermal conductivity, $\kappa$, of a homogeneous chain of generically-ranged interacting planar rotors, more precisely the inertial $\alpha-XY$ model, is numerically studied with the coupling constant decaying as $r^{-\alpha}$. The…
We study the elastic properties of a single A/B copolymer chain with a specific sequence. We predict a rich structure in the force extension relations which can be addressed to the sequence. The variational method is introduced to probe…
With paying special attention to the divergence in the compressibility $\kappa$, we study the Coulombic screening in alkali metals to find singular long-range fluctuations in the electronic polarization originating from this divergence. As…
By using high molecular weight fluorescent passive tracers with different diffusion coefficients and by changing the fluid velocity we study dependence of a characteristic mixing length on the Peclet number, $Pe$, which controls the mixing…